Activity Coefficients and Partial-Molar Heats of Mixing at Infinite Dilution of the Components for the Dimethylzinc - Dimethyl Telluride System

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dc.citation.epage473
dc.citation.issue4
dc.citation.journalTitleХімія та хімічна технологія
dc.citation.spage458
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.authorGerasymchuk, Serhiy
dc.contributor.authorPoliuzhyn, Ihor
dc.contributor.authorSerheyev, Valentyn
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2026-03-26T07:38:22Z
dc.date.created2024-02-27
dc.date.issued2024-02-27
dc.description.abstractЗа допомогою напівемпіричної моделі описано рівновагу пара – рідина в системі диметилцинк –-диметилтелурид: розраховано коефіцієнти активності компонентів розчину та парціальні теплоти розчинення за безмежного розбавлення. Первинні дані для застосування напівемпіричної моделі ми отримали, вимірявши температурну залежність тиску насиченої пари високочистих зразків диметилцинку, диметилтелуриду та їхніх розчинів.
dc.description.abstractUsing a semi-empirical model, the vaporliquid equilibrium is described in the dimethylzinc –dimethyl telluride system: the activity coefficients of the solution components and the partial-molar heats of mixing at infinite dilution are calculated. The primary data for the application of the semi-empirical model were obtained by us from measuring the temperature dependence of the saturated vapor pressure of highly pure samples of dimethylzinc, dimethyl telluride and their solutions.
dc.format.extent458-473
dc.format.pages16
dc.identifier.citationGerasymchuk S. Activity Coefficients and Partial-Molar Heats of Mixing at Infinite Dilution of the Components for the Dimethylzinc - Dimethyl Telluride System / Serhiy Gerasymchuk, Ihor Poliuzhyn, Valentyn Serheyev // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2024. — Vol 18. — No 4. — P. 458–473.
dc.identifier.citationenGerasymchuk S. Activity Coefficients and Partial-Molar Heats of Mixing at Infinite Dilution of the Components for the Dimethylzinc - Dimethyl Telluride System / Serhiy Gerasymchuk, Ihor Poliuzhyn, Valentyn Serheyev // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2024. — Vol 18. — No 4. — P. 458–473.
dc.identifier.doidoi.org/10.23939/chcht18.04.458
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/124798
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofХімія та хімічна технологія, 4 (18), 2024
dc.relation.ispartofChemistry & Chemical Technology, 4 (18), 2024
dc.relation.references[1] Poling, B. E.; Prausnitz, J. M.; OConnell, J.P. The properties of gases and liquids; 5th Edition; McGraw Hill: New York, 2001
dc.relation.references[2] Serheyev, V. Enthalpies of Mixing Methylmethacrylate with Some Organic Solvents. Chem. Chem. Technol. 2012, 6, 15–18. https://doi.org/10.23939/chcht06.01.015
dc.relation.references[3] Serheyev, V. The Enthalpy of Mixing of the Laurylmethacrylate with Some Organic Solvents. Chem. Chem. Technol. 2015, 9, 1–4. https://doi.org/10.23939/chcht09.01.001
dc.relation.references[4] Serheyev, V.; Kos, Yu.; Van-Chin-Syan, Yu. Thermodynamic Properties of Solutions of Ethacrylic Acid in Acetonitrile and Acetic Acid. Chem. Chem. Technol. 2015, 9, 131–135. https://doi.org/10.23939/chcht09.02.131
dc.relation.references[5] Serheyev, V.; Van Thanh, T. Thermodynamic Properties of Butyl Methacrylate Solutions in Organic Solvents. Chem. Chem. Technol. 2018, 12, 7–12. https://doi.org/10.23939/chcht12.01.007
dc.relation.references[6] Bacsa, J.; Hanke, F.; Hindley, S.; Odedra, R.; Darling, G. R.; Jones, A.C.; Steiner, A. The Solid State Structures of Dimethylzinc and Diethylzinc. Angew. Chem. Int. Ed. 2011, 50, 11685–11687. https://doi.org/10.1002/anie.201105099
dc.relation.references[7] Liebman, J. F., Slayden, S. W. Thermochemistry of Organoselenium and Organotellurium Compounds; PATAI’S Chemistry of Functional Groups. John Wiley & Sons, Ltd., 2011.
dc.relation.references[8] Gerasymchuk, S.; Poliuzhyn, I.; Serheyev, V.; Hnativ, T. Method For Obtaining Isothermal Diagrams of the Liquid – Vapor Equilibrium for the System as Dimethyl Zinc – Dimethyl Telluride. Chem. Chem. Technol. 2023, 17, 469–480. https://doi.org/10.23939/chcht17.03.469
dc.relation.references[9] Gerasymchuk, S. I. Thermodynamics of evaporation for alkyl compounds of zinc, selenium, tellurium and their solutions. Ph.D. Thesis, Lviv Polytechnic Institute, Lviv, Ukraine, 1991.
dc.relation.references[10] Gerasymchuk, S. I.; Poliuzhyn, I. P.; Oliynyk, L. P.; Hnativ, T. B. Evaporation Thermodynamics for Solutions of Dimethylzinc and Dimethyltelluride – Dimethyl Telluride. Chem. Technol. App. Subst. 2022, 5, 37–46. https://doi.org/10.23939/ctas2022.02.037
dc.relation.references[11] Raal, D. J.; Muhlbauer, A. L. Phase Equilibria. Measurement and Computation; Taylor & Francis, 1997.
dc.relation.references[12] Treybal, R.E. Liquid Extraction; McGraw-Hill: New York, 1963.
dc.relation.referencesen[1] Poling, B. E.; Prausnitz, J. M.; OConnell, J.P. The properties of gases and liquids; 5th Edition; McGraw Hill: New York, 2001
dc.relation.referencesen[2] Serheyev, V. Enthalpies of Mixing Methylmethacrylate with Some Organic Solvents. Chem. Chem. Technol. 2012, 6, 15–18. https://doi.org/10.23939/chcht06.01.015
dc.relation.referencesen[3] Serheyev, V. The Enthalpy of Mixing of the Laurylmethacrylate with Some Organic Solvents. Chem. Chem. Technol. 2015, 9, 1–4. https://doi.org/10.23939/chcht09.01.001
dc.relation.referencesen[4] Serheyev, V.; Kos, Yu.; Van-Chin-Syan, Yu. Thermodynamic Properties of Solutions of Ethacrylic Acid in Acetonitrile and Acetic Acid. Chem. Chem. Technol. 2015, 9, 131–135. https://doi.org/10.23939/chcht09.02.131
dc.relation.referencesen[5] Serheyev, V.; Van Thanh, T. Thermodynamic Properties of Butyl Methacrylate Solutions in Organic Solvents. Chem. Chem. Technol. 2018, 12, 7–12. https://doi.org/10.23939/chcht12.01.007
dc.relation.referencesen[6] Bacsa, J.; Hanke, F.; Hindley, S.; Odedra, R.; Darling, G. R.; Jones, A.C.; Steiner, A. The Solid State Structures of Dimethylzinc and Diethylzinc. Angew. Chem. Int. Ed. 2011, 50, 11685–11687. https://doi.org/10.1002/anie.201105099
dc.relation.referencesen[7] Liebman, J. F., Slayden, S. W. Thermochemistry of Organoselenium and Organotellurium Compounds; PATAI’S Chemistry of Functional Groups. John Wiley & Sons, Ltd., 2011.
dc.relation.referencesen[8] Gerasymchuk, S.; Poliuzhyn, I.; Serheyev, V.; Hnativ, T. Method For Obtaining Isothermal Diagrams of the Liquid – Vapor Equilibrium for the System as Dimethyl Zinc – Dimethyl Telluride. Chem. Chem. Technol. 2023, 17, 469–480. https://doi.org/10.23939/chcht17.03.469
dc.relation.referencesen[9] Gerasymchuk, S. I. Thermodynamics of evaporation for alkyl compounds of zinc, selenium, tellurium and their solutions. Ph.D. Thesis, Lviv Polytechnic Institute, Lviv, Ukraine, 1991.
dc.relation.referencesen[10] Gerasymchuk, S. I.; Poliuzhyn, I. P.; Oliynyk, L. P.; Hnativ, T. B. Evaporation Thermodynamics for Solutions of Dimethylzinc and Dimethyltelluride – Dimethyl Telluride. Chem. Technol. App. Subst. 2022, 5, 37–46. https://doi.org/10.23939/ctas2022.02.037
dc.relation.referencesen[11] Raal, D. J.; Muhlbauer, A. L. Phase Equilibria. Measurement and Computation; Taylor & Francis, 1997.
dc.relation.referencesen[12] Treybal, R.E. Liquid Extraction; McGraw-Hill: New York, 1963.
dc.relation.urihttps://doi.org/10.23939/chcht06.01.015
dc.relation.urihttps://doi.org/10.23939/chcht09.01.001
dc.relation.urihttps://doi.org/10.23939/chcht09.02.131
dc.relation.urihttps://doi.org/10.23939/chcht12.01.007
dc.relation.urihttps://doi.org/10.1002/anie.201105099
dc.relation.urihttps://doi.org/10.23939/chcht17.03.469
dc.relation.urihttps://doi.org/10.23939/ctas2022.02.037
dc.rights.holder© Національний університет “Львівська політехніка”, 2024
dc.rights.holder© Gerasymchuk S., Poliuzhyn I., Serheyev V., 2024
dc.subjectдиметилцинк
dc.subjectдиметилтелурид
dc.subjectкоефіцієнти активності
dc.subjectпарціальні теплоти розчинення
dc.subjectdimethylzinc
dc.subjectdimethyl telluride
dc.subjectactivity coefficients
dc.subjectpartial heats of mixing
dc.titleActivity Coefficients and Partial-Molar Heats of Mixing at Infinite Dilution of the Components for the Dimethylzinc - Dimethyl Telluride System
dc.title.alternativeКоефіцієнти активності та парціальномольні теплоти розчинення за безмежного розбавлення компонентів системи диметилцинк – диметилтелурид
dc.typeArticle

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Chemistry & Chemical Technology. – 2024. – Vol. 18, No. 4