Fire-resisting composites based on polymer matrix

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dc.citation.epage84
dc.citation.issue1
dc.citation.spage77
dc.contributor.affiliationMoscow State University of Civil Engineering
dc.contributor.affiliationIsraeli Association of Inventors
dc.contributor.authorUshkov, Valentin
dc.contributor.authorFigovsky, Oleg
dc.contributor.authorSmirnov, Vladimir
dc.contributor.authorSeleznev, Vyacheslav
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2020-03-02T10:50:10Z
dc.date.available2020-03-02T10:50:10Z
dc.date.created2019-02-28
dc.date.issued2019-02-28
dc.description.abstractВивчено термостабільність і пожежно- технічні параметри епоксидних композитів з різними за- твердниками, наповнювачами, пластифікаторами та ретар- дантами. Показано, що вміст мінеральних наповнювачів до 45% мало впливає на займистість. Формування диму зменшується лінійно з підвищенням ступеня наповнення. Пока- зано, що для отримання низькогорючих матеріалів кисневий індекс повинен перевищувати 31 %. Встановлено, що опти- мальна концентрація промислових бромованих вогнетривких речовин становить 8–10% за масою. Для зменшення горючості епоксидних композитів запропоновано використовувати бромвмісні ретарданти у вигляді розчину в N, N-диметил-2,4,6- трибромоаніліні. Показана висока ефективність ацетил- та α-гідроксиетилферроценових додатків для зменшення диму.
dc.description.abstractIn the present work we have studied the thermal stability, flammability, and fume evolution of epoxy matrix composites with different types and amounts of hardeners, fillers, plasticizers, and fire retardants. It is shown that chemical composition of fillers has little effect on the flammability of epoxy composites when the content of mineral fillers is less than 45 % by mass. Smoke formation decreases linearly with increase of the filling degree. It is shown that to obtain low-combustible materials the oxygen index should exceed 31 %. It was found that the optimal concentration of industrial brominated fire retardants is 8–10 % by mass. To reduce the flammability of epoxy composites, additive brominated fire retardants in the form of a solution in N,N-dimethyl- 2,4,6-tribromoaniline have been proposed. The high efficiency of acetyl- and α-hydroxyethyl ferrocene as a smoke suppressor of epoxy composites is shown.
dc.format.extent77-84
dc.format.pages8
dc.identifier.citationFire-resisting composites based on polymer matrix / Valentin Ushkov, Oleg Figovsky, Vladimir Smirnov, Vyacheslav Seleznev // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2019. — Vol 13. — No 1. — P. 77–84.
dc.identifier.citationenFire-resisting composites based on polymer matrix / Valentin Ushkov, Oleg Figovsky, Vladimir Smirnov, Vyacheslav Seleznev // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2019. — Vol 13. — No 1. — P. 77–84.
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/46417
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 1 (13), 2019
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dc.relation.referencesen29. Chen X., Jiao C., Li S., Hu Y., Fire Safety J., 2013, 58, 208. https://doi.org/10.1016/j.firesaf.2013.01.011
dc.relation.referencesen30. Lim K., Bee S., Sin L. et al., Compos. Part B-Eng., 2016, 84, 155-174. https://doi.org/10.1016/j.compositesb.2015.08.066
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dc.relation.referencesen36. Ushkov V., Lalayan V., Lomakin S., Nevzorov D., Pozharovzryvobezopasnost', 2013, 22, 33.
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dc.relation.referencesen38. Ushkov V., Abramov V., Grigor'eva L., Kir'yanova L., Stroitel'nye Mater., 2011, 12, 68.
dc.relation.referencesen39. Ushkov V., Grigor'eva L., Abramov V., VestnikMGSU, 2011, 2, 352.
dc.relation.referencesen40. Ushkov V., Nevzorov D., Kopytin A., Lalayan V., Pozharovzryvobezopasnost', 2014, 23, 27.
dc.relation.referencesen41. Ushkov V., Abramov V., Lalayan V., Kir'yanova L., Pozharovzryvobezopasnost', 2012, 21, 36.
dc.relation.referencesen42. Panina N., Chursova L., Babin A. et al., VseMaterialy. Entsikloped. Spravochn., 2014, 9, 10.
dc.relation.referencesen43. Bryk M., Destryktchia Napolnennykh Polimerov. Khimiya, Moskva 1989.
dc.relation.referencesen44. Khalturinskiy N., VseMaterialy. Entsikloped. Spravochn., 2009, 11, 22.
dc.relation.referencesen45. Khalturinskiy N., VseMaterialy. Entsikloped. Spravochn., 2009, 12, 30.
dc.relation.referencesen46. Khalturinskiy N., Rudakova T., Khim. Fizika, 2008, 27, 73.
dc.relation.referencesen47. Kudryavtzev P., FigovskyO.:US Pat. 9695111, Pub. Jul. 4, 2017.
dc.relation.urihttps://doi.org/10.1016/j.progpolymsci.2014.08.001
dc.relation.urihttps://doi.org/10.1016/j.proeng.2016.11.873
dc.relation.urihttps://doi.org/10.4028/www.scientific.net/AMR.1040.730
dc.relation.urihttps://doi.org/10.1061/(ASCE)1090-0268(2003)7:3(238
dc.relation.urihttps://doi.org/10.1061/(ASCE)1090-0268(2002)6:2(73
dc.relation.urihttps://doi.org/10.1201/b19693-79
dc.relation.urihttps://doi.org/10.1016/j.proeng.2016.11.929
dc.relation.urihttps://doi.org/10.4028/www.scientific.net/MSF.871.40
dc.relation.urihttps://doi.org/10.1016/j.firesaf.2013.01.009
dc.relation.urihttps://doi.org/10.1016/0379-7112(80)90004-1
dc.relation.urihttps://doi.org/10.3390/ma3104710
dc.relation.urihttps://doi.org/10.1016/j.polymdegradstab.2004.01.027
dc.relation.urihttps://doi.org/10.1016/j.polymdegradstab.2016.03.028
dc.relation.urihttps://doi.org/10.1016/j.firesaf.2013.01.011
dc.relation.urihttps://doi.org/10.1016/j.compositesb.2015.08.066
dc.relation.urihttps://doi.org/10.1016/j.firesaf.2014.08.019
dc.relation.urihttps://doi.org/10.1002/pola.1991.080290711
dc.relation.urihttps://doi.org/10.1016/S0082-0784(06)80690-9
dc.relation.urihttps://doi.org/10.1002/(SICI)1099-0739(199603)10:2<101::AID-AOC484>3.0.CO;2-7
dc.rights.holder© Національний університет „Львівська політехніка“, 2019
dc.rights.holder© Ushkov V., Figovsky O., Smirnov V., Seleznev V., 2019
dc.subjectбромвмісні ретарданти
dc.subjectзаймистість
dc.subjectгорючість
dc.subjectепоксидні композити
dc.subjectнаповнювач
dc.subjectпластифікатор
dc.subjectпохідні ферроцену
dc.subjectbrominated fire retardants
dc.subjectflammability
dc.subjectcombustibility
dc.subjectfume evolution index
dc.subjectepoxy matrix composites
dc.subjectfillers
dc.subjectplasticizers
dc.subjectferrocene derivatives
dc.titleFire-resisting composites based on polymer matrix
dc.title.alternativeВогнестійкі композити на основі полімерної матриці
dc.typeArticle

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Chemistry & Chemical Technology. – 2019. – Vol. 13, No. 1