(Видавництво Львівської політехніки, 2013) Veselovskyi, Volodymyr; Zakharova, Tatyana; Ischenko, Olena
Abstract – The kinetics of CO and H2 oxidation over mixed oxide catalysts based on transition metals (Cu, Co, Fe) were tested in the CO-PROX reaction. The experimental results showed that the CO oxidation rate was essentially independent of H2 and O2 concentrations, while the H2 oxidation rate was practically independent of CO and O2 concentrations. It was shown that the experimental kinetic regularities of CO oxidation could be described by the Mars-van Krevelen equation. In the CO oxidation, the reaction orders were 1 and 0 with respect to the partial pressure of CO and O2, respectively
