Дослідження кінетики комплексоутворення 2-метоксифенолу з йоном феруму(ІІІ) та йоном гексаціаноферуму(ІІІ)

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dc.citation.epage20
dc.citation.issue7
dc.citation.journalTitleХімія, технологія речовин та їх застосування
dc.citation.spage15
dc.citation.volume1
dc.contributor.affiliationНаціональний університет “Львівська політехніка”
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.authorОлійник, Л. П.
dc.contributor.authorOliynyk, L. P.
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2025-09-12T08:00:00Z
dc.date.created2024-02-27
dc.date.issued2024-02-27
dc.description.abstractДосліджено комплексоутворення 2-метоксифенолу з йоном феруму (ІІІ) та йоном гексаціаноферуму (ІІІ). Кінетичні дослідження показали, що порядок реакції щодо йона тривалентного феруму або гексаціанойона тривалентного феруму близький до одиниці. Порядок реакції за 2-метоксифенолом становить 0,8 у реакції з йоном феруму (ІІІ) і близький до нуля у реакції з гексаціанойоном феруму (ІІІ). Виявлено, що утворені комплекси стійкі в кислому середовищі за рН менше ніж 7 і швидко розкладаються в лужному. Комплекс йона феруму з 2-метоксифенолом розкладається на 2-метоксифенол і гідроксид феруму за рН понад 8. Водночас швидке окиснення 2-метоксифенолу спостерігається із підвищенням рН розчину комплексу йона гексаціаноферуму з 2-метоксифенолом. Знайдені значення Kp у разі взаємодії йона феруму з 2-метоксифенолом істотно більші, ніж для реакції із йоном гексаціаноферуму.
dc.description.abstractStudy of the formation of complexes of 2-methoxyphenol with ferrum (III) ion or hexacyanoferrum (III) ion. Kinetic studies have shown that the order of reaction for ferrum ion or ferrum hexacyanoion is close to one. The order of reaction for 2-methoxyphenol is 0.8 in the reaction with ferrum (III) ion and close to zero in the reaction with ferrum (III) hexacyanoion. It has been shown that the formed complexes are stable in acidic solution at pH less than 7 and rapidly decompose in alkaline solution. The complex of iron ion with 2-methoxyphenol decomposes into 2-methoxyphenol and ferrum hydroxide at pH above 8. At the same time, the rapid oxidation of 2-methoxyphenol is observed with increasing pH of the solution of the hexacyanoiron ion complex with 2-methoxyphenol. The found Kp values for the interaction of ferrum ion with 2-methoxyphenol are much higher than for the reaction with hexacyanoferrum ion.
dc.format.extent15-20
dc.format.pages6
dc.identifier.citationОлійник Л. П. Дослідження кінетики комплексоутворення 2-метоксифенолу з йоном феруму(ІІІ) та йоном гексаціаноферуму(ІІІ) / Л. П. Олійник // Хімія, технологія речовин та їх застосування. — Львів : Видавництво Львівської політехніки, 2024. — Том 1. — № 7. — С. 15–20.
dc.identifier.citationenOliynyk L. P. Research kinetics of complexation of 2-methoxyphenol with ferrum(III) ion and ferrum(III) hexacyanoion / L. P. Oliynyk // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2024. — Vol 1. — No 7. — P. 15–20.
dc.identifier.doidoi.org/10.23939/ctas2024.01.015
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/111749
dc.language.isouk
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofХімія, технологія речовин та їх застосування, 7 (1), 2024
dc.relation.ispartofChemistry, Technology and Application of Substances, 7 (1), 2024
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dc.relation.referencesen1. Sartaj Tabassum ; Khan Rais Ahmad; Arjmand Farukh; Juvekar Aarti S; Zingde Surekha M. (2010). Synthesis of carbohydrate-conjugate heterobimetallic Cu(II)-Sn(2)(IV) and Zn(II)-Sn(2)(IV) complexes; their interactions with CT DNA and nucleotides; DNA cleavage, in-vitro cytotoxicity., Eur. J. Med. Chem ; 45(11):4797-4806 doi: 10.1016/j.ejmech.2010.07.046.
dc.relation.referencesen2. S.Tabassum, S.H.Rafiqi, N.Nishat, F.Arjmand and S. Srivastava (2001). Synthesis and Characterization of heterobimetallic Complexes of 1,8dihydro1,3,6,8,10,13 Hexaazacyclotetradecane with Cu (II), Ni(II), Si(IV), Ge(IV) and Sn(IV)Chlorides Indian. J. Chem; 40(A), 1237-1239 http://nopr.niscpr.res.in/handle/123456789/18615
dc.relation.referencesen3. R. C. MauryaP. Patel. S. Rajput (2006) Synthesis and characterization of Mixed‐Ligand Complexes of Cu(II), Ni(II), Co(II), Zn(II), Sm(III), and U(VI)O2, with a Schiff Base Derived from the Sulfa Drug Sulfamerazine and 2,2′‐Bipyridine. Pages 801-816 Published online: 20 Aug 2006 https://doi.org/10.1081/SIM-120021647
dc.relation.referencesen4. Roger C. Pettersen and Leory E. Alexander (1968), The molecular geometry of vanadyl deoxophylloerythroetioporphyrin. An analog of chlorophyll J. Am. Chem. Soc.90, 14, 3873-3875. https://doi.org/10.1021/ja01016a056
dc.relation.referencesen5. Sahar I. Mostafa (2000) Synthesis and Structure Studies of Complexes of Some Second Row Transistion Metals with 1-(Phenylacetyl and Phenoxacetyl)-4-phenyl-3-thiosemicarbazide.Chemical andPharmaceuticalBulletinN 48 V 2 p. 266-271 doi https://doi.org/10.1248/cpb.48.266
dc.relation.referencesen6. Tracey, A. S.; Li, H.; Gresser, M. (2010) Is Vanadate Reduced by Thiols under Biological Conditions? Changing the Redox Potential of V(V)/V(IV) by Complexation in Aqueous Solutio. J. Inorg. Chem., 49, 4245-4256 doi: 10.1021/ic100080k https://doi.org/10.1021/ic100080k
dc.relation.referencesen7. Cotton FA, Murillo CA, Walton RA (2005) Multiple bonds between metal atoms, 3rd edn. Springer, Berlin https://doi.org/10.1007/b136230
dc.relation.referencesen8. Vetr F., Moradi-Shoeili Z.,Özkar S. (2018) Oxidation of o-phenylenediamine to 2,3-diaminophenazine in the presence of cubic ferrites MFe2O4 (M = Mn, Co, Ni, Zn) and the application in colorimetric detection of H2O2., vol.32, no.9, 2018 (SCI-Expanded) doi Number:10.1002/aoc.4465
dc.relation.referencesen9. Avelino Corma, Sara Iborra, Alexandra Velty (2007) Chemical Routes for the Transformation of Biomass into Chemicals. Cite this: Chem. Rev. American Chemical Society, 107, 6, 2411-2502 https://doi.org/10.1021/cr050989d
dc.relation.referencesen10. Scott Brownridge, Hongbin Du, Shirley A, Fairhurst, Robert C. Haddon, Simon Parsons.(2000) The isolation, characterisation, gas phase electron diffraction and crystal structure of the thermally stable radical [CF3- CSNSC- CF3]. J. Chem. Soc., Dalton Trans., No 1, p.3365-3382. doi:10.1039/DT99200F0VII.
dc.relation.referencesen11. Humphrey, Jamie; Walton, Paul (2006). Dalton Transactions: Developing for the Inorganic Community. Dalton Transactions. No 1. P.15-17. ISSN1477-9234. doi:10.1039/B516708F.
dc.relation.referencesen12. Jaroslav Burda, Tomáš Zimmermann (2009) Charge-scaled cavities in polarizable continuum model: Determination of acid dissociation constants for platinum-amino acid complexes. The Journal of Chemical Physics. 131, 135101 (2009) https://doi.org/10.1063/1.3236842
dc.relation.referencesen13. Tomas Zimmermann, Jerzy Leszczynski, Jaroslav V. Burda(2011) Activation of the cisplatin and transplatin complexesin solution with constant pH and concentrationof chloride anions; quantum chemical study. J Mol Model. 17 2385-2393 doi:10.1007/s00894-011-1031-6
dc.relation.referencesen14. Ashley Reichardt, Andrev A. Shapiro, Richard Otis, R.Peter Dilon (2021) Advances in additive manufacturing of metal-based functionally graded materials. Int. materials rev. 66. P.1-29. https://doi.org/10.1080/09506608.2019.1709354
dc.relation.referencesen15. Din K., Khan I.A., Shahid M. (1993) A kinetic stady of the complex formation of chromium (III) with L-glutamine. V 32A. p 171-173. https://nopr.nisepr.res.in
dc.relation.referencesen16. Venkata Subba Rao Mushini, V. Ananta Raman and V.Muralidhare Rao (2011) Kinetics of substitution of cis-bis (malonato0 diaaquchromate (III) with glycine, d,l -alanine and d,l-phenylalanine in alkaline medium. Bill. Chem. Soc. Ethiop., 25(1) p.101- 103. https;//www.ajol.info
dc.relation.referencesen17. Yosef Bayeh, Atakilt Abebe, Madhu Thomas, Wolfgang Linert. (2019) Synthesis, characterization and antimicrobial activities of new mixed ligand complexes of cooper(II) with 1,10- phenanthroline and thymine. Journal of transition metal complexes. V2, 459-466. doi:10.32371/jtmc/236072/
dc.relation.referencesen18. Hatice Gamze Sogukomerogullari, Ahmet Oral Sarioğlu (2023) New Mixed Ni(II), Cu(II), and Co (II) Complexes derived from 2-((2-mercaptophenylimino)methyl)-4-methoxyphenol and 1,10-Phenanthroline: Synthesis and Characterization.J.Sogukomerogullari and Sarioglu 2023. 13 (2), 350-358 https://doi.org/10.17714/gumusfenbil.1179269
dc.relation.urihttp://nopr.niscpr.res.in/handle/123456789/18615
dc.relation.urihttps://doi.org/10.1081/SIM-120021647
dc.relation.urihttps://doi.org/10.1021/ja01016a056
dc.relation.urihttps://doi.org/10.1248/cpb.48.266
dc.relation.urihttps://doi.org/10.1021/ic100080k
dc.relation.urihttps://doi.org/10.1007/b136230
dc.relation.urihttps://doi.org/10.1021/cr050989d
dc.relation.urihttps://doi.org/10.1063/1.3236842
dc.relation.urihttps://doi.org/10.1080/09506608.2019.1709354
dc.relation.urihttps://nopr.nisepr.res.in
dc.relation.urihttps://doi.org/10.17714/gumusfenbil.1179269
dc.rights.holder© Національний університет “Львівська політехніка”, 2024
dc.subject2-метоксифенол
dc.subjectйон гексаціаноферуму
dc.subjectйон феруму (ІІІ)
dc.subjectкомплексоутворення
dc.subject2-methoxyphenol
dc.subjecthexacyanoferrum (III) ion
dc.subjectferrum (III) in
dc.subjectcomplexation
dc.titleДослідження кінетики комплексоутворення 2-метоксифенолу з йоном феруму(ІІІ) та йоном гексаціаноферуму(ІІІ)
dc.title.alternativeResearch kinetics of complexation of 2-methoxyphenol with ferrum(III) ion and ferrum(III) hexacyanoion
dc.typeArticle

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Chemistry, Technology and Application of Substances. – 2024. – Vol. 7, No. 1