Термодинамічні параметри розчину 2-метил-5-феніл-1-(-4-метилфеніл)-пірол-3-карбонової кислоти у спиртах

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dc.contributor.affiliationНаціональний університет “Львівська політехніка”
dc.contributor.affiliationЛьвівський національний університет ім. Івана Франка
dc.contributor.affiliationНаціональний університет “Львівська політехніка”
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.affiliationIvan Franko National University of Lviv
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.authorКостюк, Р. Р.
dc.contributor.authorГорак, Ю. І.
dc.contributor.authorСобечко, І. Б.
dc.contributor.authorKostiuk, R. R.
dc.contributor.authorHorak, Yu. I.
dc.contributor.authorSobechko, I. B.
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2026-01-15T13:53:21Z
dc.date.created2024-10-10
dc.date.issued2024-10-10
dc.description.abstractЗа температурною залежністю розчинності 2-метил-5-феніл-1-(-4-метилфеніл)- пірол-3-карбонової кислоти в бутан-1-олі, бутан-2-олі, пропан-1-олі, пропан-2-олі розраховано значення ентальпії та ентропії їх розчинення. Встановлено характер взаємодії розчиненої речовини та гідроксильних розчинників. Наведено температурні залежності розчинності 2-метил-5-феніл-1-(-4-метилфеніл)-пірол-3-карбонової кислоти в спиртах. З урахуванням ентальпії та ентропії плавлення, перерахованої до 298,15 К, обчислено ентальпії та ентропії змішування.
dc.description.abstractBased on the temperature dependence of the solubility of 2-methyl-5-phenyl-1-(-4-methylphenyl)- pyrrole-3-carboxylic acid in 1-butanol, 2-butanol, 1-propanol, and 2-propanol, the enthalpy and entropy of their dissolution were calculated. Taking into account the enthalpy and entropy of melting recalculated to 298.15 K, the enthalpies and entropies of mixing were calculated.
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dc.identifier.citationКостюк Р. Р. Термодинамічні параметри розчину 2-метил-5-феніл-1-(-4-метилфеніл)-пірол-3-карбонової кислоти у спиртах / Р. Р. Костюк, Ю. І. Горак, І. Б. Собечко // Chemistry, Technology and Application of Substances. — Львів : Видавництво Львівської політехніки, 2024. — Том 7. — № 2. — С. 1–6.
dc.identifier.citation2015Костюк Р. Р., Собечко І. Б. Термодинамічні параметри розчину 2-метил-5-феніл-1-(-4-метилфеніл)-пірол-3-карбонової кислоти у спиртах // Chemistry, Technology and Application of Substances, Львів. 2024. Том 7. № 2. С. 1–6.
dc.identifier.citationenAPAKostiuk, R. R., Horak, Yu. I., & Sobechko, I. B. (2024). Termodynamichni parametry rozchynu 2-metyl-5-fenil-1-(-4-metylfenil)-pirol-3-karbonovoi kysloty u spyrtakh [Thermodynamic parameters of a solution of 2-methyl-5-phenyl-1-(-4-methylphenyl)-pyrrole-3-carboxylic acid in alcohols]. Chemistry, Technology and Application of Substances, 7(2), 1-6. Lviv Politechnic Publishing House. [in Ukrainian].
dc.identifier.citationenCHICAGOKostiuk R. R., Horak Yu. I., Sobechko I. B. (2024) Termodynamichni parametry rozchynu 2-metyl-5-fenil-1-(-4-metylfenil)-pirol-3-karbonovoi kysloty u spyrtakh [Thermodynamic parameters of a solution of 2-methyl-5-phenyl-1-(-4-methylphenyl)-pyrrole-3-carboxylic acid in alcohols]. Chemistry, Technology and Application of Substances (Lviv), vol. 7, no 2, pp. 1-6 [in Ukrainian].
dc.identifier.doihttps://doi.org/10.23939/ctas2024.02.001
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/124436
dc.language.isouk
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry, Technology and Application of Substances, 2 (7), 2024
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dc.relation.referencesen2. Santos, A. F. L. O.M., &Ribeiro da Silva,M. A. V. (2013). Molecular energetics of alkyl pyrrolecarboxylates: Calorimetric and computational study. Journal of Physical Chemistry A, 117(24), 5195–5204. https://doi.org/10.1021/jp4032628
dc.relation.referencesen3. Santos, A. F. L. O. M., & Ribeiro da Silva, M. A. V. (2014). Experimental and high level ab initio enthalpies of formation of di-, tri-, tetra-, and pentamethyl- substituted pyrroles. The Journal of Chemical Thermodynamics, 75, 1–7. https://doi.org/10.1016/j.jct.2014.04.003
dc.relation.referencesen4. Santos, A. F. L. O. M., & Ribeiro da Silva, M. A. V. (2010). Calorimetric and computational study of the thermochemistry of halogenated 1- phenylpyrrole derivatives. The Journal of Chemical Thermodynamics, 42(12), 1441–1450. https://doi.org/10.1016/j.jct.2010.06.012
dc.relation.referencesen5. Ivan, B.-C., Barbuceanu, S.-F., Hotnog, C. M., Anghel, A. I., Ancuceanu, R. V., Mihaila, M. A., Brasoveanu, L. I., Shova, S., Draghici, C., Olaru, O. T., Nitulescu, G. M., Dinu, M., & Dumitrascu, F. (2022). New pyrrole derivatives as promising biological agents: Design, synthesis, characterization, in silico, and cytotoxicity evaluation. International Journal of Molecular Sciences, 23(16), 8854. https://doi.org/10.3390/ijms23168854
dc.relation.referencesen6. Du, C. (2022). The solubility of ethyl candesartan in mono solvents and investigation of intermolecular interactions. Liquids, 2(4), 404–412. https://doi.org/10.3390/liquids2040023
dc.relation.referencesen7. Li, Z., Guo, J., Hu, B., Zhou, C., Zheng, Y., Zhao, H., & Li, Q. (2022). Solubility measurement, modeling, and solvent effect of m-hydroxyacetophenone in ten pure and binary mixed solvents from T = (289.15–325.15) K. Journal of Molecular Liquids, 353, 118798. https://doi.org/10.1016/j.molliq.2022.118798
dc.relation.referencesen8. Maharana, A., & Sarkar, D. (2019). Solubility measurements and thermodynamic modeling of pyrazinamide in five different solvent-antisolvent mixtures. Fluid Phase Equilibria, 497, 33–54. https://doi.org/10.1016/j.fluid.2019.06.004
dc.relation.referencesen9. Huang, W., Wang, H., Li, C., Wen, T., Xu, J., Ouyang, J., & Zhang, C. (2021). Measurement and correlation of solubility, Hansen solubility parameters and thermodynamic behavior of clozapine in eleven mono-solvents. Journal of Molecular Liquids, 333,115894. https://doi.org/10.1016/j.molliq.2021.115894
dc.relation.referencesen10. Wu, Y., Zhang, X., Di, Y., & Zhang, Y.(2017). Solubility determination and modelling of 4- nitro-1,2-phenylenediamine in eleven organic solvents from T = (283.15 to 318.15) K and thermodynamic properties of solutions. The Journal of Chemical Thermodynamics, 106, 22–35. https://doi.org/10.1016/j.jct.2016.11.014
dc.relation.referencesen11. Li, X., Wang, M., Du, C., Cong, Y., & Zhao, H. (2017). Thermodynamic functions for solubility of 3- nitro-o-toluic acid in nine organic solvents from T =(283.15 to 318.15) K and apparent thermodynamic properties of solutions. The Journal of Chemical Thermodynamics, 110, 87–98.https://doi.org/10.1016/j.jct.2017.02.017
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dc.relation.urihttps://doi.org/10.1021/jp911323c
dc.relation.urihttps://doi.org/10.1021/jp4032628
dc.relation.urihttps://doi.org/10.1016/j.jct.2014.04.003
dc.relation.urihttps://doi.org/10.1016/j.jct.2010.06.012
dc.relation.urihttps://doi.org/10.3390/ijms23168854
dc.relation.urihttps://doi.org/10.3390/liquids2040023
dc.relation.urihttps://doi.org/10.1016/j.molliq.2022.118798
dc.relation.urihttps://doi.org/10.1016/j.fluid.2019.06.004
dc.relation.urihttps://doi.org/10.1016/j.molliq.2021.115894
dc.relation.urihttps://doi.org/10.1016/j.jct.2016.11.014
dc.relation.urihttps://doi.org/10.1016/j.jct.2017.02.017
dc.relation.urihttps://doi.org/10.17721/fujcv7i2p1-8
dc.rights.holder© Національний університет „Львівська політехніка“, 2024
dc.subjectрозчинність
dc.subjectентальпія розчинення
dc.subjectентальпія змішування
dc.subjectентальпія плавлення
dc.subject2-метил-5-феніл-1-(-4-метилфеніл)-пірол-3-карбонова кислота
dc.subjectбутан-2-ол
dc.subjectбутан-1-ол
dc.subjectпропан-1-ол
dc.subjectпропан-2-ол
dc.subjectsolubility
dc.subjectenthalpy of dissolution
dc.subjectenthalpy of mixing
dc.subjectenthalpy of melting
dc.subject2-methyl-5-phenyl-1-(-4-methylphenyl)-pyrrole-3-carboxylic acid
dc.subject1-butanol
dc.subject2-butanol
dc.subject1-propanol
dc.subject2-propanol
dc.titleТермодинамічні параметри розчину 2-метил-5-феніл-1-(-4-метилфеніл)-пірол-3-карбонової кислоти у спиртах
dc.title.alternativeThermodynamic parameters of a solution of 2-methyl-5-phenyl-1-(-4-methylphenyl)-pyrrole-3-carboxylic acid in alcohols
dc.typeArticle

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Chemistry, Technology and Application of Substances. – 2024. – Vol. 7, No. 2