Catalysts of aldol condensation of acetic acid with formaldehyde

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dc.citation.conference7th International youth science forum «Litteris et Artibus»
dc.citation.epage77
dc.citation.journalTitleLitteris et Artibus : матеріали
dc.citation.spage76
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.affiliationInstitute for Sorption and Problems of Endoecology of NAS of Ukraine
dc.contributor.authorShpyrka, Iryna
dc.contributor.authorNebesnyi, Roman
dc.contributor.authorSydorchuk, Volodymyr
dc.contributor.authorKhalameida, Svitlana
dc.contributor.authorIvasiv, Volodymyr
dc.contributor.authorZavalii, Kateryna
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.coverage.temporal23–25 листопада 2017 року
dc.coverage.temporal23–25 November, 2017
dc.date.accessioned2018-04-12T13:06:21Z
dc.date.available2018-04-12T13:06:21Z
dc.date.created2017-12-23
dc.date.issued2017-12-23
dc.description.abstractIt had been demonstrated that mechanochemical and hydrothermal treatment of support allows increasing activity and selectivity of the catalyst in the studied process. Hydrothermal treatment (HTT) of silica increases mechanical strength of silica gel granules subjected to hydrothermal treatment, also reduction of coke formation takes place, as well as prolongation of the catalysts life. Similarly, the same approaches allow to optimize the pore structure of titanium phosphates.
dc.format.extent76-77
dc.format.pages2
dc.identifier.citationCatalysts of aldol condensation of acetic acid with formaldehyde / Iryna Shpyrka, Roman Nebesnyi, Volodymyr Sydorchuk, Svitlana Khalameida, Volodymyr Ivasiv, Kateryna Zavalii // Litteris et Artibus : proceedings, 23–25 November, 2017. — Lviv : Lviv Polytechnic Publishing House, 2017. — P. 76–77. — (6th International academic conference «Chemistry & chemical technology 2017» (CCT-2017)).
dc.identifier.citationenCatalysts of aldol condensation of acetic acid with formaldehyde / Iryna Shpyrka, Roman Nebesnyi, Volodymyr Sydorchuk, Svitlana Khalameida, Volodymyr Ivasiv, Kateryna Zavalii // Litteris et Artibus : proceedings, 23–25 November, 2017. — Lviv : Lviv Polytechnic Publishing House, 2017. — P. 76–77. — (6th International academic conference «Chemistry & chemical technology 2017» (CCT-2017)).
dc.identifier.isbn978-966-941-108-2
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/40478
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Polytechnic Publishing House
dc.relation.ispartofLitteris et Artibus : матеріали, 2017
dc.relation.ispartofLitteris et Artibus : proceedings, 2017
dc.relation.references[1] H. Danner, M. Ürmös, M. Gartner, R. Braun, “Biotechnological Production of Acrylic Acid from Biomass”, Applied Biochemistry and Biotechnology, vol. 70, pp. 887-894, 2008,doi:10.1007/BF02920199.
dc.relation.references[2] Cuncun Zuo, Yaping Li, Chunshan Li, Shasha Cao, Haoyu Yao, Suojiang Zhang, “Thermodynamics and separation process for quaternary acrylic systems”, AlChE J., 62, 228–240, 2015, doi:10.1002/aic.15015.
dc.relation.references[3] Valentina T.Shashkova, Irina A.Matveeva, Nikolay N.Glagolev, Tatyana S.Zarkhina, Anastasiya V.Cherkasova, Svetlana L.Kotova, Peter S.Timashev, Anna B.Solovieva, “Synthesis of polylactide acrylate derivatives for the preparation of 3D structures by photo-curing”. Mendeleev Communications, , vol. 26, pp. 418-420, 2016doi: 10.1016/j.mencom.2016.09.018.
dc.relation.references[4] Killian Flégeau, Richard Pace, HélèneGautier, Gildas Rethore, Jerome Guicheux, Catherine Le Visage, PierreWeiss, “Toward the development of biomimetic injectable and macroporous biohydrogels for regenerative medicine”, Advances in Colloid and Interface Science, 2017,doi: 10.1016/j.cis.2017.07.012.
dc.relation.references[5] X. Li, Y. Zhang, “Highly Efficient Process for the Conversion of Glycerol to Acrylic Acid via Gas Phase Catalytic Oxidation of an Allyl Alcohol Intermediate”, ACS Catalysis, vol. 6, pp. 143-150, 2016, doi: 10.1021/acscatal.5b01843.
dc.relation.references[6] Zhyznevs'kyy V.M., Nebesnyy R.V., Ivasiv V.V., S. V. Shybanov. “Obtaining of acrylic monomers by gas-phased catalytic condensation of carbonyl compounds in gas phase”, Reports of NAS Ukraine, vol. 10, pp. 114–118, 2010.
dc.relation.references[7] Patent 0343319 US, Process for preparing acrylic acid with high space-time ield / M. Goebel // BASF SE., filing date: 18.05.2013; publication date: 08.04.2014.
dc.relation.references[8] R.V. Nebesnyi, V.V. Ivasiv, V.M. Zhyznevskyy, S.V. Shybanov, S.V. Maykova, “Condensation of acetic acid with formaldehyde to acrylic acid over B-P-Mo-Cs-Ox catalysts in the gas phase”, Visnyk NU ”LP” “Chemistry, technology of substances and their applications”, no 667, pp. 196-199, 2010.
dc.relation.references[9] R. Nebesnyi, V. Ivasiv, Y. Dmytruk, N. Lapychak, “Acrylic acid obtaining by acetic acid catalytic condensation with formaldehyde”, Eastern- European Journal of Enterprise Technologies, Vol. 6, no 6(66), pp. 40-42, 2013.
dc.relation.references[10] V.V. Ivasiv, Z.G. Pikh, V.M. Zhyznevskyy, R.V. Nebesnyi, “Physical-chemical properties of surface of B2O3 – P2O5 – МеOх/SiO2 catalysts and their influence on parameters of propionic acid aldol condensation with formaldehyde”, Reports of NASc of Ukraine, no. 11, pp. 126-130, 2011.
dc.relation.references[11] E. Skwarek, S. Khalameida, W. Janusz, V. Sydorchuk, N. Konovalova, V. Zazhigalov, J. Skubiszewska- Zięba, R. Leboda Influence of mechanochemical activation on structure and some properties of mixed vanadium-molybdenum oxides. Journal of Thermal Analysis and Calorimetry, vol.106, no3, pp.881-894, 2011.
dc.relation.references[12] J. Skubiszewska-Zieba, S. Khalameida, V. Sydorchuk. Comparison of surface properties of silica xero- and hydrogels hydrothermally modified using mechanochemical, microwave and classical methods. Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 504, pp. 139-153, 2016.
dc.relation.referencesen[1] H. Danner, M. Ürmös, M. Gartner, R. Braun, "Biotechnological Production of Acrylic Acid from Biomass", Applied Biochemistry and Biotechnology, vol. 70, pp. 887-894, 2008,doi:10.1007/BF02920199.
dc.relation.referencesen[2] Cuncun Zuo, Yaping Li, Chunshan Li, Shasha Cao, Haoyu Yao, Suojiang Zhang, "Thermodynamics and separation process for quaternary acrylic systems", AlChE J., 62, 228–240, 2015, doi:10.1002/aic.15015.
dc.relation.referencesen[3] Valentina T.Shashkova, Irina A.Matveeva, Nikolay N.Glagolev, Tatyana S.Zarkhina, Anastasiya V.Cherkasova, Svetlana L.Kotova, Peter S.Timashev, Anna B.Solovieva, "Synthesis of polylactide acrylate derivatives for the preparation of 3D structures by photo-curing". Mendeleev Communications, , vol. 26, pp. 418-420, 2016doi: 10.1016/j.mencom.2016.09.018.
dc.relation.referencesen[4] Killian Flégeau, Richard Pace, HélèneGautier, Gildas Rethore, Jerome Guicheux, Catherine Le Visage, PierreWeiss, "Toward the development of biomimetic injectable and macroporous biohydrogels for regenerative medicine", Advances in Colloid and Interface Science, 2017,doi: 10.1016/j.cis.2017.07.012.
dc.relation.referencesen[5] X. Li, Y. Zhang, "Highly Efficient Process for the Conversion of Glycerol to Acrylic Acid via Gas Phase Catalytic Oxidation of an Allyl Alcohol Intermediate", ACS Catalysis, vol. 6, pp. 143-150, 2016, doi: 10.1021/acscatal.5b01843.
dc.relation.referencesen[6] Zhyznevs'kyy V.M., Nebesnyy R.V., Ivasiv V.V., S. V. Shybanov. "Obtaining of acrylic monomers by gas-phased catalytic condensation of carbonyl compounds in gas phase", Reports of NAS Ukraine, vol. 10, pp. 114–118, 2010.
dc.relation.referencesen[7] Patent 0343319 US, Process for preparing acrylic acid with high space-time ield, M. Goebel, BASF SE., filing date: 18.05.2013; publication date: 08.04.2014.
dc.relation.referencesen[8] R.V. Nebesnyi, V.V. Ivasiv, V.M. Zhyznevskyy, S.V. Shybanov, S.V. Maykova, "Condensation of acetic acid with formaldehyde to acrylic acid over B-P-Mo-Cs-Ox catalysts in the gas phase", Visnyk NU "LP" "Chemistry, technology of substances and their applications", no 667, pp. 196-199, 2010.
dc.relation.referencesen[9] R. Nebesnyi, V. Ivasiv, Y. Dmytruk, N. Lapychak, "Acrylic acid obtaining by acetic acid catalytic condensation with formaldehyde", Eastern- European Journal of Enterprise Technologies, Vol. 6, no 6(66), pp. 40-42, 2013.
dc.relation.referencesen[10] V.V. Ivasiv, Z.G. Pikh, V.M. Zhyznevskyy, R.V. Nebesnyi, "Physical-chemical properties of surface of B2O3 – P2O5 – MeOkh/SiO2 catalysts and their influence on parameters of propionic acid aldol condensation with formaldehyde", Reports of NASc of Ukraine, no. 11, pp. 126-130, 2011.
dc.relation.referencesen[11] E. Skwarek, S. Khalameida, W. Janusz, V. Sydorchuk, N. Konovalova, V. Zazhigalov, J. Skubiszewska- Zięba, R. Leboda Influence of mechanochemical activation on structure and some properties of mixed vanadium-molybdenum oxides. Journal of Thermal Analysis and Calorimetry, vol.106, no3, pp.881-894, 2011.
dc.relation.referencesen[12] J. Skubiszewska-Zieba, S. Khalameida, V. Sydorchuk. Comparison of surface properties of silica xero- and hydrogels hydrothermally modified using mechanochemical, microwave and classical methods. Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 504, pp. 139-153, 2016.
dc.rights.holder© Національний університет “Львівська політехніка”, 2017
dc.subjectacrylic acid
dc.subjectaldol condensation
dc.subjectmechanochemical treatment
dc.subjecthydrothermal treatment
dc.subjectporous structure
dc.titleCatalysts of aldol condensation of acetic acid with formaldehyde
dc.typeConference Abstract

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