Spectroscopy of gadolinium gallium garnet doped with cerium under high hydrostatic pressure

dc.contributor.authorKaminska, A.
dc.contributor.authorDuzynska, A.
dc.contributor.authorBerkowski, M.
dc.contributor.authorSuchocki, A.
dc.date.accessioned2012-10-16T06:36:04Z
dc.date.available2012-10-16T06:36:04Z
dc.date.issued2012
dc.description.abstractStudies of the spectroscopic properties of Ce3+ dopant in bulk Gd3Ga5O12:Ce crystal under pressure are presented. In spite of strong inter-shell 4f ® 5d absorption bands at ambient pressure the cerium luminescence in Gd3Ga5O12 is entirely quenched even at low temperature. It has been shown that applying pressure allows for recovering the 5d ® 4f radiative transitions. Further increase of pressure improves the emission efficiency. This effect is analyzed in terms of two possible phenomena: (i) by pressure-induced electronic crossover of the excited 5d energy level of the Ce3+ with the conduction band bottom of host crystal, and (ii) by decrease of electron-lattice coupling with increasing pressure, resulting in reducing of Stokes shift and non-radiative transitions between the low vibrational levels of the 5d state and high vibrational levels of the ground 4f state.uk_UA
dc.identifier.citationSpectroscopy of gadolinium gallium garnet doped with cerium under high hydrostatic pressure / A. Kaminska, A. Duzynska, M. Berkowsk, A. Suchocki // Оксидні матеріали електронної техніки – отримання, властивості, застосування (ОМЕЕ – 2012) : збірник матеріалів міжнародної наукової конференції, 3-7 вересня 2012 року, Львів, Україна / Національний університет “Львівська політехніка”. – Львів : Видавництво Львівської політехніки, 2012. – С. 198–199. – Bibliography: 24 titles.uk_UA
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/15299
dc.language.isoenuk_UA
dc.publisherВидавництво Львівської політехнікиuk_UA
dc.subjectGd3Ga5O12:Ce3+ crystalsuk_UA
dc.subjectluminescence and absorption under high pressureuk_UA
dc.subjectelectron-lattice couplinguk_UA
dc.titleSpectroscopy of gadolinium gallium garnet doped with cerium under high hydrostatic pressureuk_UA
dc.typeArticleuk_UA

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