Технологічні особливості отримання та властивості прищеплених полівінілпірролідонових кополімерів

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dc.citation.epage216
dc.citation.issue2
dc.citation.spage210
dc.contributor.affiliationНаціональний університет “Львівська політехніка”
dc.contributor.affiliationЛьвівський державний університет безпеки життєдіяльності
dc.contributor.affiliationЛюблінський католицький університет імені Івана Павла ІІ
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.affiliationLviv State University of Life Safety
dc.contributor.affiliationThe John Paul II Catholic University of Lublin
dc.contributor.authorЗемке, В. М.
dc.contributor.authorЧопик, Н. В.
dc.contributor.authorХром’як, У. В.
dc.contributor.authorЛевицький, В. Є.
dc.contributor.authorZemke, V. M.
dc.contributor.authorChopyk, N. V.
dc.contributor.authorKhromyak, U. V.
dc.contributor.authorLevytskyi, V. Ye.
dc.coverage.placenameLviv
dc.coverage.placenameLviv
dc.date.accessioned2024-01-22T08:47:16Z
dc.date.available2024-01-22T08:47:16Z
dc.date.created2020-03-16
dc.date.issued2020-03-16
dc.description.abstractДосліджено вплив природи, концентрації та температури на кінетику дисперсійної полімеризації у присутності полівінілпіролідону. Визначено оптимальні технологічні параметри процесу синтезу кополімеру. Визначено, що властивості дисперсійної полімеризації залежать від умов процесу. Такими умовами є температура, співвідношення мономеру та водної фази, концентрації мономеру та ініціатора, а також кількість полівінілпіролідону. Наведені матеріали, отримані на основі розроблених композицій, характеризуються принципово високими робочими та фізико-механічними властивостями.
dc.description.abstractThe impact of the vinyl monomers nature, concentration, and temperature on the kinetics of dispersion polymerization in the presence of polyvinylpyrrolidone was studied. The optimal technological parameters of the copolymer synthesis process are determined. It is defined that the properties of dispersion polymerization depend on the process conditions. Such conditions are temperature, monomer and aqueous phase ratio, monomer and initiator concentrations and as well as the amount of polyvinylpyrrolidone. Presented materials derived on the ground of the developed compositions are characterized by principally high working and physical-mechanical properties.
dc.format.extent210-216
dc.format.pages7
dc.identifier.citationТехнологічні особливості отримання та властивості прищеплених полівінілпірролідонових кополімерів / В. М. Земке, Н. В. Чопик, У. В. Хром’як, В. Є. Левицький // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2021. — Том 4. — № 2. — С. 210–216.
dc.identifier.citationenTechnological features of obtaining and properties of grafted polyvinylpyrrolidone copolymers / V. M. Zemke, N. V. Chopyk, U. V. Khromyak, V. Ye. Levytskyi // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2021. — Vol 4. — No 2. — P. 210–216.
dc.identifier.doidoi.org/10.23939/ctas2021.02.210
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/60899
dc.language.isouk
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry, Technology and Application of Substances, 2 (4), 2021
dc.relation.references1. Long A. C. (2007) Composites forming technologies. Cambridge: Woodhead Publishing House, 344.
dc.relation.references2. Rakesh K. Gupta, Elliot Kennel, Kwang-Jea Kim (2009). Polymer Nanocomposites Handbook. Cambridge: CRC Press.
dc.relation.references3. K. Chen-Yu, L. Tzu-Chiang, L. Wen-Chie (2203) Influence of polyvinylpyrrolidone on the hydrophobic properties of partially porous poly(styrenedivinylbenzene) particles for biological applications / J. Appl. Polym. Sci. 87 (11), 1818–1824.
dc.relation.references4. Bianco Gilmene, Gehlen Marcelo H. (2002) Synthesis of poly(N-vinyl-2-pyrrolidone) and copolymers with methacrylic acid initiated by the photo-Fenton reaction. J. Photochem. and Photobiol. 13, 115–119.
dc.relation.references5. Novikov M. B., Roos A., Creton C. (2003) Dynamic mechanical and tensile properties of poly(Nvinylpyrrolidone)– poly(ethyleneglycol) blends / Polymer, (44) 12, 3561–3578.
dc.relation.references6. Feldstein M. M.,. Shandryuk N. A. Plate N. A (2001) Relation of glass transition temperature to the hydrogen-bonding degree and energy in poly(Nvinylpyrrolidone) blends with hydroxyl-containing plasticizers. Part 1. Effects ofhydroxyl group number in plasticizer molecule / Polymer. 42 (3), P. 971–979.
dc.relation.references7. Feldstein M. M., Shandryuk G. A.,. Kuptsov S. A., Plate N. A. (2000) Coherence of thermal transitions in poly(N-vinylpyrrolidone) – poly(ethyleneglycol) compatible blends 3. Impact of sorbed water upon phase behaviour / Polymer. 41 (14), 5349–5359.
dc.relation.references8. Kuo S. W., Chang F. C. (2001) Studies of miscibility behavior and hydrogen bonding in blends of poly(vinylphenol) and poly(vinylpyrrolidone) / Macromolecules.34 (15), 5224–5228.
dc.relation.references9. Trong N. Q. Loic L. B., Jean N. (1985) Preparation of membranes from polyacrylonitrilpolyvinylpyrrolidone blends and the study of their behaviour in the pervaporation of water-organic liquid mixtures / J. Membr. Sci. – 85 (22), 245–255.
dc.relation.references10. Khromiak U., Levytskyi V., Stepova K., Tarnawsky A. (2018) Synthesis and properties of adhesive polymer-methylmethacrylate materials / International Journal of Polymer Science, 1-9. https://doi.org/10.1155/2018/4905304.
dc.relation.references11. Zaccaron C. M., Oliveira R. V., Guiotoku M. (2005) Blends of hydroxypropyl methylcellulose and poly(l-vinylpyrrolidone-co-vinyl acetate): miscibility and thermal stability / Polym. Degrad. and Stab. – 90 (1), 21–27.
dc.relation.references12. Khromyak U. V., Levytskyi V. Ye., Stepova K. V., Skorokhoda V. Y. (2018) Synthesis and properties of composites based on copolymers of polyvinylpyrrolidone and methylmethacrylate / Voprosy Khimii i Khimicheskoi Tekhnologii 4, 135-141. DOI: 10.1037/aca0000211 http://oaji.net/articles/2017/1954-1531896702.pdf
dc.relation.references13. Levytskyi Volodymyr, Khromiak Ulyana, Skorokhoda Volodymyr, Levytska Khrystyna,MelnykYurii (2018) Technological aspects of obtaining and properties of polyvinylpyrrolidone copolymers and composites; Technological and design aspects of the processing of composites and nanocomposites. Monography, Vol. I: [Ed.]: SikoraJanusz, DulebováĽudmila. Košice: TechnicalUniversityofKošice, 162–174. ISBN 978-80-553-2773-0.
dc.relation.referencesen1. Long A. C. (2007) Composites forming technologies. Cambridge: Woodhead Publishing House, 344.
dc.relation.referencesen2. Rakesh K. Gupta, Elliot Kennel, Kwang-Jea Kim (2009). Polymer Nanocomposites Handbook. Cambridge: CRC Press.
dc.relation.referencesen3. K. Chen-Yu, L. Tzu-Chiang, L. Wen-Chie (2203) Influence of polyvinylpyrrolidone on the hydrophobic properties of partially porous poly(styrenedivinylbenzene) particles for biological applications, J. Appl. Polym. Sci. 87 (11), 1818–1824.
dc.relation.referencesen4. Bianco Gilmene, Gehlen Marcelo H. (2002) Synthesis of poly(N-vinyl-2-pyrrolidone) and copolymers with methacrylic acid initiated by the photo-Fenton reaction. J. Photochem. and Photobiol. 13, 115–119.
dc.relation.referencesen5. Novikov M. B., Roos A., Creton C. (2003) Dynamic mechanical and tensile properties of poly(Nvinylpyrrolidone)– poly(ethyleneglycol) blends, Polymer, (44) 12, 3561–3578.
dc.relation.referencesen6. Feldstein M. M.,. Shandryuk N. A. Plate N. A (2001) Relation of glass transition temperature to the hydrogen-bonding degree and energy in poly(Nvinylpyrrolidone) blends with hydroxyl-containing plasticizers. Part 1. Effects ofhydroxyl group number in plasticizer molecule, Polymer. 42 (3), P. 971–979.
dc.relation.referencesen7. Feldstein M. M., Shandryuk G. A.,. Kuptsov S. A., Plate N. A. (2000) Coherence of thermal transitions in poly(N-vinylpyrrolidone) – poly(ethyleneglycol) compatible blends 3. Impact of sorbed water upon phase behaviour, Polymer. 41 (14), 5349–5359.
dc.relation.referencesen8. Kuo S. W., Chang F. C. (2001) Studies of miscibility behavior and hydrogen bonding in blends of poly(vinylphenol) and poly(vinylpyrrolidone), Macromolecules.34 (15), 5224–5228.
dc.relation.referencesen9. Trong N. Q. Loic L. B., Jean N. (1985) Preparation of membranes from polyacrylonitrilpolyvinylpyrrolidone blends and the study of their behaviour in the pervaporation of water-organic liquid mixtures, J. Membr. Sci, 85 (22), 245–255.
dc.relation.referencesen10. Khromiak U., Levytskyi V., Stepova K., Tarnawsky A. (2018) Synthesis and properties of adhesive polymer-methylmethacrylate materials, International Journal of Polymer Science, 1-9. https://doi.org/10.1155/2018/4905304.
dc.relation.referencesen11. Zaccaron C. M., Oliveira R. V., Guiotoku M. (2005) Blends of hydroxypropyl methylcellulose and poly(l-vinylpyrrolidone-co-vinyl acetate): miscibility and thermal stability, Polym. Degrad. and Stab, 90 (1), 21–27.
dc.relation.referencesen12. Khromyak U. V., Levytskyi V. Ye., Stepova K. V., Skorokhoda V. Y. (2018) Synthesis and properties of composites based on copolymers of polyvinylpyrrolidone and methylmethacrylate, Voprosy Khimii i Khimicheskoi Tekhnologii 4, 135-141. DOI: 10.1037/aca0000211 http://oaji.net/articles/2017/1954-1531896702.pdf
dc.relation.referencesen13. Levytskyi Volodymyr, Khromiak Ulyana, Skorokhoda Volodymyr, Levytska Khrystyna,MelnykYurii (2018) Technological aspects of obtaining and properties of polyvinylpyrrolidone copolymers and composites; Technological and design aspects of the processing of composites and nanocomposites. Monography, Vol. I: [Ed.]: SikoraJanusz, DulebováĽudmila. Košice: TechnicalUniversityofKošice, 162–174. ISBN 978-80-553-2773-0.
dc.relation.urihttps://doi.org/10.1155/2018/4905304
dc.relation.urihttp://oaji.net/articles/2017/1954-1531896702.pdf
dc.rights.holder© Національний університет “Львівська політехніка”, 2021
dc.subjectводна фаза
dc.subjectметилметакрилат
dc.subjectкополімер
dc.subjectполівінілпіролідон
dc.subjectдисперсійна полімеризація
dc.subjectвінілові мономери
dc.subjectaqueous phase
dc.subjectmethylmethacrylate
dc.subjectcopolymer
dc.subjectpolyvinylpyrrolidone
dc.subjectdispersion polymerization
dc.subjectvinyl monomers
dc.titleТехнологічні особливості отримання та властивості прищеплених полівінілпірролідонових кополімерів
dc.title.alternativeTechnological features of obtaining and properties of grafted polyvinylpyrrolidone copolymers
dc.typeArticle

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Chemistry, Technology and Application of Substances. – 2021. – Vol. 4, No. 2