Використання перфторованих сульфамідів у процесі окиснення циклогексану

Simple item page
dc.citation.epage68
dc.citation.issue1
dc.citation.journalTitleХімія, технологія речовин та їх застосування
dc.citation.spage60
dc.citation.volume6
dc.contributor.affiliationНаціональний університет “Львівська політехніка”
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.authorРеутський, В. В.
dc.contributor.authorЛудин, А. М.
dc.contributor.authorReutskyy, V. V.
dc.contributor.authorLudyn, A. M.
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2024-02-09T09:24:36Z
dc.date.available2024-02-09T09:24:36Z
dc.date.created2023-02-28
dc.date.issued2023-02-28
dc.description.abstractРозглянуто шляхи використання перфторованих сульфамідів у різних технологічних процесах. Досліджено можливість використання амінатоксану як каталізатора в процесі окиснення циклогексану. Вивчено різні технологічні параметри використання бінарної каталітичної системи: нафтенат кобальту – амінатоксан у процесі окиснення циклогексану та вплив їх на основні показники даного процесу. Визначено позитивний вплив перфторованих сульфамідів у складі бінарних систем із нафтенатом кобальту на їх каталітичну активність у процесі окиснення циклогексану.
dc.description.abstractWays of using perfluorinated sulfonamides in various technological processes are considered. The possibility of using aminotoxane as a catalyst in the process of cyclohexane oxidation was studied. Various technological parameters of the use of the binary catalytic system: cobalt naphthenate – aminotoxane in the process of cyclohexane oxidation and their influence on the main indicators of this process were studied. The positive influence of perfluorinated sulfamides in binary systems with cobalt naphthenate on their catalytic activity in the process of cyclohexane oxidation was determined.
dc.format.extent60-68
dc.format.pages9
dc.identifier.citationРеутський В. В. Використання перфторованих сульфамідів у процесі окиснення циклогексану / В. В. Реутський, А. М. Лудин // Хімія, технологія речовин та їх застосування. — Львів : Видавництво Львівської політехніки, 2023. — Том 6. — № 1. — С. 60–68.
dc.identifier.citationenReutskyy V. V. Perfluorinated sulfamides in the oxidation process of cyclohexane / V. V. Reutskyy, A. M. Ludyn // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2023. — Vol 6. — No 1. — P. 60–68.
dc.identifier.doidoi.org/10.23939/ctas2023.01.060
dc.identifier.issn2617-7307
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/61172
dc.language.isouk
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofХімія, технологія речовин та їх застосування, 1 (6), 2023
dc.relation.ispartofChemistry, Technology and Application of Substances, 1 (6), 2023
dc.relation.references1. Hoff, P. T., Scheirs, J., Van de Vijver, K., Van Dongen, W., Esmans, E. L., Blust, R., De Coen, W. (2004). Biochemical Effect Evaluation of Perfluoroctane Sulfonic Acid-Contaminated Wood Mice. Environmental Health Perspectives, 112 (6), 681 – 686. doi: 10.1289/ehp.6479.
dc.relation.references2. Olsen, G. W., Church, T. R., Larson, E. B., van Belle G., Lundberg, J. K., Hansen, K. J., Burris, J. M., Mandel, J. H., Zobel, L. R. (2004). Serum concentrations of perfluorooctanesulfonate and other fluorochemicals in an elderly population from Seattle, Washington. Chemosphere, 54 (11), 1599–611. doi:10.1016/j.chemosphere.2003.09.025.
dc.relation.references3. Lehmler, H. J. (2005). Synthesis of environmentally relevant fluorinated surfactantsa review. Chemosphere, 58 (11), 1471–96. doi:10.1016/j.chemosphere.2004.11.078. PMID 15694468".
dc.relation.references4. Olsen, G. W., Church, T. R., Miller, J. P., et al. (2003). Perfluorooctanesulfonate and other fluorochemicals in the serum of American Red Cross adult blood donors. Environ. Health Perspect, 111 (16), 1892–901. doi:10.1289/ehp.6316].
dc.relation.references5. Grossman, M. R., Mispagel, M. E., Bowen, J. M. (1992). Distribution and tissue elimination in rats during and after prolonged dietary exposure to a highly fluorinated sulfonamide pesticide. J. Agric. Food Chem, 40 (12). 2505. doi:10.1021/jf00024a033.
dc.relation.references6. Ankley, G. T., Kuehl, D. W., Kahl. M. D., Jensen, K. M., Linnum, A., Leino, R. L., Villeneuvet. D. A. (2005). Reproductive and developmental toxicity and bioconcentration of perfluorooctanesulfonate in a partial life-cycle test with the fathead minnow (Pimephales promelas). Environ Toxicol Chem, 24 (9), 231–624. DOI: 10.1897/04-634r.1.
dc.relation.references7. Boulanger, B., Vargo, J., Schnoor, J. L., Hornbuckle, K. C. (2004). Detection of perfluorooctane surfactants in Great Lakes water. Environ Sci Technol, 38 (15), 4064-4070. https://doi.org/10.1021/es0496975.
dc.relation.references8. Ying, Chang, Yeong-Beom, Lee, Chulsung, Bae. (2011). Partially Fluorinated Sulfonated Poly(ether amide) Fuel Cell Membranes: Influence of Chemical Structure on Membrane Properties. Polymers, 3(1), 222–235. https://doi.org/10.3390/polym301.
dc.relation.references9. Takehiko, Yamato, Jian-yong, Hu, Naoki, Shinoda. (2007). Perfluorinated sulfonic acid resin (Nafion-H) catalysed Ritter reaction of benzyl alcohols. Journal of Chemical Research, 38, 641–643. https://doi.org/10.3184/030823407X262436.
dc.relation.references10. Saferstein, Lowell, Looney, Dwayne, L. (2002). US 20070054880. Johnson and Johnson.Ethicon Inc.
dc.relation.references11. Debaprasad, Mandal, John, A. Gladysz. (2010). Syntheses of fluorous quaternary ammonium salts and their application as phase transfer catalysts for halide substitution reactions in extremely nonpolar fluorous solvents. Journals & Books-Tetrahedron, Vol. 66, Issue 5, 1070–1077. https://doi.org/10.1016/j.tet.2009.11.012.
dc.relation.references12. Iwona, B., Szymańska, K., Madajska, A., Butrymowicz, M., B. (2021). Materials, 14(23), 7451. https://doi.org/10.3390/ma14237451.
dc.relation.references13. Ludyn, А., Reutskyy, V., Reutskyy, V., Hrynchuk, Y. (2021). Influence Of Amino Acids And Alcohols On Catalytic Oxidation Of Cyclohexane. Сhemistry & Сhemical Тechnology, Vol. 15, 3, 352–358. https://doi.org/10.23939/chcht15.03.352.
dc.relation.references14. Ludyn, A.. Reutskyy, V., Reutskyy, V. (2019). Creating The Basis Of Non-exhaustive Technology Of Cyclogexan Oxidation. Chemistry, Technology and Application of Substances, Vol. 2, 2, 91–96.
dc.relation.references15. Mudryy, S., Reutskyy, V., Ivashchuk, O., Suprun, O., Ivasiv, V. (2015). Influence of Organic Additives on Catalysts of Liquid-Phase Cyclohexane Oxidation. Chemistry & Chemical Technology, Vol. 9, 1, 37–42. https://doi.org/10.23939/chcht09.01.037.
dc.relation.references16. Melnyk, Y., Melnyk, S., Starchevskyy, V., Reutskyy, V., Reutskyi, V. (2011). Catalytic oxidation of organic compounds in the presence crown-ethers. Chemical Engineering Transactions, Vol. 24, 163–168. DOI: 10.3303/CET1124028.
dc.relation.references17. Ludyn, A. M. (1994). Udoskonalenja promyslovych katalizatoriv procesu okyslenya cyclohexanу (Kandydatska dissertacija). 0495U002663. Lviv: Dergavnyj universytet ―Lvivskа politechnika.
dc.relation.referencesen1. Hoff, P. T., Scheirs, J., Van de Vijver, K., Van Dongen, W., Esmans, E. L., Blust, R., De Coen, W. (2004). Biochemical Effect Evaluation of Perfluoroctane Sulfonic Acid-Contaminated Wood Mice. Environmental Health Perspectives, 112 (6), 681 – 686. doi: 10.1289/ehp.6479.
dc.relation.referencesen2. Olsen, G. W., Church, T. R., Larson, E. B., van Belle G., Lundberg, J. K., Hansen, K. J., Burris, J. M., Mandel, J. H., Zobel, L. R. (2004). Serum concentrations of perfluorooctanesulfonate and other fluorochemicals in an elderly population from Seattle, Washington. Chemosphere, 54 (11), 1599–611. doi:10.1016/j.chemosphere.2003.09.025.
dc.relation.referencesen3. Lehmler, H. J. (2005). Synthesis of environmentally relevant fluorinated surfactantsa review. Chemosphere, 58 (11), 1471–96. doi:10.1016/j.chemosphere.2004.11.078. PMID 15694468".
dc.relation.referencesen4. Olsen, G. W., Church, T. R., Miller, J. P., et al. (2003). Perfluorooctanesulfonate and other fluorochemicals in the serum of American Red Cross adult blood donors. Environ. Health Perspect, 111 (16), 1892–901. doi:10.1289/ehp.6316].
dc.relation.referencesen5. Grossman, M. R., Mispagel, M. E., Bowen, J. M. (1992). Distribution and tissue elimination in rats during and after prolonged dietary exposure to a highly fluorinated sulfonamide pesticide. J. Agric. Food Chem, 40 (12). 2505. doi:10.1021/jf00024a033.
dc.relation.referencesen6. Ankley, G. T., Kuehl, D. W., Kahl. M. D., Jensen, K. M., Linnum, A., Leino, R. L., Villeneuvet. D. A. (2005). Reproductive and developmental toxicity and bioconcentration of perfluorooctanesulfonate in a partial life-cycle test with the fathead minnow (Pimephales promelas). Environ Toxicol Chem, 24 (9), 231–624. DOI: 10.1897/04-634r.1.
dc.relation.referencesen7. Boulanger, B., Vargo, J., Schnoor, J. L., Hornbuckle, K. C. (2004). Detection of perfluorooctane surfactants in Great Lakes water. Environ Sci Technol, 38 (15), 4064-4070. https://doi.org/10.1021/es0496975.
dc.relation.referencesen8. Ying, Chang, Yeong-Beom, Lee, Chulsung, Bae. (2011). Partially Fluorinated Sulfonated Poly(ether amide) Fuel Cell Membranes: Influence of Chemical Structure on Membrane Properties. Polymers, 3(1), 222–235. https://doi.org/10.3390/polym301.
dc.relation.referencesen9. Takehiko, Yamato, Jian-yong, Hu, Naoki, Shinoda. (2007). Perfluorinated sulfonic acid resin (Nafion-H) catalysed Ritter reaction of benzyl alcohols. Journal of Chemical Research, 38, 641–643. https://doi.org/10.3184/030823407X262436.
dc.relation.referencesen10. Saferstein, Lowell, Looney, Dwayne, L. (2002). US 20070054880. Johnson and Johnson.Ethicon Inc.
dc.relation.referencesen11. Debaprasad, Mandal, John, A. Gladysz. (2010). Syntheses of fluorous quaternary ammonium salts and their application as phase transfer catalysts for halide substitution reactions in extremely nonpolar fluorous solvents. Journals & Books-Tetrahedron, Vol. 66, Issue 5, 1070–1077. https://doi.org/10.1016/j.tet.2009.11.012.
dc.relation.referencesen12. Iwona, B., Szymańska, K., Madajska, A., Butrymowicz, M., B. (2021). Materials, 14(23), 7451. https://doi.org/10.3390/ma14237451.
dc.relation.referencesen13. Ludyn, A., Reutskyy, V., Reutskyy, V., Hrynchuk, Y. (2021). Influence Of Amino Acids And Alcohols On Catalytic Oxidation Of Cyclohexane. Shemistry & Shemical Technology, Vol. 15, 3, 352–358. https://doi.org/10.23939/chcht15.03.352.
dc.relation.referencesen14. Ludyn, A.. Reutskyy, V., Reutskyy, V. (2019). Creating The Basis Of Non-exhaustive Technology Of Cyclogexan Oxidation. Chemistry, Technology and Application of Substances, Vol. 2, 2, 91–96.
dc.relation.referencesen15. Mudryy, S., Reutskyy, V., Ivashchuk, O., Suprun, O., Ivasiv, V. (2015). Influence of Organic Additives on Catalysts of Liquid-Phase Cyclohexane Oxidation. Chemistry & Chemical Technology, Vol. 9, 1, 37–42. https://doi.org/10.23939/chcht09.01.037.
dc.relation.referencesen16. Melnyk, Y., Melnyk, S., Starchevskyy, V., Reutskyy, V., Reutskyi, V. (2011). Catalytic oxidation of organic compounds in the presence crown-ethers. Chemical Engineering Transactions, Vol. 24, 163–168. DOI: 10.3303/CET1124028.
dc.relation.referencesen17. Ludyn, A. M. (1994). Udoskonalenja promyslovych katalizatoriv procesu okyslenya cyclohexanu (Kandydatska dissertacija). 0495U002663. Lviv: Dergavnyj universytet ―Lvivska politechnika.
dc.relation.urihttps://doi.org/10.1021/es0496975
dc.relation.urihttps://doi.org/10.3390/polym301
dc.relation.urihttps://doi.org/10.3184/030823407X262436
dc.relation.urihttps://doi.org/10.1016/j.tet.2009.11.012
dc.relation.urihttps://doi.org/10.3390/ma14237451
dc.relation.urihttps://doi.org/10.23939/chcht15.03.352
dc.relation.urihttps://doi.org/10.23939/chcht09.01.037
dc.rights.holder© Національний університет “Львівська політехніка”, 2023
dc.subjectперфторовані сульфаміди
dc.subjectамінатоксан
dc.subjectциклогексан
dc.subjectокиснення
dc.subjectконверсія сировини
dc.subjectселективність за цільовими продуктами
dc.subjectнафтенат кобальту
dc.subjectperfluorinated sulfamides
dc.subjectaminotoxane
dc.subjectcyclohexane
dc.subjectoxidation
dc.subjectraw material conversion
dc.subjectselectivity for target products
dc.subjectcatalyst
dc.subjectcobalt naphthenate
dc.titleВикористання перфторованих сульфамідів у процесі окиснення циклогексану
dc.title.alternativePerfluorinated sulfamides in the oxidation process of cyclohexane
dc.typeArticle

Files

Original bundle

Now showing 1 - 2 of 2
Thumbnail Image
Name:
2023v6n1_Reutskyy_V_V-Perfluorinated_sulfamides_60-68.pdf
Size:
2.08 MB
Format:
Adobe Portable Document Format
Download
Thumbnail Image
Name:
2023v6n1_Reutskyy_V_V-Perfluorinated_sulfamides_60-68__COVER.png
Size:
493.76 KB
Format:
Portable Network Graphics
Download

License bundle

Now showing 1 - 1 of 1
No Thumbnail Available
Name:
license.txt
Size:
1.8 KB
Format:
Plain Text
Description:
Download

Collections

Chemistry, Technology and Application of Substances. – 2023. – Vol. 6, No. 1