Вивчення комплексоутворення йонів міді (II) з поліакриловою кислотою

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dc.citation.epage7
dc.citation.issue1
dc.citation.journalTitleХімія, технологія речовин та їх застосування
dc.citation.spage1
dc.citation.volume6
dc.contributor.affiliationНаціональний університет “Львівська політехніка”
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.authorОлійник, Л. П.
dc.contributor.authorOliynyk, L. P.
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2024-02-09T09:24:35Z
dc.date.available2024-02-09T09:24:35Z
dc.date.created2023-02-28
dc.date.issued2023-02-28
dc.description.abstractДосліджено процес взаємодії йонів міді з поліакриловою кислотою. Показано, що комплекси утворюються при взаємодіїї поліакрилової кислоти з йонами міді (ІІ) в широкому діапазоні pH. При рН<4 випадає осад комплексів при цьому pH розчину зростає, утворюються водорозчинні комплекси міді (ІІ) з поліакриловою кислотою. Розчинність таких комплексів залежить від кількості іонізованих карбоксильних груп макромолекули. При низьких концентраціях йонів міді (ІІ) у суміші утворюються комплекси, зв’язані з двома карбоксильними групами полікислоти. При високих концентраціях йонів міді (ІІ) один йон міді (ІІ) зв’язує лиш одну карбоксильну групу і утворюються гідроксокомплекси міді (ІІ).
dc.description.abstractThe process of interaction of copper ions with polyacrylic acid is investigated in this paper. It is shown that complexes are formed by the interaction of polyacrylic acid with copperions (II) in a wide range of pH. At pH <4 the precipitate of complexes falls, the pH of the solution increases, water-soluble copper complexes (II) with polyacrylic acid are formed. The solubility of such complexes depends on the number of ionized carboxyl groups of the macromolecule. At low concentrations of copper ions (II) in the mixture, complexes associated with two carboxyl groups of polyacids are formed. At high concentrations of copper ions (II), one ion of copper (II) binds only one carboxyl group and hydroxocomplex copper (II) is formed. It was established that the viscosity of aqueous solutions of polyacrylic acid decreases with an increase in the concentration of copper ions (II) due to the formation of complexes between them. The influence of the pH of the solution, the concentration of polyacrylic acid and copper ions (II) in the solution on the amount of bound copper during the formation of copper salt sediment with polyacids is shown.
dc.format.extent1-7
dc.format.pages7
dc.identifier.citationОлійник Л. П. Вивчення комплексоутворення йонів міді (II) з поліакриловою кислотою / Л. П. Олійник // Хімія, технологія речовин та їх застосування. — Львів : Видавництво Львівської політехніки, 2023. — Том 6. — № 1. — С. 1–7.
dc.identifier.citationenOliynyk L. P. Study of complex formation copper (II) ions with polyacrylic acid / L. P. Oliynyk // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2023. — Vol 6. — No 1. — P. 1–7.
dc.identifier.doidoi.org/10.23939/ctas2023.01.001
dc.identifier.issn2617-7307
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/61171
dc.language.isouk
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofХімія, технологія речовин та їх застосування, 1 (6), 2023
dc.relation.ispartofChemistry, Technology and Application of Substances, 1 (6), 2023
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dc.relation.references18. Bekturov, Ye. A., Bimendina, L. A., Mamitbekov, G. K. (2002). Kompleksy vodorastvorimykh polimerov i gidrogeley. Ġilim. Almata.
dc.relation.references19. Bimendina, L. A., Yashkarova, M. G., Kudaibergenov, S. Ê., Bekturov, Ye. A. (2003). Polimernyye kompleksy (polucheniye, svoystva, primeneniye) : monografiya. Semipalatinskiy gosudarstvennyy universitet im. Shakarima. Semipalatinsk.
dc.relation.references20. Oliynyk, L. P., Vretsena, N. B., Chernyak, B. I. (1999). Sintez i fiziko-khimicheskiye issledovaniya slozhnokationnykh nitrozopentatsianoferratov. Koordinatsionnaya khimiya, T. 25, 7, 513–515.
dc.relation.referencesen1. Khutoryanskiy, V. V., Smyslov, R. Y., Yakimansky, A. V. (2018). Modern methods for studying polymer complexes in aqueous and organic solutions. Polymer Science Series A, 60 (5), 553–576. ISSN 1555-6107. doi: https://doi.org/10.1134/S0965545X18050085. http://centaur.reading.ac.uk/79019/.
dc.relation.referencesen2. Starchevskyy, V., Bernatska, N., Typilo, I., Oliynyk, L., Kvit, R. (2018). Determination of the Cavitation Influence on the Destruction Process of Microorganism Cells Agglomerates. Chemistry, Chemical, Technol., 12, 462. https://doi.org/10.23939/chcht12.04.462.
dc.relation.referencesen3. Aneli, J., Shamanauri, L., Markarashvili, E., Tatrishvili, T. (2017). Polymer-silicate composites with modified minerals.Chemistry, Chemical, Technol, 11, 201. https://doi.org/10.23939/chcht11.02.201.
dc.relation.referencesen4. Dzhardimaliyeva, G., Pomogaylo, A. (2009). Monomernyye i polimernyye karboksilaty metallov. Fizmatlit. Moskva.
dc.relation.referencesen5. Kolawole, E. G., Mathieson, S. M. (1979). Binding of Cu (II) to poly(metacrylic acid). Journal of Polymer Science: Polymer Chemistry, 17, 9, 573–577.
dc.relation.referencesen6. Skopenko, V. V., Zub, V. YA. (2003). Praktykum z koordynatsiynoyi khimiyi. Kyyiv: Vyd. KNU.
dc.relation.referencesen7. Crooks, R. C., Zhao, M., Sun, L., et al. (2001). Dendrimer-Encapsulated Metal Nanoparticles: Synthesis, Characterization, and Applications to Catalysis. Accounts of Chemical Research, 34, 181. https://doi.org/10.1021/ar000110a.
dc.relation.referencesen8. Pomogaylo, A. D., Rozenberg, I. Ye., Uflyand, I. Ye. (2000). Nanochastitsy metallov v polimerakh Khimiya. Moskva.
dc.relation.referencesen9. Kislenko, V. N., Oliynyk, L. P. (2002). Complex formation of polyethyleneimine with copper (II), nickel (II), and cobalt (II) ions. Journal of Polymer Science Part A: Polymer Chemistry, 40, 914. https://doi.org/10.1002/pola.10157.
dc.relation.referencesen10. Kolawole, E. G., Bello, M. A. (1980). Interaction of divalent ions of copper, magnesium and zinc with isotactic polymethacrylic acid. European Polymer Journal,16, 325. https://doi.org/10.1016/0014-3057(80)90077-4.
dc.relation.referencesen11. Lázaro-Martínez, J. M., Monti, G. A., Chattah, A. K. (2013). Insights into the coordination sphere of copper ion in polymers containing carboxylic acid and azole groups. Polymer, 54, 19, 5214–5221. https://doi.org/10.1016/j.polymer.2013.07.036.
dc.relation.referencesen12. Annenkov, V. V., Danilovtseva, E. N., Saraev, V. V., Mikhaleva, A. I.(2003). Complexation of copper (II) ions with imidazole – carboxylic polymeric systems. Journal of Polymer Science Part A: Polymer Chemistry, 41, 2256. doi:10.1002/pola.10769.
dc.relation.referencesen13. Kislenko , V. N. Verlinskaya, R. M. (2003). Kinetics of copper dissolving in the water solution of polyacrylic acid or its copolymers with acrylonitrile and hydrogen peroxide. Journal of Colloid and Interface Science, 265, 129–133. https://www.elsevier.com/locate/jcis.
dc.relation.referencesen14. Filenko, M., Demchenko, Z., Mustafaeva, M. (2000). Behavior of ternary complex: bovine serum albumin – Cu- copolymer of acrylic acid with N-isopropylamide (fluorescent approach). Living physics, T. 8, 2, 72–81.
dc.relation.referencesen15. Generalova, A. N., Zubov, V. P. (2016). Dispersions of polyacrolein-based multifunctional microspheres for the creation of bioanalytical and visualizing reagents. Polymer Science Series B, 58(4), 385–410. https://doi.org/10.1134/S1560090416040023.
dc.relation.referencesen16. Kotton, F., Uilkinson, Dzh. (1969). Sovremennaya neorganicheskaya khimiya. M. : Mir,T. 3, 620.
dc.relation.referencesen17. Patel, K. N., Patel, N. H., Patel, K. M., Patel, M. N. (2000). Synthesis and Characterization of Cobalt (II), Nickel (II), Copper (II) and Zinc (II) Mixed-Ligand Complexes Inorganic and Metal-Organic Chemistry, 30(5), 921–930. doi.org/10.1080/00945710009351809.
dc.relation.referencesen18. Bekturov, Ye. A., Bimendina, L. A., Mamitbekov, G. K. (2002). Kompleksy vodorastvorimykh polimerov i gidrogeley. Ġilim. Almata.
dc.relation.referencesen19. Bimendina, L. A., Yashkarova, M. G., Kudaibergenov, S. Ê., Bekturov, Ye. A. (2003). Polimernyye kompleksy (polucheniye, svoystva, primeneniye) : monografiya. Semipalatinskiy gosudarstvennyy universitet im. Shakarima. Semipalatinsk.
dc.relation.referencesen20. Oliynyk, L. P., Vretsena, N. B., Chernyak, B. I. (1999). Sintez i fiziko-khimicheskiye issledovaniya slozhnokationnykh nitrozopentatsianoferratov. Koordinatsionnaya khimiya, T. 25, 7, 513–515.
dc.relation.urihttps://doi.org/10.1134/S0965545X18050085
dc.relation.urihttp://centaur.reading.ac.uk/79019/
dc.relation.urihttps://doi.org/10.23939/chcht12.04.462
dc.relation.urihttps://doi.org/10.23939/chcht11.02.201
dc.relation.urihttps://doi.org/10.1021/ar000110a
dc.relation.urihttps://doi.org/10.1002/pola.10157
dc.relation.urihttps://doi.org/10.1016/0014-3057(80)90077-4
dc.relation.urihttps://doi.org/10.1016/j.polymer.2013.07.036
dc.relation.urihttps://www.elsevier.com/locate/jcis
dc.relation.urihttps://doi.org/10.1134/S1560090416040023
dc.rights.holder© Національний університет “Львівська політехніка”, 2023
dc.subjectкомплексоутворення
dc.subjectполіакрилова кислота
dc.subjectполікислоти
dc.subjectйони міді (ІІ)
dc.subjectкарбоксилвмісні полімер
dc.subjectcomplexes
dc.subjectpolyacrylic acid
dc.subjectpolyacids
dc.subjectcopper ions (II)
dc.subjectcarboxyl-containing polymers
dc.titleВивчення комплексоутворення йонів міді (II) з поліакриловою кислотою
dc.title.alternativeStudy of complex formation copper (II) ions with polyacrylic acid
dc.typeArticle

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Chemistry, Technology and Application of Substances. – 2023. – Vol. 6, No. 1