The mass transfer during the dissolution of boric acid in water intensified by mechanical stirring
| dc.citation.epage | 160 | |
| dc.citation.issue | 2 | |
| dc.citation.spage | 153 | |
| dc.contributor.affiliation | Національний університет “Львівська політехніка” | |
| dc.contributor.affiliation | Національний університет “Львівська політехніка” | |
| dc.contributor.affiliation | Національний університет “Львівська політехніка” | |
| dc.contributor.affiliation | Lviv Polytechnic National University | |
| dc.contributor.affiliation | Lviv Polytechnic National University | |
| dc.contributor.affiliation | Lviv Polytechnic National University | |
| dc.contributor.author | Кузик, О. О. | |
| dc.contributor.author | Атаманюк, В. М. | |
| dc.contributor.author | Гумницький, Я. М. | |
| dc.contributor.author | Kuzyk, O. O. | |
| dc.contributor.author | Atamanyuk, V. M. | |
| dc.contributor.author | Gumnitsky, Y. M. | |
| dc.coverage.placename | Львів | |
| dc.coverage.placename | Lviv | |
| dc.date.accessioned | 2026-01-15T13:53:23Z | |
| dc.date.created | 2024-10-10 | |
| dc.date.issued | 2024-10-10 | |
| dc.description.abstract | У дослідженні наведено кінетику розчинення кульок гранул борної кислоти залежно від температури розчину та частоти обертання мішалки. Експериментально визначено коефіцієнти масовіддачі та наведено порівняння їх із теоретично визначеними. Встановлено, що за збільшення частоти обертання мішалки та температури розчину збільшується коефіцієнт масовіддачі. Отримано розрахункову залежність, яка дає змогу прогнозувати процес розчинення гранул борної кислоти залежно від температури розчину і частоти обертання мішалки. Отримані результати підтверджують суттєвий вплив конструктивних параметрів реактора та умов перемішування на процес масообміну в системі «тверде тіло – рідина». Отримані результати дослідження дають змогу змоделювати та оптимізувати процеси масообміну в системах тверде тіло – рідина, що у свою чергу дає можливість подальшої оптимізації технологічних процесів в хімічній промисловості, та забезпечення зменшення енергозатратності процесу розчинення. | |
| dc.description.abstract | The kinetics granules of boric acid (GBA) dissolution were investigated based on the solution temperature and stirring frequency. Experimental mass transfer coefficients were determined and compared with theoretical values. The results indicate that increasing the stirring frequency and the solvent temperature increases the mass transfer coefficient. A computational relationship was derived, enabling the prediction of GBA dissolution based on solution temperature and stirring frequency. These findings highlight the significant impact of reactor parameters and mixing conditions on the mass transfer process in solid-liquid systems. The study’s results facilitate the simulation and optimization of mass transfer processes in solid-liquid systems, contributing to the optimization of chemical industry technological processes and reducing the energy consumption of the dissolution process. | |
| dc.format.extent | 153-160 | |
| dc.format.pages | 8 | |
| dc.identifier.citation | Kuzyk O. O. The mass transfer during the dissolution of boric acid in water intensified by mechanical stirring / O. O. Kuzyk, V. M. Atamanyuk, Y. M. Gumnitsky // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2024. — Vol 7. — No 2. — P. 153–160. | |
| dc.identifier.citation2015 | Kuzyk O. O., Gumnitsky Y. M. The mass transfer during the dissolution of boric acid in water intensified by mechanical stirring // Chemistry, Technology and Application of Substances, Lviv. 2024. Vol 7. No 2. P. 153–160. | |
| dc.identifier.citationenAPA | Kuzyk, O. O., Atamanyuk, V. M., & Gumnitsky, Y. M. (2024). The mass transfer during the dissolution of boric acid in water intensified by mechanical stirring. Chemistry, Technology and Application of Substances, 7(2), 153-160. Lviv Politechnic Publishing House.. | |
| dc.identifier.citationenCHICAGO | Kuzyk O. O., Atamanyuk V. M., Gumnitsky Y. M. (2024) The mass transfer during the dissolution of boric acid in water intensified by mechanical stirring. Chemistry, Technology and Application of Substances (Lviv), vol. 7, no 2, pp. 153-160. | |
| dc.identifier.doi | https://doi.org/10.23939/ctas2024.02.153 | |
| dc.identifier.uri | https://ena.lpnu.ua/handle/ntb/124451 | |
| dc.language.iso | en | |
| dc.publisher | Видавництво Львівської політехніки | |
| dc.publisher | Lviv Politechnic Publishing House | |
| dc.relation.ispartof | Chemistry, Technology and Application of Substances, 2 (7), 2024 | |
| dc.relation.references | 1. Wahl, M. (2005). Boric acid. In Encyclopedia of Toxicology (2nd ed., pp. 329–330). https://doi.org/10.1016/B0-12-369400-0/00142-3 | |
| dc.relation.references | 2. Nahurskyi, O. A. (2012). Zakonomirnosti kapsuluvannia rechovyn u stani pseudoridzhennia ta yikh dyfuziinoho vivilnennia: monohrafiia. Lviv: Vydavnytstvo Lvivskoi politekhniky. | |
| dc.relation.references | 3. Liang H, Jahanmir S. (1995). Boric acid as an additive for core-drilling of alumina. J. Tribol., 117:65–73. | |
| dc.relation.references | 4. Wei J. J., Erdemir A., Fenske G. R. (2000). Dry lubricant films for aluminum forming. Tribol. Trans.,43(3):535–41. | |
| dc.relation.references | 5. Erdemir A. (1991). Tribological properties of boric acid and boric-acid-forming surfaces. Part I: crystal chemistry and mechanism of self- lubrication of boric acid. Lubr. Eng., 47:168–73. | |
| dc.relation.references | 6. Rao K. P., Wei J. J. (2001). Performance of a new dry lubricant in the forming of aluminum alloy sheets. Wear, 249, 86–93. | |
| dc.relation.references | 7. Lyuta, O. V., & Symak, D. M. (2018). Extraction of soluble solid phase from a layer of porous inert medium. Bulletin of Lviv Polytechnic National University. Chemistry, Technology of Substances and Their Applications, (886), 165–170. | |
| dc.relation.references | 8. Atamaniuk, V. M., Symak, D. M., & Danyliuk, O. M. (2016). Dissolution of the polydisperse solid phase in a gas-liquid flow. Bulletin of Lviv Polytechnic National University. Chemistry, Technology of Substances and Their Applications, (841), 271–277. | |
| dc.relation.references | 9. Symak, D., Atamaniuk, V., & Gumnitsky, Ya.(2015). Analysis of dissolution kinetics based on the local isotropic turbulence theory. Chemistry & Chemical Technology, 9(4), 493–497. https://doi.org/10.23939/chcht09.04.493 | |
| dc.relation.references | 10. Sabadash, V., Mylanyk, O., Matsutska, O., & Gumnytsky, J. (2017). Kinetic regularities of copper ions adsorption by natural zeolite. Chemistry & Chemical Technology, 11(4), 459–462. https://doi.org/10.23939/chcht11.04.459 | |
| dc.relation.references | 11. Symak, D. M., & Liuta, O. V. (2015). Nestatsionarnyi protses rozchynennia sharu zernystoho materialu. Khimiia, tekhnolohiia rechovyn ta yikh zastosuvannia, (812), 308–312. | |
| dc.relation.references | 12. Symak, D., Gumnytsky, Y., Atamaniuk, V.,& Danyliuk, O. (2015). Kinetika rozchynnya polidyspersnoho kaliyu sulfatu za pereminnoyi rushiynoyi syly. Scientific Works, 80(1). https://doi.org/10.15673/swonaft.v80i1.193 | |
| dc.relation.references | 13. Aksielrud, G., & Lysiański, V. (1978). Solidliquid extraction. Warsaw: Wydaw, Nauk. Techn. | |
| dc.relation.references | 14. Semenishin, Y. M., Trotskyi, V. I., & Fedorchuk-Moroz, V. I. (2004). Osoblyvosti ekstrahuvannia tsilovykh komponentiv z porystykh struktur. Naukovyi visnyk NLTU Ukrainy, 14(4), 317–321. | |
| dc.relation.references | 15. Humnytskyi, Y. M., & Symak, D. M. (2017). Intensification of mass transfer processes in the solidliquid system by the introduction of the gas phase. Proceedings of the XVIII International Scientific and Practical Conference. | |
| dc.relation.references | 16. Pangarkar, V. G.; Yawalkar, A. A.; Sharma, M. M.; Beenackers, A. A. C. M. (2002). Particle– Liquid Mass Transfer Coefficient in Two-/Three-Phase Stirred Tank Reactors. Ind. Eng. Chem. Res., 41, 4141–4167. DOI: 10.1021/ie010933j | |
| dc.relation.references | 17. Meneses, J. P. C. H.; Calcada, L. A.; Scheid, C. M.; Magalhães, S. d. C. (2017). Determination of the Convective Mass Transfer Coefficient in the Dissolution of NaCl Particles in Non-Newtonian Fluids. J. Nat. Gas Sci. Eng., 45, 118– 126. DOI: 10.1016/j.jngse.2017.03.014 | |
| dc.relation.references | 18. Carletti, C.; Bikić, S.; Montante, G.; Paglianti, A. (2018). Mass Transfer in Dilute Solid-liquid Stirred Tanks. Ind. Eng. Chem. Res., 57, 6505–6515. DOI:10.1021/acs.iecr.7b04730 | |
| dc.relation.references | 19. Harriott, P. (1962). Mass Transfer to Particles: Part I. Suspended in Agitated Tanks. AIChE J., 8, 93–101. DOI: 10.1002/aic.690080122 | |
| dc.relation.references | 20. Guiza, S.; Hajji, H.; Bagane, M. (2019). External Mass Transport Process during the Adsorption of Fluoride from Aqueous Solution by Activated Clay. C. R. Chim., 22, 161–168. DOI: 10.1016/j.crci.2019.02.001 | |
| dc.relation.references | 21. Girish, C. R.; Murty, V. R. (2016). Mass Transfer Studies on Adsorption of Phenol from Wastewater Using Lantana Camara. Int. J. Chem. Eng., 1–11.DOI: 10.1155/2016/5809505 | |
| dc.relation.references | 22. Oriakhi, C. O. (2021). Chemistry in Quantitative Language: Fundamentals of General Chemistry Calculations. Oxford: Oxford University Press. | |
| dc.relation.references | 23. Salmi, T. O., Mikkola, J., & Warna, J. P.(2019). Chemical Reaction Engineering and Reactor Technology (2nd ed.). Boca Raton: CRC Press. | |
| dc.relation.references | 24. Sabadash, V., Mylanyk, O., Matsuska, O., & Gumnitsky, J. (2017). Kinetic regularities of copper ions adsorption by natural zeolite. Chemistry & Chemical Technology, 11, 459–462.https://doi.org/10.23939/chcht11.04.459 | |
| dc.relation.references | 25. Miyabe, K., & Isogai, R. (2011). Estimation of molecular diffusivity in liquid phase systems by the Wilke–Chang equation. Journal of Chromatography,1218(38), 6639–6645. https://doi.org/10.1016/j.chroma.2011.07.018 | |
| dc.relation.referencesen | 1. Wahl, M. (2005). Boric acid. In Encyclopedia of Toxicology (2nd ed., pp. 329–330). https://doi.org/10.1016/B0-12-369400-0/00142-3 | |
| dc.relation.referencesen | 2. Nahurskyi, O. A. (2012). Zakonomirnosti kapsuluvannia rechovyn u stani pseudoridzhennia ta yikh dyfuziinoho vivilnennia: monohrafiia. Lviv: Vydavnytstvo Lvivskoi politekhniky. | |
| dc.relation.referencesen | 3. Liang H, Jahanmir S. (1995). Boric acid as an additive for core-drilling of alumina. J. Tribol., 117:65–73. | |
| dc.relation.referencesen | 4. Wei J. J., Erdemir A., Fenske G. R. (2000). Dry lubricant films for aluminum forming. Tribol. Trans.,43(3):535–41. | |
| dc.relation.referencesen | 5. Erdemir A. (1991). Tribological properties of boric acid and boric-acid-forming surfaces. Part I: crystal chemistry and mechanism of self- lubrication of boric acid. Lubr. Eng., 47:168–73. | |
| dc.relation.referencesen | 6. Rao K. P., Wei J. J. (2001). Performance of a new dry lubricant in the forming of aluminum alloy sheets. Wear, 249, 86–93. | |
| dc.relation.referencesen | 7. Lyuta, O. V., & Symak, D. M. (2018). Extraction of soluble solid phase from a layer of porous inert medium. Bulletin of Lviv Polytechnic National University. Chemistry, Technology of Substances and Their Applications, (886), 165–170. | |
| dc.relation.referencesen | 8. Atamaniuk, V. M., Symak, D. M., & Danyliuk, O. M. (2016). Dissolution of the polydisperse solid phase in a gas-liquid flow. Bulletin of Lviv Polytechnic National University. Chemistry, Technology of Substances and Their Applications, (841), 271–277. | |
| dc.relation.referencesen | 9. Symak, D., Atamaniuk, V., & Gumnitsky, Ya.(2015). Analysis of dissolution kinetics based on the local isotropic turbulence theory. Chemistry & Chemical Technology, 9(4), 493–497. https://doi.org/10.23939/chcht09.04.493 | |
| dc.relation.referencesen | 10. Sabadash, V., Mylanyk, O., Matsutska, O., & Gumnytsky, J. (2017). Kinetic regularities of copper ions adsorption by natural zeolite. Chemistry & Chemical Technology, 11(4), 459–462. https://doi.org/10.23939/chcht11.04.459 | |
| dc.relation.referencesen | 11. Symak, D. M., & Liuta, O. V. (2015). Nestatsionarnyi protses rozchynennia sharu zernystoho materialu. Khimiia, tekhnolohiia rechovyn ta yikh zastosuvannia, (812), 308–312. | |
| dc.relation.referencesen | 12. Symak, D., Gumnytsky, Y., Atamaniuk, V.,& Danyliuk, O. (2015). Kinetika rozchynnya polidyspersnoho kaliyu sulfatu za pereminnoyi rushiynoyi syly. Scientific Works, 80(1). https://doi.org/10.15673/swonaft.v80i1.193 | |
| dc.relation.referencesen | 13. Aksielrud, G., & Lysiański, V. (1978). Solidliquid extraction. Warsaw: Wydaw, Nauk. Techn. | |
| dc.relation.referencesen | 14. Semenishin, Y. M., Trotskyi, V. I., & Fedorchuk-Moroz, V. I. (2004). Osoblyvosti ekstrahuvannia tsilovykh komponentiv z porystykh struktur. Naukovyi visnyk NLTU Ukrainy, 14(4), 317–321. | |
| dc.relation.referencesen | 15. Humnytskyi, Y. M., & Symak, D. M. (2017). Intensification of mass transfer processes in the solidliquid system by the introduction of the gas phase. Proceedings of the XVIII International Scientific and Practical Conference. | |
| dc.relation.referencesen | 16. Pangarkar, V. G.; Yawalkar, A. A.; Sharma, M. M.; Beenackers, A. A. C. M. (2002). Particle– Liquid Mass Transfer Coefficient in Two-/Three-Phase Stirred Tank Reactors. Ind. Eng. Chem. Res., 41, 4141–4167. DOI: 10.1021/ie010933j | |
| dc.relation.referencesen | 17. Meneses, J. P. C. H.; Calcada, L. A.; Scheid, C. M.; Magalhães, S. d. C. (2017). Determination of the Convective Mass Transfer Coefficient in the Dissolution of NaCl Particles in Non-Newtonian Fluids. J. Nat. Gas Sci. Eng., 45, 118– 126. DOI: 10.1016/j.jngse.2017.03.014 | |
| dc.relation.referencesen | 18. Carletti, C.; Bikić, S.; Montante, G.; Paglianti, A. (2018). Mass Transfer in Dilute Solid-liquid Stirred Tanks. Ind. Eng. Chem. Res., 57, 6505–6515. DOI:10.1021/acs.iecr.7b04730 | |
| dc.relation.referencesen | 19. Harriott, P. (1962). Mass Transfer to Particles: Part I. Suspended in Agitated Tanks. AIChE J., 8, 93–101. DOI: 10.1002/aic.690080122 | |
| dc.relation.referencesen | 20. Guiza, S.; Hajji, H.; Bagane, M. (2019). External Mass Transport Process during the Adsorption of Fluoride from Aqueous Solution by Activated Clay. C. R. Chim., 22, 161–168. DOI: 10.1016/j.crci.2019.02.001 | |
| dc.relation.referencesen | 21. Girish, C. R.; Murty, V. R. (2016). Mass Transfer Studies on Adsorption of Phenol from Wastewater Using Lantana Camara. Int. J. Chem. Eng., 1–11.DOI: 10.1155/2016/5809505 | |
| dc.relation.referencesen | 22. Oriakhi, C. O. (2021). Chemistry in Quantitative Language: Fundamentals of General Chemistry Calculations. Oxford: Oxford University Press. | |
| dc.relation.referencesen | 23. Salmi, T. O., Mikkola, J., & Warna, J. P.(2019). Chemical Reaction Engineering and Reactor Technology (2nd ed.). Boca Raton: CRC Press. | |
| dc.relation.referencesen | 24. Sabadash, V., Mylanyk, O., Matsuska, O., & Gumnitsky, J. (2017). Kinetic regularities of copper ions adsorption by natural zeolite. Chemistry & Chemical Technology, 11, 459–462.https://doi.org/10.23939/chcht11.04.459 | |
| dc.relation.referencesen | 25. Miyabe, K., & Isogai, R. (2011). Estimation of molecular diffusivity in liquid phase systems by the Wilke–Chang equation. Journal of Chromatography,1218(38), 6639–6645. https://doi.org/10.1016/j.chroma.2011.07.018 | |
| dc.relation.uri | https://doi.org/10.1016/B0-12-369400-0/00142-3 | |
| dc.relation.uri | https://doi.org/10.23939/chcht09.04.493 | |
| dc.relation.uri | https://doi.org/10.23939/chcht11.04.459 | |
| dc.relation.uri | https://doi.org/10.15673/swonaft.v80i1.193 | |
| dc.relation.uri | https://doi.org/10.1016/j.chroma.2011.07.018 | |
| dc.rights.holder | © Національний університет „Львівська політехніка“, 2024 | |
| dc.subject | борна кислота | |
| dc.subject | розчинення | |
| dc.subject | частота обертання мішалки | |
| dc.subject | коефіцієнт масовіддачі | |
| dc.subject | система тверде тіло – рідина | |
| dc.subject | boric acid | |
| dc.subject | dissolution | |
| dc.subject | stirring frequency | |
| dc.subject | mass transfer coefficient | |
| dc.subject | solidliquid system | |
| dc.title | The mass transfer during the dissolution of boric acid in water intensified by mechanical stirring | |
| dc.title.alternative | Масообмін під час розчинення борної кислоти у воді, інтенсифікований механічним перемішуванням | |
| dc.type | Article |