Effect of the reactants molar ratio on the kinetics of cycloaddition of 2,3-dimethylbuta-1,3-diene to methylacrylate

dc.citation.conference7th International youth science forum «Litteris et Artibus»
dc.citation.epage94
dc.citation.journalTitleLitteris et Artibus : матеріали
dc.citation.spage91
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.affiliationJan and Jedrzej Sniadecki University of Technology and Life Sciences in Bydgoszcz, POLAND
dc.contributor.authorKostiv, I. S.
dc.contributor.authorMarshalok, G. A.
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.coverage.temporal23–25 листопада 2017 року
dc.coverage.temporal23–25 November, 2017
dc.date.accessioned2018-04-12T13:06:28Z
dc.date.available2018-04-12T13:06:28Z
dc.date.created2017-12-23
dc.date.issued2017-12-23
dc.description.abstractThe cycloaddition reaction between 2,3-dimethylbuta- 1,3-diene and methylacrylate proceeds by the second order kinetics. The rate constants increase with the increase in the excess of one of the reactants. The change in the effective rate constants is described by the Michaelis–Menten equation indicating that the reaction proceeds through the initial equilibrium stage of formation of an intermediate complex which then transforms into the product. The effective rate constants, the equilibrium constants of formation of the intermediate complex, and the rate constant of its transformation into the reaction product were determined, as well as the thermodynamic parameters of the formation of the intermediate complex and the activation parameters of the transformation of the intermediate complex into the product. The limiting stage of the reaction is established and itsmechanism is suggested.
dc.format.extent91-94
dc.format.pages4
dc.identifier.citationKostiv I. S. Effect of the reactants molar ratio on the kinetics of cycloaddition of 2,3-dimethylbuta-1,3-diene to methylacrylate / I. S. Kostiv, G. A. Marshalok // Litteris et Artibus : proceedings, 23–25 November, 2017. — Lviv : Lviv Polytechnic Publishing House, 2017. — P. 91–94. — (6th International academic conference «Chemistry & chemical technology 2017» (CCT-2017)).
dc.identifier.citationenKostiv I. S. Effect of the reactants molar ratio on the kinetics of cycloaddition of 2,3-dimethylbuta-1,3-diene to methylacrylate / I. S. Kostiv, G. A. Marshalok // Litteris et Artibus : proceedings, 23–25 November, 2017. — Lviv : Lviv Polytechnic Publishing House, 2017. — P. 91–94. — (6th International academic conference «Chemistry & chemical technology 2017» (CCT-2017)).
dc.identifier.isbn978-966-941-108-2
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/40486
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Polytechnic Publishing House
dc.relation.ispartofLitteris et Artibus : матеріали, 2017
dc.relation.ispartofLitteris et Artibus : proceedings, 2017
dc.relation.references[1] J.M. Velazquez, S.R. Hertenstein, J.R. Clare, and M.N. Green, US Patent 2010/0152083, 2010.
dc.relation.references[2] J. Smets, M. Newman, H. Schenk, and P. Haspeter, US Patent 2008/0200359, 2008.
dc.relation.references[3] І.S. Polyova, I.P. Polyuzhin, G.O. Marshalok and A.I. Gladii, “Analytical control of process obtaining R-allyl-1,3,4-trimethylcyclohex-3-encarboxylate by method gas-liquid hromatografy” Abstract of Papers, III Ukrainian Sci. Conf. of Students and Aspirants “Khimichny Karazinski Chitaniya 2011,” p. 41, Kharkov, 2011.
dc.relation.references[4] R. Shmid, and V.N. Sapunov, “Neformal’naya kinetika (Unformal Cinetics)”, Moscow: Mir, p.264, 1985.
dc.relation.references[5] R. Jasinski, M. Kwiatnowska and A. Baranski, “Мechanistyczne aspekty nieuzgodnionych (4+2)pelektronowych cykloaddycji”, Wiadom. Chemiczne, vol. 61, no. 7–8, p. 485-514, 2007.
dc.relation.references[6] R.B. Woodward, and T.J Katz, “Studies of amineinduced ring opening of some mesoionic xanthines” Tetrahedron, vol. 5, no. 1, p. 70, 1959.
dc.relation.references[7] L. Hammett, “Physical Organic Chemistry”, New York: McGraw-Hill, p.105, 1970.
dc.relation.references[8] A.Coda Corsico, G. Desimoni, E. Ferrari, P. Righetti, and G. Tacconi, “Solvent effect as the result of frontier molecular orbital interaction-1 : The dielsalder reaction between 1,4-naphthoquinone and 2,3- dimethylbutadiene”, Tetrahedron, vol. 40, no. 9, p. 1611-1615, 1984.
dc.relation.references[9] G. Desimoni, G. Faita, P. Righetti, and G. Tacconi, “Diels-Alder Reactions in Micellar”, Media J. Chem. Soc., Perkin Trans. 2, no. 3, p. 437-441, 1989.
dc.relation.referencesen[1] J.M. Velazquez, S.R. Hertenstein, J.R. Clare, and M.N. Green, US Patent 2010/0152083, 2010.
dc.relation.referencesen[2] J. Smets, M. Newman, H. Schenk, and P. Haspeter, US Patent 2008/0200359, 2008.
dc.relation.referencesen[3] I.S. Polyova, I.P. Polyuzhin, G.O. Marshalok and A.I. Gladii, "Analytical control of process obtaining R-allyl-1,3,4-trimethylcyclohex-3-encarboxylate by method gas-liquid hromatografy" Abstract of Papers, III Ukrainian Sci. Conf. of Students and Aspirants "Khimichny Karazinski Chitaniya 2011," p. 41, Kharkov, 2011.
dc.relation.referencesen[4] R. Shmid, and V.N. Sapunov, "Neformal’naya kinetika (Unformal Cinetics)", Moscow: Mir, p.264, 1985.
dc.relation.referencesen[5] R. Jasinski, M. Kwiatnowska and A. Baranski, "Mechanistyczne aspekty nieuzgodnionych (4+2)pelektronowych cykloaddycji", Wiadom. Chemiczne, vol. 61, no. 7–8, p. 485-514, 2007.
dc.relation.referencesen[6] R.B. Woodward, and T.J Katz, "Studies of amineinduced ring opening of some mesoionic xanthines" Tetrahedron, vol. 5, no. 1, p. 70, 1959.
dc.relation.referencesen[7] L. Hammett, "Physical Organic Chemistry", New York: McGraw-Hill, p.105, 1970.
dc.relation.referencesen[8] A.Coda Corsico, G. Desimoni, E. Ferrari, P. Righetti, and G. Tacconi, "Solvent effect as the result of frontier molecular orbital interaction-1 : The dielsalder reaction between 1,4-naphthoquinone and 2,3- dimethylbutadiene", Tetrahedron, vol. 40, no. 9, p. 1611-1615, 1984.
dc.relation.referencesen[9] G. Desimoni, G. Faita, P. Righetti, and G. Tacconi, "Diels-Alder Reactions in Micellar", Media J. Chem. Soc., Perkin Trans. 2, no. 3, p. 437-441, 1989.
dc.rights.holder© Національний університет “Львівська політехніка”, 2017
dc.subject2 3-dimethylbuta-1 3-diene
dc.subjectmethylacrylate
dc.subjectmethyl-3 4-dimethylcyclohex-3-ene-1-carboxylate
dc.subjectcycloaddition reaction
dc.subjectMichaelis–Menten equation
dc.subjecteffective rate constants
dc.subjectintermediate complex
dc.subjectlimiting stage
dc.titleEffect of the reactants molar ratio on the kinetics of cycloaddition of 2,3-dimethylbuta-1,3-diene to methylacrylate
dc.typeConference Abstract

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