Technological features of the formation of film products from modified hydrogels by the centrifugal method.

dc.citation.epage210
dc.citation.issue7
dc.citation.journalTitleХімія, технологія речовин та їх застосування
dc.citation.spage202
dc.citation.volume1
dc.contributor.affiliationНаціональний університет “Львівська політехніка”
dc.contributor.affiliationТехнічний університет Кошице
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.affiliationTechnical University in Košice
dc.contributor.authorГриценко, О. М.
dc.contributor.authorГайдос, І.
dc.contributor.authorГриценко, Т. О.
dc.contributor.authorЯковенко, М. М.
dc.contributor.authorGrytsenko, O. M.
dc.contributor.authorGajdoš, I.
dc.contributor.authorGrytsenko, T. O.
dc.contributor.authorYakovenko, M. M.
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2025-09-12T07:59:58Z
dc.date.created2024-02-27
dc.date.issued2024-02-27
dc.description.abstractПерероблення полімерів та композиційних матеріалів на їх основі методом відцентрового формування актуальне для виготовлення виробів у вигляді тіл обертання, які використовують у різних галузях народного господарства. В роботі проаналізовано відцентрове формування та подано результати дослідження нової сфери його використання як методу для виготовлення гідрогелевих плівок із матеріалів на основі кополімерів 2-гідроксіетилметакрилату з полівінілпіролідоном, зокрема наповнених, які можна застосовувати у медицині, електротехніці та приладобудуванні.
dc.description.abstractProcessing of polymers and composites based on them by centrifugal molding is important for production the bodies of revolution, which are used in various industries. This article analyzes the centrifugal molding and presents the results of research about new areas of such materials applications. For instance as method for the hydrogel films production of materials based on copolymers of 2-hydroxyethyl methacrylate (HEMA) with polyvinylpyrrolidone (PVP), including filled hydrogels, which can be applicable in medicine, electrical and tool engineering.
dc.format.extent202-210
dc.format.pages9
dc.identifier.citationTechnological features of the formation of film products from modified hydrogels by the centrifugal method. / O. M. Grytsenko, I. Gajdoš, T. O. Grytsenko, M. M. Yakovenko // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2024. — Vol 1. — No 7. — P. 202–210.
dc.identifier.citationenTechnological features of the formation of film products from modified hydrogels by the centrifugal method. / O. M. Grytsenko, I. Gajdoš, T. O. Grytsenko, M. M. Yakovenko // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2024. — Vol 1. — No 7. — P. 202–210.
dc.identifier.doidoi.org/10.23939/ctas2024.01.202
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/111747
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofХімія, технологія речовин та їх застосування, 7 (1), 2024
dc.relation.ispartofChemistry, Technology and Application of Substances, 7 (1), 2024
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dc.relation.references2. Baur, E., Osswald, T., Rudolph, N. Plastics Handbook. The Resource for Plastics Engineers. Munich: Carl Hanser Verlag, 2019. 680 p. https://doi.org/10.3139/9781569905609
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dc.relation.references4. Olson, L.G., Crawford, R., Kearns, M., Geiger, N. (2000). Rotational molding of plastics: Comparison of simulation and experimental results for an axisymmetric mold. Polymer Engineering & Science. 40(8), 1758-1764. https://doi.org/10.1002/pen.11307
dc.relation.references5. Hashmi, S. A. R., Dwivedi, U. K. (2006). Estimation of Concentration of Particles in Polymerizing Fluid during Centrifugal Casting of Functionally Graded Polymer Composites. Journal of Polymer Research, 14(1), 75-81. doi:10.1007/s10965-006-9083-5.
dc.relation.references6. Stabik, J., Dybowska, A., Pluszyñski, J., Szczepanik, M., Suchoñ, £. (2010). Magnetic induction of polymer composites filled with ferrite powders. Archives of Materials Science and Engineering, 41(1), 13-20
dc.relation.references7. Jachowicz, T., Sikora, J. (2013). Investigation of the influence of mold rotational speed on the cast wall thickness in the rotational molding process. Advances in Science and Technology Research Journal, 7(19), 79-87. DOI: 10.5604/20804075.1062380
dc.relation.references8. Zhang, H., Zhang, L., Chen, X., Wang, Y., Zhao, F., Luo, M., Liao, S. (2020). The Role of Non-Rubber Components on Molecular Network of Natural Rubber during Accelerated Storage. Polymers, 12, 2880. https://doi.org/10.3390/polym12122880
dc.relation.references9. Funabashi, M. (1997). Gradient composites of nickel coated carbon fibre filled epoxy resin moulded under centrifugal force. Composites Part A, 28, 731-737. https://doi.org/10.1016/S1359-835X(97)00016-X
dc.relation.references10. Calò, E., Massaro, C., Terzi, R. (2012). Rotational Molding of Polyamide-6 Nanocomposites with Improved Flame Retardancy. International Polymer Processing, 27, 370-377. https://doi.org/10.3139/217.2552
dc.relation.references11. Wang, F., Yao, W.G., Qiao, C.D., Jia, Y.X. (2012). Finite element analysis of the physical gelation process of PVC plastisol during rotational molding. Acta Polymerica Sinica, 9, 1035-1041.DOI:10.3724/SP.J.1105.2012.12081
dc.relation.references12. Rusu, M., Ibanescu, C., Murariu, M., Bordeianu, A., Balint, S., Andrei, E. (1998). Centrifugal Casting of Polyamide 6. Influence of Thermal Treatment. Polymers and Polymer Composites, 6(3), 143-146. doi:10.1177/147823919800600303
dc.relation.references13. Martens T. (2011). Use of Fused Deposition Modeling of Polyphenylsulfone for Centrifugal Casting of Polyurethane: Material, Surface, and Process Considerations. Journal of manufacturing science and engineering, 133(5), 0510031-051003.10. https://doi.org/10.1115/1.4004848
dc.relation.references14. Stabik, J., Dybowska, A., Chomiak, M. (2010). Polymer composites filled with powders as polymer graded materials. Journal of Achievements in Materials and Manufacturing Engineering, 43(1), 153-161
dc.relation.references15. Watanabe, Y., Kawamoto, A., Matsuda, K. (2002). Particle size distributions in functionally graded materials fabricated by the centrifugal solid-particle method. Composites Science and Technology, 62, 881-888. https://doi.org/10.1016/S0266-3538(02)00023-4
dc.relation.references16. Kaelble, D. H. (1965). Spin casting of polymer films. Journal of Applied Polymer Science, 9(4), 1209-1212. doi:10.1002/app.1965.070090402.
dc.relation.references17. Suberlyak, O., Grytsenko, O., Kochubei, V. (2015). The role of FeSO4 in the obtaining of polyvinylpirolidone copolymers. Chemistry & Chemical Technology, 9, 429-434. doi: https://doi.org/10.23939/chcht09.04.429.
dc.relation.references18. Grytsenko, O., Dulebova, L., Suberlyak, O., Skorokhoda, V., Spišák, E., Gajdos, I. (2020). Features of structure and properties of pHEMA-gr-PVP block copolymers, obtained in the presence of Fe2+. Materials, 13(20), 4580-4594. https://doi.org/10.3390/ma13204580
dc.relation.references19. Suberlyak, O. V., Skorokhoda, V. Y.,Grytsenko O. M. (2000). Naukovi aspekty rozroblennya tekhnolohiyi syntezu hidrofilʹnykh kopolimeriv polivinilpirolidonu. Voprosy khymyy i khymycheskoy tekhnolohyy, 1, 236-238
dc.relation.references20. Grytsenko, O. M., Skorokhoda, V. Y., Shapoval, P. Y., &Bukhvak, I. V. (2000). Doslidzhennya pryshcheplenoyi polimeryzatsiyi na PVP, initsiyovanoyi solyamy metaliv zminnoyi valentnosti. Visnyk Derzhavnoho univesytetu «Lvivska politekhnika», 414, 82-85. Retrieved from: http://ena.lp.edu.ua/bitstream/ntb/8974/1/25.pdf
dc.relation.references21. Grytsenko, O. M., Skorokhoda, V. Y., Yadushynsʹkyy, R. Y. (2004). Strukturni parametry ta vlastyvosti kopolimeriv 2-OEMA-PVP, oderzhanykh v prysutnosti Fe2+. Visnyk Natsionalʹnoho universytetu «Lvivska politekhnika», 488, 300-303. Retrieved from: http://ena.lp.edu.ua/bitstream/ntb/12009/1/45.pdf
dc.relation.references22. Grytsenko, O., Jachowicz, T., Suberlyak, O., Krasinskyi, V. Development of equipment for the production of hydrogel films by centrifugal molding. Advanced technologies in designing, engineering and manufacturing research problems. Monography. Lublin, 2015, 29-42.
dc.relation.references23. Suberlyak, O., Grytsenko, O., Hischak, K., Hnatchuk, N. (2013). Researching influence the nature of metal on mechanism of synthesis polyvinilpyrrolidone metal copolymers. Chemistry & chem. Tecnology, 7(3), 289-294. https://doi.org/10.23939/chcht07.03.289
dc.relation.references24. Grytsenko, O., Suberlak, O., Gajdoš, I., Fedasiuk, D. The features of film composite hydrogel materials obtaining technology by centrifugal molding. Technological and design aspects of extrusion and injection moulding of thermoplastic polymer composites and nanocomposites. Monography. Volume II: Kosice, 2014, 213-230.
dc.relation.references25. Grytsenko, O. M., Suberlyak, O. V., Pokhmursʹka, A. V., Bedlʹovsʹka, Kh. M., Gaydos I. (2017). Osoblyvosti utvorennya poverkhni metalonapovnenykh hidrohelevykh plivok, oderzhanykh vidtsentrovym formuvannyam. Visnyk Natsionalʹnoho universytetu «Lvivska politekhnika», 868, 381-387.
dc.relation.references26. Grytsenko, O., Suberlyak, O., Krasinskyi, V., Moravskyi, V., Berezhnyy, B. (2019). Physical-mechanical properties of metal-filled hydrogel films, obtained by centrifugal molding. Acta Mechanica Slovaca, 23(3), 18-23. DOI: 10.21496/ams.2019.024
dc.relation.references27. Grytsenko, O.M., Suberlyak, O.V., Pokhmursʹka, A.V., Krasinsʹkyy, V.V., Voloshkevych, P.P. (2018). Zakonomirnosti vidtsentrovoho utvorennya metalonapovnenykh hidrohelevykh plyvok. Chemistry, Technology and Application of Substances, 1(2), 149-156. https://doi.org/10.23939/ctas2018.02.149
dc.relation.referencesen1. Shrivastava, A. Introduction to Plastics Engineering. A volume in Plastics Design Library. New York: William Andrew Publishing. Elsevier Inc., 2018. 246 p. https://doi.org/10.1016/P.2014-0-03688-X
dc.relation.referencesen2. Baur, E., Osswald, T., Rudolph, N. Plastics Handbook. The Resource for Plastics Engineers. Munich: Carl Hanser Verlag, 2019. 680 p. https://doi.org/10.3139/9781569905609
dc.relation.referencesen3. Osswald, T. Understanding Polymer Processing. Processes and Governing Equations. Second Edition. Munich: Carl Hanser Verlag GmbH & Co. KG., 2017. 362 p. https://doi.org/10.3139/9781569906484
dc.relation.referencesen4. Olson, L.G., Crawford, R., Kearns, M., Geiger, N. (2000). Rotational molding of plastics: Comparison of simulation and experimental results for an axisymmetric mold. Polymer Engineering & Science. 40(8), 1758-1764. https://doi.org/10.1002/pen.11307
dc.relation.referencesen5. Hashmi, S. A. R., Dwivedi, U. K. (2006). Estimation of Concentration of Particles in Polymerizing Fluid during Centrifugal Casting of Functionally Graded Polymer Composites. Journal of Polymer Research, 14(1), 75-81. doi:10.1007/s10965-006-9083-5.
dc.relation.referencesen6. Stabik, J., Dybowska, A., Pluszyñski, J., Szczepanik, M., Suchoñ, £. (2010). Magnetic induction of polymer composites filled with ferrite powders. Archives of Materials Science and Engineering, 41(1), 13-20
dc.relation.referencesen7. Jachowicz, T., Sikora, J. (2013). Investigation of the influence of mold rotational speed on the cast wall thickness in the rotational molding process. Advances in Science and Technology Research Journal, 7(19), 79-87. DOI: 10.5604/20804075.1062380
dc.relation.referencesen8. Zhang, H., Zhang, L., Chen, X., Wang, Y., Zhao, F., Luo, M., Liao, S. (2020). The Role of Non-Rubber Components on Molecular Network of Natural Rubber during Accelerated Storage. Polymers, 12, 2880. https://doi.org/10.3390/polym12122880
dc.relation.referencesen9. Funabashi, M. (1997). Gradient composites of nickel coated carbon fibre filled epoxy resin moulded under centrifugal force. Composites Part A, 28, 731-737. https://doi.org/10.1016/S1359-835X(97)00016-X
dc.relation.referencesen10. Calò, E., Massaro, C., Terzi, R. (2012). Rotational Molding of Polyamide-6 Nanocomposites with Improved Flame Retardancy. International Polymer Processing, 27, 370-377. https://doi.org/10.3139/217.2552
dc.relation.referencesen11. Wang, F., Yao, W.G., Qiao, C.D., Jia, Y.X. (2012). Finite element analysis of the physical gelation process of PVC plastisol during rotational molding. Acta Polymerica Sinica, 9, 1035-1041.DOI:10.3724/SP.J.1105.2012.12081
dc.relation.referencesen12. Rusu, M., Ibanescu, C., Murariu, M., Bordeianu, A., Balint, S., Andrei, E. (1998). Centrifugal Casting of Polyamide 6. Influence of Thermal Treatment. Polymers and Polymer Composites, 6(3), 143-146. doi:10.1177/147823919800600303
dc.relation.referencesen13. Martens T. (2011). Use of Fused Deposition Modeling of Polyphenylsulfone for Centrifugal Casting of Polyurethane: Material, Surface, and Process Considerations. Journal of manufacturing science and engineering, 133(5), 0510031-051003.10. https://doi.org/10.1115/1.4004848
dc.relation.referencesen14. Stabik, J., Dybowska, A., Chomiak, M. (2010). Polymer composites filled with powders as polymer graded materials. Journal of Achievements in Materials and Manufacturing Engineering, 43(1), 153-161
dc.relation.referencesen15. Watanabe, Y., Kawamoto, A., Matsuda, K. (2002). Particle size distributions in functionally graded materials fabricated by the centrifugal solid-particle method. Composites Science and Technology, 62, 881-888. https://doi.org/10.1016/S0266-3538(02)00023-4
dc.relation.referencesen16. Kaelble, D. H. (1965). Spin casting of polymer films. Journal of Applied Polymer Science, 9(4), 1209-1212. doi:10.1002/app.1965.070090402.
dc.relation.referencesen17. Suberlyak, O., Grytsenko, O., Kochubei, V. (2015). The role of FeSO4 in the obtaining of polyvinylpirolidone copolymers. Chemistry & Chemical Technology, 9, 429-434. doi: https://doi.org/10.23939/chcht09.04.429.
dc.relation.referencesen18. Grytsenko, O., Dulebova, L., Suberlyak, O., Skorokhoda, V., Spišák, E., Gajdos, I. (2020). Features of structure and properties of pHEMA-gr-PVP block copolymers, obtained in the presence of Fe2+. Materials, 13(20), 4580-4594. https://doi.org/10.3390/ma13204580
dc.relation.referencesen19. Suberlyak, O. V., Skorokhoda, V. Y.,Grytsenko O. M. (2000). Naukovi aspekty rozroblennya tekhnolohiyi syntezu hidrofilʹnykh kopolimeriv polivinilpirolidonu. Voprosy khymyy i khymycheskoy tekhnolohyy, 1, 236-238
dc.relation.referencesen20. Grytsenko, O. M., Skorokhoda, V. Y., Shapoval, P. Y., &Bukhvak, I. V. (2000). Doslidzhennya pryshcheplenoyi polimeryzatsiyi na PVP, initsiyovanoyi solyamy metaliv zminnoyi valentnosti. Visnyk Derzhavnoho univesytetu "Lvivska politekhnika", 414, 82-85. Retrieved from: http://ena.lp.edu.ua/bitstream/ntb/8974/1/25.pdf
dc.relation.referencesen21. Grytsenko, O. M., Skorokhoda, V. Y., Yadushynsʹkyy, R. Y. (2004). Strukturni parametry ta vlastyvosti kopolimeriv 2-OEMA-PVP, oderzhanykh v prysutnosti Fe2+. Visnyk Natsionalʹnoho universytetu "Lvivska politekhnika", 488, 300-303. Retrieved from: http://ena.lp.edu.ua/bitstream/ntb/12009/1/45.pdf
dc.relation.referencesen22. Grytsenko, O., Jachowicz, T., Suberlyak, O., Krasinskyi, V. Development of equipment for the production of hydrogel films by centrifugal molding. Advanced technologies in designing, engineering and manufacturing research problems. Monography. Lublin, 2015, 29-42.
dc.relation.referencesen23. Suberlyak, O., Grytsenko, O., Hischak, K., Hnatchuk, N. (2013). Researching influence the nature of metal on mechanism of synthesis polyvinilpyrrolidone metal copolymers. Chemistry & chem. Tecnology, 7(3), 289-294. https://doi.org/10.23939/chcht07.03.289
dc.relation.referencesen24. Grytsenko, O., Suberlak, O., Gajdoš, I., Fedasiuk, D. The features of film composite hydrogel materials obtaining technology by centrifugal molding. Technological and design aspects of extrusion and injection moulding of thermoplastic polymer composites and nanocomposites. Monography. Volume II: Kosice, 2014, 213-230.
dc.relation.referencesen25. Grytsenko, O. M., Suberlyak, O. V., Pokhmursʹka, A. V., Bedlʹovsʹka, Kh. M., Gaydos I. (2017). Osoblyvosti utvorennya poverkhni metalonapovnenykh hidrohelevykh plivok, oderzhanykh vidtsentrovym formuvannyam. Visnyk Natsionalʹnoho universytetu "Lvivska politekhnika", 868, 381-387.
dc.relation.referencesen26. Grytsenko, O., Suberlyak, O., Krasinskyi, V., Moravskyi, V., Berezhnyy, B. (2019). Physical-mechanical properties of metal-filled hydrogel films, obtained by centrifugal molding. Acta Mechanica Slovaca, 23(3), 18-23. DOI: 10.21496/ams.2019.024
dc.relation.referencesen27. Grytsenko, O.M., Suberlyak, O.V., Pokhmursʹka, A.V., Krasinsʹkyy, V.V., Voloshkevych, P.P. (2018). Zakonomirnosti vidtsentrovoho utvorennya metalonapovnenykh hidrohelevykh plyvok. Chemistry, Technology and Application of Substances, 1(2), 149-156. https://doi.org/10.23939/ctas2018.02.149
dc.relation.urihttps://doi.org/10.1016/C2014-0-03688-X
dc.relation.urihttps://doi.org/10.3139/9781569905609
dc.relation.urihttps://doi.org/10.3139/9781569906484
dc.relation.urihttps://doi.org/10.1002/pen.11307
dc.relation.urihttps://doi.org/10.3390/polym12122880
dc.relation.urihttps://doi.org/10.1016/S1359-835X(97)00016-X
dc.relation.urihttps://doi.org/10.3139/217.2552
dc.relation.urihttps://doi.org/10.1115/1.4004848
dc.relation.urihttps://doi.org/10.1016/S0266-3538(02)00023-4
dc.relation.urihttps://doi.org/10.23939/chcht09.04.429
dc.relation.urihttps://doi.org/10.3390/ma13204580
dc.relation.urihttp://ena.lp.edu.ua/bitstream/ntb/8974/1/25.pdf
dc.relation.urihttp://ena.lp.edu.ua/bitstream/ntb/12009/1/45.pdf
dc.relation.urihttps://doi.org/10.23939/chcht07.03.289
dc.relation.urihttps://doi.org/10.23939/ctas2018.02.149
dc.rights.holder© Національний університет “Львівська політехніка”, 2024
dc.subjectвідцентрове формування
dc.subjectкомпозиційні гідрогелі
dc.subjectкополімери
dc.subjectполівінілпіролідон
dc.subject2-гідроксіетилметакрилат
dc.subjectcentrifugal molding
dc.subjectcomposite hydrogels
dc.subjectcopolymers
dc.subjectpolyvinylpyrrolidone
dc.subject2-hydroxyethylmethacrylate
dc.titleTechnological features of the formation of film products from modified hydrogels by the centrifugal method.
dc.title.alternativeТехнологічні особливості формування плівкових виробів з модифікованих гідрогелів відцентровим методом
dc.typeArticle

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