Evaporation thermodynamics for solutions of dimethylzinc and dimethyltelluride

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dc.citation.epage46
dc.citation.issue2
dc.citation.journalTitleChemistry, Technology and Application of Substances
dc.citation.spage37
dc.contributor.affiliationНаціональний університет “Львівська політехніка”
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.authorГерасимчук, С. І.
dc.contributor.authorПолюжин, І. П.
dc.contributor.authorОлійник, Л. П.
dc.contributor.authorГнатів, Т. Б.
dc.contributor.authorGerasymchuk, S. I.
dc.contributor.authorPoliuzhyn, I. P.
dc.contributor.authorOliynyk, L. P.
dc.contributor.authorHnativ, T. B.
dc.coverage.placenameLviv
dc.coverage.placenameLviv
dc.date.accessioned2025-03-05T07:39:19Z
dc.date.created2005-03-01
dc.date.issued2005-03-01
dc.description.abstractУ роботі за допомогою статичного методу із мембранним нуль-манометром експериментально досліджено рівновагу рідина – пара в системі “диметилцинк – диметилтелурид” у діапазоні температур 270–360 К із вмістом диметилцинку 50,00 та 70,32 % моль. Загальний тиск пари виміряно для обох ділянок як насиченої, так і ненасиченої пари та для різних наважок. Встановлено, що ці розчини не є азеотропними. Використовуючи рівняння стану PV = nRT, за даними термічного розширення ненасиченої пари розрахували середню молекулярну масу пари сумішей “диметилцинк – диметилтелурид” вищевказаного складу. Результати цього розрахунку вказують на відсутність істотної асоціації молекул компонентів розчину в газовій фазі.
dc.description.abstractIn the work with the help of a static method with a membrane zero-manometer, the liquid- vapor balance in the system “dimethylzinc – dimethyl telluride” in the temperature range 270– 360 K with the content of dimethylzinc as 50.00 and 70.32 % mol. The total vapor pressure was measured for both saturated and unsaturated vapors for different samples. It was found that these solutions are not azeotropic. Using the equation of state PV = nRT, according to the thermal expansion of unsaturated vapor, the average molecular weight was calculated for mixtures “dimethylzinc – dimethyltelluride” mentioned compositions. The results of this calculation indicate the absence of significant association between molecules of the solution components in the gas phase.
dc.format.extent37-46
dc.format.pages10
dc.identifier.citationEvaporation thermodynamics for solutions of dimethylzinc and dimethyltelluride / S. I. Gerasymchuk, I. P. Poliuzhyn, L. P. Oliynyk, T. B. Hnativ // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2022. — Vol 5. — No 2. — P. 37–46.
dc.identifier.citationenEvaporation thermodynamics for solutions of dimethylzinc and dimethyltelluride / S. I. Gerasymchuk, I. P. Poliuzhyn, L. P. Oliynyk, T. B. Hnativ // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2022. — Vol 5. — No 2. — P. 37–46.
dc.identifier.doidoi.org/10.23939/ctas2022.02.037
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/63662
dc.language.isoen
dc.publisherLviv Politechnic Publishing House
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry, Technology and Application of Substances, 2 (5), 2022
dc.relation.ispartofChemistry, Technology and Application of Substances, 2 (5), 2022
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dc.relation.referencesen1. Comprehensive Inorganic Chemistry II From Elements to Applications 2nd Edition - July 23, 2013. Write a review Editors-in-Chief: Jan Reedijk, Kenneth Poeppelmeier eBook. ISBN: 9780080965291.
dc.relation.referencesen2. Chasteen, T. G.; Bentley, R. (2003). Biomethylation of Selenium and Tellurium: Microorganisms and Plants. Chemical Reviews. 103 (1): 1-26. DOI: https://doi.org/10.1021/cr010210
dc.relation.referencesen3. Nguyen, H. P., Su, J., Wang, Z., Vullers, R. J., Vereecken, P. M., & Fransaer, J. (2011). Investigation of dimethyl sulfoxide electrolytes for electrodepositing thermoelectric bismuth telluride films. ECS Transactions, 33(18), 75-80. https://doi.org/10.1149/1.3551493
dc.relation.referencesen4. Singh, H. B., & Sudha, N. (1996). Organotellurium precursors for metal organic chemical vapour deposition (MOCVD) of mercury cadmium telluride (MCT). Polyhedron, 15(5-6), 745-763. DOI: https://doi.org/10.1016/0277-5387(95)00249-X
dc.relation.referencesen5. Afzaal, M., Malik, M. A., & O'Brien, P. (2007). Preparation of zinc containing materials. New Journal of Chemistry, 31 (12): 2029-2040. DOI: https://doi.org/10.1039/b712235g
dc.relation.referencesen6. Gerasimchuk, S. I., Pavlovskii, Y. P., & Van-Chin-Syan, Y. Y. (2012). Thermodynamics of the evaporation of dimethylzinc, dimethylselenium, and their equimolecular solutions. Russian Journal of Physical Chemistry A, 86(10), 1500-1506. DOI: https://doi.org/10.1134/S003602441210010X
dc.relation.referencesen7. Gerasimchuk, S. I., Pavlovskii, Y. P., Sobechko, I. B., & Van-Chin-Syan, Y. Y. (2014). Thermodynamics of the vaporization of alkyl compounds of zinc, selenium, cadmium, tellurium, and their equimolecular solutions. Russian Journal of Physical Chemistry A, 88(3), 365-371. DOI: https://doi.org/10.1134/S0036024414030054
dc.relation.referencesen8. Gerasymchuk, S. I., Poliuzhyn, I. P., Melnyk, H. V., Pavlovskyi, Yu. P., Sergeyev, V. V. (2019). Phase vapor - liquid equilibrium for the solu- tions of dimethylzinc and dimethyl selenide. Chemis- try, Technology and Application of Substances. Vol. 2, No. 2, 1-6. DOI: https://doi.org/10.23939/ctas2019.02.001
dc.relation.referencesen9. Herasymchuk, S. I., Poliuzhyn, I. P., Melnyk, H. V., Pavlovskyi, Yu. P., Serheiev, V. V. (2020). Fazova rivnovaha para-ridyna rozchyniv dymetylteluru ta dymetylkadmiiu. Visnyk Natsio- nalnoho universytetu "Lvivska politekhnika". Khimi- ia, tekhnolohiia rechovyn ta yikh zastosuvannia.Vol. 3, No. 1, 1-8. DOI: https://doi.org/10.23939/ctas2020.01.001
dc.relation.referencesen10. Poling, B. E., Prausnitz, J. M., & OConnell, J. P. (2001). The properties of gases and liquids. New York: McGraw.
dc.relation.referencesen11. Naryshkin, D. G. (2016). Himicheskaja termodinamika s Mathcad. Moskva: RIOR: INFRA-M.
dc.relation.referencesen12. Hala, E., Pick, J., Fried, V. & Vilim, O. (1967). Vapour-Liquid Equilibrium Pergamon Press London-New York - Paris - Los Ageles.
dc.relation.referencesen13. Glantz, S. A., Slinker, B. K., Neilands, T. B. (2016). Primer of applied regression and analysis of variance [3 ed.]. McGraw-Hill.
dc.relation.referencesen14. Seber, G., Lee, A. (2003). Linear regression analysis. Publisher: Wiley. https://doi.org/10.1002/9780471722199
dc.relation.referencesen15. Suvorov, A. V. (1970). Termodinamiches- kaya khimiya paroobraznogo sostoyaniya. Lening- rad: Himija.
dc.relation.urihttps://doi.org/10.1021/cr010210
dc.relation.urihttps://doi.org/10.1149/1.3551493
dc.relation.urihttps://doi.org/10.1016/0277-5387(95)00249-X
dc.relation.urihttps://doi.org/10.1039/b712235g
dc.relation.urihttps://doi.org/10.1134/S003602441210010X
dc.relation.urihttps://doi.org/10.1134/S0036024414030054
dc.relation.urihttps://doi.org/10.23939/ctas2019.02.001
dc.relation.urihttps://doi.org/10.23939/ctas2020.01.001
dc.relation.urihttps://doi.org/10.1002/9780471722199
dc.rights.holder© Національний університет “Львівська політехніка”, 2022
dc.subjectдиметилцинк – диметилтелурид
dc.subjectрозчин
dc.subjectтиск пари
dc.subjectсередня молекулярна маса
dc.subjectстатичний тензиметричний метод
dc.subjectdimethylzinc
dc.subjectdimethyltelluride
dc.subjectsolution
dc.subjectvapor pressure
dc.subjectaverage molecular weight
dc.subjectstatic tensimetric method
dc.titleEvaporation thermodynamics for solutions of dimethylzinc and dimethyltelluride
dc.title.alternativeТермодинаміка випаровування розчинів диметилцинку та диметилтелуриду
dc.typeArticle

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Chemistry, Technology and Application of Substances. – 2022. – Vol. 5, No. 2