Synthesis, properties and application of amphiphilic copolymers based on poly(fluoroalkylmethacrylate)s with terminal peroxide group

Date
2017-12-23
Authors
Paiuk, Olena
Volianiuk, Kateryna
Sobko, Iryna
Nadashkevych, Zoriana
Mitina, Nataliya
Zaichenko, Olexandr
Journal Title
Journal ISSN
Volume Title
Publisher
Видавництво Львівської політехніки
Lviv Polytechnic Publishing House
Abstract
Polymers with terminal peroxide fragment were synrhesized via radical polymerization of fluoroalkyl methacrylates. Amphiphilic block-copolymers with hydrophilic block of different structure were synthesized by usage of obtained polymers with terminal peroxide group as macroinitiators. Kinethic peculiarities of polymerization were studied on both stages. The strucrure of polymers were confirmed by IR- and NMR-spectroscopy.
Description
Keywords
fluoroalkyle methacrylate , peroxide group , radical polymerization , controlled synthesis
Citation
Synthesis, properties and application of amphiphilic copolymers based on poly(fluoroalkylmethacrylate)s with terminal peroxide group / Olena Paiuk, Kateryna Volianiuk, Iryna Sobko, Zoriana Nadashkevych, Nataliya Mitina, Olexandr Zaichenko // Litteris et Artibus : proceedings, 23–25 November, 2017. — Lviv : Lviv Polytechnic Publishing House, 2017. — P. 50–51. — (6th International academic conference «Chemistry & chemical technology 2017» (CCT-2017)).