Chemistry & Chemical Technology. – 2010. – Vol. 4, No. 3

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The scientific-technical journal

It is the scientific-technical journal in English in Ukraine discussing actual problems of chemistry and chemical technology. Compared with other chemical journals Ch&ChT is publishing materials of both theoretical and practical values in such fields as analytical, general organic, physical and inorganic chemistry; chemistry of high molecular compounds; materials science and engineering; chemical kinetics and catalysis; technology of inorganic substances; technology of organic synthesis products; chemical technology of processing of combustible minerals; processes and apparatus of chemical and food productions; biotechnology and ecology.

Chemistry & Chemical Technology : [the scientific-technical journal] / Lviv Polytechnic National University ; editor-in-chief M. Bratychak. – Lviv : Publishing House of Lviv Polytechnic National University, 2010. – Volume 4, number 3. – P. 167–260, IV : ill.

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    UV curable heat resistant epoxy acrylate coatings
    (Publishing House of Lviv Polytechnic National University, 2010) Firdous, Habib; Bajpai, Madhu
    Polymeric materials are exposed to high temperatures that results in lowering of the film integrity. A blend of an epoxy resin with the silicone acrylate resin was developed to provide high heat resistance UV cured coatings. Earlier siliconized epoxy coatings had been developed by conventional curing. But due to environmental awareness, high productivity rate, low process costs and energy saving UV curable coatings are enjoying considerable growth. Thermally stable UV cured coatings used in the present study were developed from silicone acrylate and epoxy acrylate resin with different diluents and photoinitiator. Such coatings provide higher thermal stability (693 K) along with physical and chemical resistance. In addition, such coatings can also be obtained by using functional amino silanes. The resin developed provides a simple and practical solution to improve heat resistance along with physical and chemical resistance of the UV cured coatings. The purpose of this research paper is to develop UV curable heat resistant coatings by the combination of inorganic and organic polymer, taking epoxy acrylate as a base resin. В роботі вивчено отримання термостабільних УФ-затверджених покриттів, виходячи з силікон-акрилатів та епоси-акрилатних смол, в присутності різних за природою розчинників іфотоініціаторів. Встановлено, що такі покриття характеризуються високою термостабільністю (693 К) та проявляють фізичну і хімічну стійкість. Запропонований метод дає можливість отримувати термостійкі покриття, виходячи як із органічного, так і неорганічного полімеру, в тому числі функцій них аміносиланів, беручи за основу епоксидний акрилат.