Chemistry & Chemical Technology. – 2012. – Vol. 6, No. 3

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The scientific-technical journal

It is the scientific-technical journal in English in Ukraine discussing actual problems of chemistry and chemical technology. Compared with other chemical journals Ch&ChT is publishing materials of both theoretical and practical values in such fields as analytical, general organic, physical and inorganic chemistry; chemistry of high molecular compounds; materials science and engineering; chemical kinetics and catalysis; technology of inorganic substances; technology of organic synthesis products; chemical technology of processing of combustible minerals; processes and apparatus of chemical and food productions; biotechnology and ecology.

Chemistry & Chemical Technology : [the scientific-technical journal] / Lviv Polytechnic National University ; editor-in-chief M. Bratychak. – Lviv : Publishing House of Lviv Polytechnic National University, 2012. – Volume 6, number 3. – P. 237–354, IV : ill.

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Author: search.filters.author.Matienko, LudmilaSubject: search.filters.subject.oxidation

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    The selective ethylbenzene oxidation by dioxygen into α-phenyl ethyl hydroperoxide, catalyzed with triple catalytic system {NiII(acac)2+NaSt(LiSt)+PhOH}. Formation of nanostructures {NiII(acac)2·NaSt·(PhOH)}n with assistance of intermolecular H-bonds
    (Publishing House of Lviv Polytechnic National University, 2012) Matienko, Ludmila; Binyukov, Vladimir; Mosolova, Larisa; Zaikov, Gennady
    The role of intra- and intermolecular H-bonds in mechanisms of catalysis with triple heterobinuclear hetero ligand complexes NiII(acac)2∙NaSt(LiSt)∙PhOH, including nickel and redox-inactive metal Na(Li), in the ethylbenzene oxidation by dioxygen into a-phenyl ethyl hydroperoxide is discussed. The AFM method has been used for research of the stable supramolecular nanostructures formation possibility on the basis of triple complex NiII(acac)2∙NaSt∙PhOH, with the assistance of intermolecular H-bonds. Розглянуто роль внутрішньо- та міжмолекулярних Н-зв‘язків в механізмах каталізу потрійними гетеро-біядерними гетеролігандними комплексами NiII(acac)2∙ NaSt(LiSt)∙PhOH, які включають нікель і редокс-неактивний метал Na(Li), в реакціях окиснення етилбензолу молекулярним киснем в a-фенілетилгідропероксид. З використанням методу атомно-силової мікроскопії досліджено можливість формування стабільних супрамолекулярних наноструктур на основі потрійного комплексу NiII(acac)2∙NaSt∙PhOH, за допомогою міжмолекулярних Н-зв‘язків.