Хімія та хімічні технології
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Item Catalytic Cyclohexane Oxidation In The Presence Of Alcohols Of Different Nature(Видавництво Львівської політехніки, 2013) Suprun, Oleksandr; Reutskyy, Viktor; Ivashchuk, Oleksandr; Mudryy, SergiyQuantitative and qualitative influence of binary catalytic systems [cobalt naphthenate – alcohol] in liquidphase homogeneous-catalytic oxidation of cyclohexane was considered.Item Effect of nitrogen- and oxygen-containing additives on the efficiency of the catalytic oxidation of cyclohexane(Видавництво Львівської політехніки, 2013) Mudryy, Sergiy; Reutskyy, Victor; Ivashchuk, Oleksandr; Suprun, OleksandrThe research of influence of oxygen- and nitrogen- containing organic catalytic additives to the general parameters of the process of cyclohexane oxidation have been conducted. Investigated additives can change the composition of the products of oxidation and the ratio between them.The most effective additives was bis-2-cyanethyl ether and polyethylene glycol with a molecular weight of 400 g/mole. This effect is explained by research results of IR- spectra. With the use of modern computer technology built spatial model of intermediate active complex consisting of organic additives and cobalt naphthenate.