Effect of nitrogen- and oxygen-containing additives on the efficiency of the catalytic oxidation of cyclohexane

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Date

2013

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Видавництво Львівської політехніки

Abstract

The research of influence of oxygen- and nitrogen- containing organic catalytic additives to the general parameters of the process of cyclohexane oxidation have been conducted. Investigated additives can change the composition of the products of oxidation and the ratio between them.The most effective additives was bis-2-cyanethyl ether and polyethylene glycol with a molecular weight of 400 g/mole. This effect is explained by research results of IR- spectra. With the use of modern computer technology built spatial model of intermediate active complex consisting of organic additives and cobalt naphthenate.

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Keywords

oxidation, cyclohexane, catalyst, additive, cyclohexanol, cyclohexanone, homogeneous, acid, peroxide, ether

Citation

Effect of nitrogen- and oxygen-containing additives on the efficiency of the catalytic oxidation of cyclohexane / Sergiy Mudryy, Victor Reutskyy, Oleksandr Ivashchuk, Oleksandr Suprun // Хімія та хімічні технології : матеріали IІI Міжнародної конференції молодих вчених CCT-2013, 21–23 листопада 2013 року, Україна, Львів / Національний університет "Львівська політехніка". – Львів : Видавництво Львівської політехніки, 2013. – С. 20–23. – (4-й Міжнародний молодіжний фестиваль науки "Litteris et Artibus"). – Bibliography: 13 titles.

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