Environmental Problems

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Author: search.filters.author.Sabadash, ViraSubject: search.filters.subject.ammonium

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    Simulation of ion exchange interaction kinetics in the clinoptylolite – ammonium ion system
    (Видавництво Львівської політехніки, 2021-06-01) Sabadash, Vira; Gumnitsky, Jaroslaw; Omelyanova, Sofia; Lviv Polytechnic National University
    The kinetics of adsorption of ammonium ions under dynamic conditions has been studied. A mathematical model of the process was built. The mass transfer coefficient was calculated depending on the intensity of the change of location. It was established that ion exchange occurs in external and internal diffusion regions. The rate constants of ion exchange for the region of external and internal diffusion were calculated.
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    Investigation of the process of ammonium ion adsorption by natural and synthetic sorbents by methods of multidimensional cluster analysis
    (Видавництво Львівської політехніки, 2020-02-10) Sabadash, Vira; Gumnitsky, Yaroslav; Liuta, Oksana; Lviv Polytechnic National University
    The results of the research of the adsorption capacity of a number of sorbents of natural and synthetic origin for ammonium ions have been clustered. The natural zeolite of the Sokyrnytsia deposit, a synthetic sorbent based on the fly ash of Dobrotvir state district heat power plant, Al2O3, SiO2, as well as some types of soil: sandy soil, black soil, and clay were used in the research. Equations describing the regularities of adsorption processes depending on the type of sorbent were obtained. According to the obtained dendrograms, two main clusters of sorbents were identified. The statistical parameters of the process and the significance of the obtained results were calculated. The coefficient of determination of the experimental data was 0.67–0.99, the standard deviation was 0.017–0.026.
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    Complex water treatment of agroindustrial complexes
    (Publishing House of Lviv Polytechnic National University, 2016) Sabadash, Vira; Gumnitsky, Jaroslav; Tyzrbir, Galyna
    The aim of this work was studying the process of phosphate adsorption on natural and synthesized adsorbents such as aluminosilicates. Sorption properties of natural zeolite concerning phosphates in static and dynamic conditions were investigated. It was found that phosphates were absorbed better in an acidic environment. Zeolites based on fly ashes of Dobrotvir heat power plant were synthesized and modified. The equilibrium values of adsorption capacity were established and the proper isotherms at a temperature 20 °C were built.