The Effect of Composition and Structure of NBR-Based Elastomer Blends in the Vulcanization Process and Study of Their Aging by Exposure to Heat and Radiation

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dc.citation.epage835
dc.citation.issue4
dc.citation.spage829
dc.contributor.affiliationMinistry of Science and Education Republic of Azerbaijan, Institute of Radiation Problems
dc.contributor.affiliationAzerbaijan State Oil and Industry University
dc.contributor.authorMammadov, Shiraz
dc.contributor.authorAzizova, Gunel
dc.contributor.authorMammadova, Gunel
dc.contributor.authorKhankishiyeva, Rana
dc.contributor.authorMovlayev, Ibrahim
dc.contributor.authorMammadov, Jovdat
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2025-03-05T08:54:10Z
dc.date.created2023-02-28
dc.date.issued2023-02-28
dc.description.abstractДосліджено процес вулканізації еластомерних сумішей на основі хлорованого ароматичного нітрил-бутадієнового каучуку (СКН-40М). На прикладі суміші бутадієн-нітрильного каучуку з полівінілхлоридом досліджено структурні параметри (молекулярна маса, пластичність, жорсткість, кількість ланцюгів сітки, зшиті молекули) в термовулканізатах за допомогою віскозиметрії та золь-гель процесу.
dc.description.abstractThe vulcanization process of elastomeric blends based on chlorinated aromatic nitrile-butadiene rubber (SKN-40M) has been studied in the present work. The structural parameters (molecular weight, plasticity, rigidity, number of network chains, cross-linked molecules) in thermovulcanizates were investigated on an example of nitrile-butadiene rubber blend with polyvinyl chloride using viscometry and the sol-gel process.
dc.format.extent829-835
dc.format.pages7
dc.identifier.citationThe Effect of Composition and Structure of NBR-Based Elastomer Blends in the Vulcanization Process and Study of Their Aging by Exposure to Heat and Radiation / Shiraz Mammadov, Gunel Azizova, Gunel Mammadova, Rana Khankishiyeva, Ibrahim Movlayev, Jovdat Mammadov // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2023. — Vol 17. — No 4. — P. 829–835.
dc.identifier.citationenThe Effect of Composition and Structure of NBR-Based Elastomer Blends in the Vulcanization Process and Study of Their Aging by Exposure to Heat and Radiation / Shiraz Mammadov, Gunel Azizova, Gunel Mammadova, Rana Khankishiyeva, Ibrahim Movlayev, Jovdat Mammadov // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2023. — Vol 17. — No 4. — P. 829–835.
dc.identifier.doidoi.org/10.23939/chcht17.04.829
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/63693
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 4 (17), 2023
dc.relation.references[1] Mammadov, Sh. Synthesis, Processing and Vulcanization of Butadiene-Nitrile Rubbers; Lap Lambert Academic Publishing, 2015.
dc.relation.references[2] Mammadov, Sh. Nitrile Butadiene Rubbers and Rubbers Based on them; Elm Press, 2001.
dc.relation.references[3] Rahimova, S.A.; Khankishiyeva, R.F.; Amirov, F.A.; Movlayev, I.H.; Mammadov, Sh.M.; Mammadova, G.A.; Ismayilova, P.I. Modification of Isoprene Rubber with High Molecular Weight Compounds in Mixtures. Func. Mater. 2022, 29, 371–376. https://doi.org/10.15407/fm29.03.371.
dc.relation.references[4] Coran, A.Y. Vulcanization. In The Science and Technology of Rubber, 3rd ed.; Mark, J.E.; Erman, B.; Eirich, F.R., Eds.; Elsevier: Amsterdam, 2005; pp 321–366.
dc.relation.references[5] Onishchenko, E.V. Modification of Elastomers with Hydroxyl and Amino Compounds; Naukova Dumka: Kyiv, 2002.
dc.relation.references[6] White, J.R.; De, S.K. Rubber Technologist’s Handbook; Rapra Technology Limited: Shawbury, Shrewsbury, Shropshire, UK, 2001.
dc.relation.references[7] Klingender, R.C. Handbook of Specialty Elastomers; CRC Press: USA, 2008.
dc.relation.references[8] Jiri, G.D. Handbook of Thermoplastic Elastomer; William Andrew Publishing: New York, 2007.
dc.relation.references[9] Elias, H.-G. Macromolecules. Physical Structure and Properties; Wiley VCH: Weinheim, 2008.
dc.relation.references[10] Bellamy, L.J. The Infra-red Spectra of Complex Molecules; Springer Dordrecht: London, 2013.
dc.relation.references[11] Mark, J.E.; Erman, B.; Roland, C.M. The Science and Technology of Rubber. Academic Press: Berlin, 2013.
dc.relation.references[12] Mammadov, Sh.M.; Rahimova, S.A.; Khankishiyeva, R.F.; Ismayilova, P.I.; Movlayev, I.T.; Mammadov, J.Sh. Features of the Structure and Properties of Compositions of Modified Isoprene Rubber with Chloride-Containing and Epoxy Compounds. Azerbaijan Chem. J. 2023, 1, 129–134. doi.org/10.32737/0005-2531-2023-1-129-134
dc.relation.references[13] Heinrich, G.; Kipscholl, R.; Stoček, R. Degradation of Elastomers in Practice. Experiments and Modeling; Springer, 2022.
dc.relation.references[14] Sisanth, K.S.; Thomas, M.G.; Abraham, J.; Thomas, S. 1 – General introduction to rubber compounding. In Progress in Rubber Nanocomposites; Thomas, S.; Maria, H.J., Eds.; Woodhead Publishing, 2017.
dc.relation.references[15] Zhao, J.; Yang, R.; Iervolino, R.; Barbera, S. Changes of Chemical Structure and Mechanical Property Levels During Thermo-Oxidative Aging of NBR. Rubber Chem. Technol. 2013, 86, 591–603. https://doi.org/10.5254/RCT.13.87969
dc.relation.references[16] Andrew, T.; Jones, K.P. Improving the Morphology and Properties of NR/NBR Blends with Polychloroprene as the Compatibilizing Agent; Springer-Verlag, 1998.
dc.relation.references[17] Budrugeac, P. Accelerated Thermal Aging of NBR and other Materials under Air or Oxygen Pressures. Die Angewandte Makromolekulare Chemie 2007, 247.
dc.relation.references[18] Vishnevskii, K.; Shashok, Z.; Prokopchuk, N. Some Properties of Elastomeric Compositions with High-Dispersed Carbon Additives. Chem. Chem. Technol. 2016, 10, 305–310. https://doi.org/10.23939/chcht10.03.305
dc.relation.references[19] Livanova, N.; Karpova, S.; Zaikov, G. The Structure of Acrylonitrile-Butadiene Rubbers: Paramagnetic-Probe Study. Chem. Chem. Technol. 2013, 7, 69–72. https://doi.org/10.23939/chcht07.01.069
dc.relation.references[20] Barlow, F.W. Rubber Compounding. Principles: Materials, and Techniques; CRC Press: Boca Raton, 1993.
dc.relation.references[21] Lipatov, Y.S. Fizika khimiya mnoqokomponentnykh system; Naukova Dumka: Kiev, 1998.
dc.relation.references[22] Przybyszewska, M.; Zaborski, M.; Jakubowski, B.; Zawadiak, J. Zinc Chelates as New Activators for Sulphur Vulcanization of Acrylonitrile-Butadiene Elastomer. Express Polym. Lett. 2009, 3, 256–266. https://doi.org/10.3144/expresspolymlett.2009.32.
dc.relation.references[23] Mamedov, Sh.M.; Garibov, A.A. Radiation Physics and Chemistry of Polymers; LAP LAMBERT Academic Publishing: Baku, 2015.
dc.relation.referencesen[1] Mammadov, Sh. Synthesis, Processing and Vulcanization of Butadiene-Nitrile Rubbers; Lap Lambert Academic Publishing, 2015.
dc.relation.referencesen[2] Mammadov, Sh. Nitrile Butadiene Rubbers and Rubbers Based on them; Elm Press, 2001.
dc.relation.referencesen[3] Rahimova, S.A.; Khankishiyeva, R.F.; Amirov, F.A.; Movlayev, I.H.; Mammadov, Sh.M.; Mammadova, G.A.; Ismayilova, P.I. Modification of Isoprene Rubber with High Molecular Weight Compounds in Mixtures. Func. Mater. 2022, 29, 371–376. https://doi.org/10.15407/fm29.03.371.
dc.relation.referencesen[4] Coran, A.Y. Vulcanization. In The Science and Technology of Rubber, 3rd ed.; Mark, J.E.; Erman, B.; Eirich, F.R., Eds.; Elsevier: Amsterdam, 2005; pp 321–366.
dc.relation.referencesen[5] Onishchenko, E.V. Modification of Elastomers with Hydroxyl and Amino Compounds; Naukova Dumka: Kyiv, 2002.
dc.relation.referencesen[6] White, J.R.; De, S.K. Rubber Technologist’s Handbook; Rapra Technology Limited: Shawbury, Shrewsbury, Shropshire, UK, 2001.
dc.relation.referencesen[7] Klingender, R.C. Handbook of Specialty Elastomers; CRC Press: USA, 2008.
dc.relation.referencesen[8] Jiri, G.D. Handbook of Thermoplastic Elastomer; William Andrew Publishing: New York, 2007.
dc.relation.referencesen[9] Elias, H.-G. Macromolecules. Physical Structure and Properties; Wiley VCH: Weinheim, 2008.
dc.relation.referencesen[10] Bellamy, L.J. The Infra-red Spectra of Complex Molecules; Springer Dordrecht: London, 2013.
dc.relation.referencesen[11] Mark, J.E.; Erman, B.; Roland, C.M. The Science and Technology of Rubber. Academic Press: Berlin, 2013.
dc.relation.referencesen[12] Mammadov, Sh.M.; Rahimova, S.A.; Khankishiyeva, R.F.; Ismayilova, P.I.; Movlayev, I.T.; Mammadov, J.Sh. Features of the Structure and Properties of Compositions of Modified Isoprene Rubber with Chloride-Containing and Epoxy Compounds. Azerbaijan Chem. J. 2023, 1, 129–134. doi.org/10.32737/0005-2531-2023-1-129-134
dc.relation.referencesen[13] Heinrich, G.; Kipscholl, R.; Stoček, R. Degradation of Elastomers in Practice. Experiments and Modeling; Springer, 2022.
dc.relation.referencesen[14] Sisanth, K.S.; Thomas, M.G.; Abraham, J.; Thomas, S. 1 – General introduction to rubber compounding. In Progress in Rubber Nanocomposites; Thomas, S.; Maria, H.J., Eds.; Woodhead Publishing, 2017.
dc.relation.referencesen[15] Zhao, J.; Yang, R.; Iervolino, R.; Barbera, S. Changes of Chemical Structure and Mechanical Property Levels During Thermo-Oxidative Aging of NBR. Rubber Chem. Technol. 2013, 86, 591–603. https://doi.org/10.5254/RCT.13.87969
dc.relation.referencesen[16] Andrew, T.; Jones, K.P. Improving the Morphology and Properties of NR/NBR Blends with Polychloroprene as the Compatibilizing Agent; Springer-Verlag, 1998.
dc.relation.referencesen[17] Budrugeac, P. Accelerated Thermal Aging of NBR and other Materials under Air or Oxygen Pressures. Die Angewandte Makromolekulare Chemie 2007, 247.
dc.relation.referencesen[18] Vishnevskii, K.; Shashok, Z.; Prokopchuk, N. Some Properties of Elastomeric Compositions with High-Dispersed Carbon Additives. Chem. Chem. Technol. 2016, 10, 305–310. https://doi.org/10.23939/chcht10.03.305
dc.relation.referencesen[19] Livanova, N.; Karpova, S.; Zaikov, G. The Structure of Acrylonitrile-Butadiene Rubbers: Paramagnetic-Probe Study. Chem. Chem. Technol. 2013, 7, 69–72. https://doi.org/10.23939/chcht07.01.069
dc.relation.referencesen[20] Barlow, F.W. Rubber Compounding. Principles: Materials, and Techniques; CRC Press: Boca Raton, 1993.
dc.relation.referencesen[21] Lipatov, Y.S. Fizika khimiya mnoqokomponentnykh system; Naukova Dumka: Kiev, 1998.
dc.relation.referencesen[22] Przybyszewska, M.; Zaborski, M.; Jakubowski, B.; Zawadiak, J. Zinc Chelates as New Activators for Sulphur Vulcanization of Acrylonitrile-Butadiene Elastomer. Express Polym. Lett. 2009, 3, 256–266. https://doi.org/10.3144/expresspolymlett.2009.32.
dc.relation.referencesen[23] Mamedov, Sh.M.; Garibov, A.A. Radiation Physics and Chemistry of Polymers; LAP LAMBERT Academic Publishing: Baku, 2015.
dc.relation.urihttps://doi.org/10.15407/fm29.03.371
dc.relation.urihttps://doi.org/10.5254/RCT.13.87969
dc.relation.urihttps://doi.org/10.23939/chcht10.03.305
dc.relation.urihttps://doi.org/10.23939/chcht07.01.069
dc.relation.urihttps://doi.org/10.3144/expresspolymlett.2009.32
dc.rights.holder© Національний університет “Львівська політехніка”, 2023
dc.rights.holder© Mammadov Sh., Azizova G., Mammadova G., Khankishiyeva R., Movlayev I., Mammadov J., 2023
dc.subjectреологія
dc.subjectвулканізація
dc.subjectгексахлоропара-ксилен
dc.subjectнітрилбутадієновий каучук
dc.subjectзшивання
dc.subjectrheology
dc.subjectvulcanization
dc.subjecthexachloroparaxylene
dc.subjectnitrile butadiene rubber
dc.subjectcross-linking
dc.titleThe Effect of Composition and Structure of NBR-Based Elastomer Blends in the Vulcanization Process and Study of Their Aging by Exposure to Heat and Radiation
dc.title.alternativeВплив складу і структури сумішей еластомерів на основі БНК в процесі вулканізації та дослідження їхнього старіння під дією тепла і радіації
dc.typeArticle

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Chemistry & Chemical Technology. – 2023. – Vol. 17, No. 4