Solid Polymer Electrolyte Membranes on the Basis of Fluorosiloxane Matrix

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dc.citation.epage204
dc.citation.issue2
dc.citation.spage198
dc.contributor.affiliationIv. Javakhishvili Tbilisi State University
dc.contributor.authorMukbaniani, Omari
dc.contributor.authorAneli, Jimsher
dc.contributor.authorTatrishvili, Tamara
dc.contributor.authorMarkarashvili, Eliza
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2024-01-09T10:19:11Z
dc.date.available2024-01-09T10:19:11Z
dc.date.created2021-03-16
dc.date.issued2021-03-16
dc.description.abstractДосліджено реакції гідросилювання 2,4,6,8-тетрагідро-2,4,6,8-тетраметилциклотетрасилоксана (D4H) з 2,2,3,3,4,4,5,5-октафлуоропентил акрилатом у співвідношенні 1:4,2 в присутності платинового каталізатора и одержано відповідний адукт (D4R). В присутності безводного гідроксиду калию проведено полімеризацію D4R, внаслідок чого отримано відповідний комб-полімер з бічними групами 2,2,3,3,4,4,5,5-октафлуоропентил пропіонату. Синтезований продукт та полімери проаналізовано за допомогою методів Фур‘є-спектроскопії, 1H, 13C і 29Si спектроскопії. Тверді полімер-електролитні мембрани одержані за допомогою золь-гель реакцій полімерів з тетраетоксисиланом, допованим трифлуорометансульфонатом літію (трифлат) та біс(трифлуорометансульфонил)імідом літію. Встановлено, що електропровідність полімер-електролітних мембран за кімнатної температури знаходиться в межах (1,9•10-6)–5,9•10-10 См/см.
dc.description.abstractHydrosilylation reactions of 2,4,6,8-tetrahydro-2,4,6,8-tetramethylcyclotetrasiloxane (D4H) with 2,2,3,3,4,4,5,5-octafluoropentyl acrylate at 1:4.2 ratio of initial compounds catalysed by platinum catalysts have been studied and corresponding adduct D4 R' has been obtained. Ring opening polymerization of D4 R in the presence of dry potassium hydroxide has been carried out and comb-type polymers with 2,2,3,3,4,4,5,5-octafluoropentyl propionate side groups have been obtained. The synthesized product D4 R and polymers were analyzed by FTIR, 1H, 13C, and 29Si NMR spectroscopy. The solid polymer electrolyte membranes have been obtained via sol-gel reactions of polymers with tetraethoxysilane doped with lithium trifluoromethylsulfonate (triflat) and lithium bis(trifluorosulfonyl)imide. It has been found that the electric conductivity of the polymer electrolyte membranes at room temperature changes in the range of (1.9·10-6) – (5.9·10-10) S·cm -1.
dc.format.extent198-204
dc.format.pages7
dc.identifier.citationSolid Polymer Electrolyte Membranes on the Basis of Fluorosiloxane Matrix / Omari Mukbaniani, Jimsher Aneli, Tamara Tatrishvili, Eliza Markarashvili // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2021. — Vol 15. — No 2. — P. 198–204.
dc.identifier.citationenSolid Polymer Electrolyte Membranes on the Basis of Fluorosiloxane Matrix / Omari Mukbaniani, Jimsher Aneli, Tamara Tatrishvili, Eliza Markarashvili // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2021. — Vol 15. — No 2. — P. 198–204.
dc.identifier.doidoi.org/10.23939/chcht15.02.198
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/60727
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 2 (15), 2021
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dc.relation.urihttps://doi.org/10.1080/15583724.2015.1011966
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dc.relation.urihttps://doi.org/10.1016/j.nanoen.2017.01.028
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dc.relation.urihttps://doi.org/10.1016/j.ensm.2016.07.003
dc.relation.urihttps://doi.org/10.1016/j.electacta.2016.10.122
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dc.relation.urihttps://doi.org/10.1016/j.matlet.2013.08.062
dc.relation.urihttps://doi.org/10.1002/pola.1993.080311023
dc.relation.urihttps://en.wikipedia.org/wiki/Infrared
dc.relation.urihttps://doi.org/10.1039/B806290K
dc.rights.holder© Національний університет “Львівська політехніка”, 2021
dc.rights.holder© Mukbaniani O., Aneli J., Tatrishvili T., Markarashvili E., 2021
dc.subjectгідросилювання
dc.subjectполімеризація
dc.subjectзоль-гель реакції
dc.subjectтверді полімер-електролитні мембраны
dc.subjectспектроскопія
dc.subjectйонопровідність
dc.subjecthydrosilylation
dc.subjectpolymerization
dc.subjectsol-gel reactions
dc.subjectpolymer electrolyte membrane
dc.subjectspectroscopy
dc.subjection-conductivity
dc.titleSolid Polymer Electrolyte Membranes on the Basis of Fluorosiloxane Matrix
dc.title.alternativeТверді полімер-електролітні мембрани на основі флуоросилоксанової матриці
dc.typeArticle

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Chemistry & Chemical Technology. – 2021. – Vol. 15, No. 2