Argentinian Sugar Cane Vinasse: Characterization of Phenolic Compounds and Evaluation of Adsorption as a Possible Remediation Technique

dc.citation.epage491
dc.citation.issue3
dc.citation.spage484
dc.contributor.affiliationUniversidad Nacional de La Plata
dc.contributor.affiliationConsejo Nacional de Investigaciones Cientificas y Técnicas
dc.contributor.authorCaputo, Maricel
dc.contributor.authorAparicio, Francisca
dc.contributor.authorLaurella, Sergio
dc.contributor.authorMaría de las Mercedes Schiavoni
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2024-01-22T12:00:10Z
dc.date.available2024-01-22T12:00:10Z
dc.date.created2022-03-16
dc.date.issued2022-03-16
dc.description.abstractВивчено хімічний склад барди цукрового очерету (Тукуман, Аргентина) та встановлено високу концентрацію органічних сполук. Серед фенольних сполук виявлено переважно флавоноїди, антоціани, похідні резорцину та ферулової кислоти. Описано ізотерми адсорбції фенольних сполук та загальних органічних сполук на чотирьох комерційних активованих вугіллях з різними фізико-хімічними властивостями за двох температур. Встановлено, що форма ізотерми залежить від типу вуглецю, а адсорбційна здатність посилюється із збільшенням температури. Визначені ентальпії процесу адсорбції, та доведено, що адсорбція органічних сполук є хемосорбційним процесом, тоді як адсорбція фенольних сполук є фізичною адсорбцією для трьох типів вуглецю та хемосорбцією для четвертого (CONCARBO).
dc.description.abstractChemical composition of sugar cane vinasse (Tucumán, Argentina) was studied finding high concentration of organic compounds. Phenolic compounds were partially characterized, finding mostly flavonoids, anthocyanins, as well as resorcinol and ferulic acid derivatives. Adsorption isotherms of phenolic compounds and total organic compounds were measured on four commercial activated carbons with different physical and chemical properties at two temperatures. The isotherm shape depends on the type of carbon and the adsorption capacity is enhanced as temperature increases. Enthalpies of the adsorption process were estimated, revealing that the adsorption of organic compounds is a chemisorption process, while the adsorption of phenolic compounds is a physisorption process on three of the tested carbons and a chemisorption process on the other one (CONCARBO).
dc.format.extent484-491
dc.format.pages8
dc.identifier.citationArgentinian Sugar Cane Vinasse: Characterization of Phenolic Compounds and Evaluation of Adsorption as a Possible Remediation Technique / Maricel Caputo, Francisca Aparicio, Sergio Laurella, María de las Mercedes Schiavoni // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2022. — Vol 16. — No 3. — P. 484–491.
dc.identifier.citationenArgentinian Sugar Cane Vinasse: Characterization of Phenolic Compounds and Evaluation of Adsorption as a Possible Remediation Technique / Maricel Caputo, Francisca Aparicio, Sergio Laurella, María de las Mercedes Schiavoni // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2022. — Vol 16. — No 3. — P. 484–491.
dc.identifier.doidoi.org/10.23939/chcht16.03.484
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/60996
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 3 (16), 2022
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dc.relation.references[5] Robertiello, A. Upgrading of Agricultural and Agroindustrial Waste: The Treatment of Distillery Effluents (Vinasse) in Italy. Agric. Wastes 1981, 4, 387-395.
dc.relation.references[6] Coca, M.; Garcı́a, M.T.; Gonzalez, G.; Peña, M.; García, J.A. Study of Coloured Components Formed in Sugar Beet Processing. Food Chem. 2004, 86, 421-433. https://doi.org/10.1016/j.foodchem.2003.09.017
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dc.relation.references[23] Barrett, E.P.; Joyner, L.G.; Halenda, P.P.J. The Determination of Pore Volume and Area Distributions in Porous Substances. I. Computations from Nitrogen Isotherms. Am. Ceram. Soc. 1951, 73, 373-380. http://dx.doi.org/10.1021/ja01145a126
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dc.relation.references[29] Garcıa-Araya, J.F.; Beltran, F.J.; Alvarez, P.; Masa, F.J. Activated Carbon Adsorption of Some Phenolic Compounds Present in Agroindustrial Wastewater. Adsorption 2003, 9, 107-115. https://doi.org/10.1023/A:1024228708675
dc.relation.references[30] Garg, D.; Kumar, S.; Sharma, K.; Majumder, C.B. Application of Waste Peanut Shells to Form Activated Carbon and its Utilization for the Removal of Acid Yellow 36 from Wastewater. Groundw. Sustain. Dev. 2019, 8, 512-519. https://doi.org/10.1016/j.gsd.2019.01.010
dc.relation.references[31] Aljeboree, A.M.; Alshirifi, A.N.; Alkaim, A.F. Kinetics and Equilibrium Study for the Adsorption of Textile Dyes on Coconut Shell Activated Carbon. Arab. J. Chem. 2017, 10, S3381-S3393. https://doi.org/10.1016/j.arabjc.2014.01.020
dc.relation.references[32] Namasivayam, C.; Kavitha, D. Adsorptive Removal of 2,4‐Dichlorophenol from Aqueous Solution by Low‐Cost Carbon from an Agricultural Solid Waste: Coconut Coir Pith. Sep. Sci. Technol. 2005, 39, 1407-1425. https://doi.org/10.1081/SS-120030490
dc.relation.references[33] Bansal, R.C.; Goyal, M. Activated Carbon Adsorption. CRC Press: Boca Raton, 2005. https://doi.org/10.1201/9781420028812
dc.relation.referencesen[1] García, A.; Rojas, C. Posibilidades de Uso de la Vinaza en la Agricultura de Acuerdo con su Modo de Acción en Los Suelos. Nota Técnica Tecnicaña 2006, 10, 3-13.
dc.relation.referencesen[2] https://inta.gob.ar/noticias/energia-limpia-para-un-ambiente-sano
dc.relation.referencesen[3] Alfaro Portuguez, R.; Ocampo Chinchilla, R. Cambios Físico-Químicosprovocados por la Vinaza en un Suelo Vertisol en Costa Rica. XIX Congreso de la asociación de Técnicos Azucareros de Centroamérica ATACA, 1-12 y 13 de Setiembre del 2013; Costa Rica, San José, 2013.
dc.relation.referencesen[4] Parnaudeau, V.; Condom, N.; Oliver, R.; Cazevieille, P.; Recous, P. Vinasse Organic Matter Quality and Mineralization Potential, as Influenced by Raw Material, Fermentation and Concentration Processes. Bioresour. Technol. 2008, 99, 1553-1562. https://doi.org/10.1016/j.biortech.2007.04.012
dc.relation.referencesen[5] Robertiello, A. Upgrading of Agricultural and Agroindustrial Waste: The Treatment of Distillery Effluents (Vinasse) in Italy. Agric. Wastes 1981, 4, 387-395.
dc.relation.referencesen[6] Coca, M.; Garcı́a, M.T.; Gonzalez, G.; Peña, M.; García, J.A. Study of Coloured Components Formed in Sugar Beet Processing. Food Chem. 2004, 86, 421-433. https://doi.org/10.1016/j.foodchem.2003.09.017
dc.relation.referencesen[7] España-Gamboa, E.; Mijangos-Cortes, J.; Barahona-Perez, L.; Dominques-Maldonado, G.; Hernández-Zarate, G.; Alzate-Gaviria, L. Vinasses: Characterization and Treatments. Waste Manag. Res. 2011, 29, 1235-1250. https://doi.org/10.1177/0734242X10387313
dc.relation.referencesen[8] Gutiérrez, C.; Grosso, J.; Bullón, L.; Rennola, L., Salazar, F., Cardenas, A. Ultrafiltration de Vinazas Provenientes de Destilerías de Etanol. Revista Ciencia y Tecnología 2009, 30, 121-126.
dc.relation.referencesen[9] Díaz Marrero, M.A.; Cabrera Díaz, A.; Regalon Ramos, C. Evaluación del Modelo de Rusten en un Filtro Empacado Aireado Tratando Vinaza Cruda Cubana. RIHA 2019, 40, 39-49. https://riha.cujae.edu.cu/index.php/riha/article/view/487
dc.relation.referencesen[10] Lorenzo-Acosta, Y.; Doménech-López, F.; Eng-Sánchez, F.; Almazán-del Olmo, O.; Chanfón-Curbelo, J. M. Tratamiento Industrial de Vinazas de Destilerías en Reactores UASB. Tecnología Química 2015, 35, 108-123.
dc.relation.referencesen[11] Cabrera, Díaz A.; Díaz Marrero, M.A. Tratamiento de Vinaza Cubana en un Reactor Anaerobio Empacado de Flujo Ascendente. RIHA 2013, 34, 41-49.
dc.relation.referencesen[12] Susial Badajoz, P.; Pérez Báez, S.; López-Pérez, L. Estudio y Análisis Económico en el Tratamiento de Vinazas. Tecnología Del Agua 2001, 21, 48-56.
dc.relation.referencesen[13] Chaile, A.; Viera, H.; Ferreyra de Ruiz Holgado, M. Oxidación y Recuperación de Sales Inorgánicas de un Efluente de la Industria Alcoholera, VIIIº Congreso Argentino de Ingeniería Industrial, 12 y 13 de Noviembre de 2015; Córdoba, Argentina, 2015.
dc.relation.referencesen[14] Caqueret, V.; Bostyn, S.; Cagnon, B.; Fauduet, H. Purification of Sugar Beet Vinasse – Adsorption of Polyphenolic and Dark Colored Compounds on Different Commercial Activated Carbons. Bioresour. Technol. 2008, 99, 5814-5821. https://doi.org/10.1016/j.biortech.2007.10.009
dc.relation.referencesen[15] Gaspard, S.; Altenor, S.; Passe-Coutrin, N.; Ouensanga, A.; Brouers, F. Parameters from a New Kinetic Equation to Evaluate Activated Carbons Efficiency for Water Treatment. Water Res. 2006, 40, 3467-3477. https://doi.org/10.1016/j.watres.2006.07.018
dc.relation.referencesen[16] Brouers, F.; Sotolongo-Costa, O. Generalized Fractal Kinetics in Complex Systems (Application to Biophysics and Biotechnology). Phys. A 2006, 368, 165-175. https://doi.org/10.1016/j.physa.2005.12.062
dc.relation.referencesen[17] Seixas, F.L.; Gimenes, M.L.; Fernandes-Machado, N.R.C. Treatment of Vinasse by Adsorption on Carbon from Sugar Cane Bagasse. Quím. Nova 2016, 39, 172-179. https://doi.org/10.5935/0100-4042.20160013
dc.relation.referencesen[18] Rothwell, J.A.; Urpi-Sarda, M.; Boto-Ordoñez, M.; Knox, C.; Llorach, R.; Eisner, R.; Cruz, J.; Neveu, V.; Wishart, D.; Manach, C. et al. Phenol-Explorer 2.0: A Major Update of the Phenol-Explorer Database Integrating Data on Polyphenol Metabolism and Pharmacokinetics in Humans and Experimental Animals. Database 2012, 2012, bas0341. https://doi.org/10.1093/database/bas031
dc.relation.referencesen[19] Rothwell, J.A.; Pérez-Jiménez, J.; Neveu, V.; Medina-Remón, A.; M'Hiri, N.; García-Lobato, P.; Manach, C.; Knox, C.; Eisner, R.; Wishart, D.S. et al. Phenol-Explorer 3.0: A Major Update of the Phenol-Explorer Database to Incorporate Data on the Effects of Food Processing on Polyphenol Content. Database 2013, 2013, bat070. https://doi.org/10.1093/database/bat070
dc.relation.referencesen[20] Rothwell, J.A.; Medina-Remon, A.; Perez-Jimenez, J.; Neveu, V.; Knaze, V.; Slimani, N.; Scalbert, A. Effects of Food Processing on Polyphenol Contents: A Systematic Analysis Using Phenol-Explorer Data. Mol. Nutr. Food Res. 2015, 59, 160-170. https://doi.org/10.1002/mnfr.201400494
dc.relation.referencesen[21] Brunauer, S.; Emmett, P.; Teller, E. In Introduction to Characterization and Testing of Catalysts; Anderson, J.R.; Pratt, K.C., Eds.; Academic Press: Sydney, 1985.
dc.relation.referencesen[22] Guillot, A.; Stoeckli, F. Reference Isotherm for High Pressure Adsorption of CO2 by Carbons at 273 K. Carbon 2001, 39, 2059-2064. https://doi.org/10.1016/S0008-6223(01)00022-7
dc.relation.referencesen[23] Barrett, E.P.; Joyner, L.G.; Halenda, P.P.J. The Determination of Pore Volume and Area Distributions in Porous Substances. I. Computations from Nitrogen Isotherms. Am. Ceram. Soc. 1951, 73, 373-380. http://dx.doi.org/10.1021/ja01145a126
dc.relation.referencesen[24] Newcombe, G.; Drikas, M. Adsorption of NOM onto Activated Carbon: Electrostatic and Non-Electrostatic Effects. Carbon 1997, 35, 1239-1250. https://doi.org/10.1016/S0008-6223(97)00078-X
dc.relation.referencesen[25] Boehm, H.P. Some Aspects of the Surface Chemistry of Carbon Blacks and Other Carbons. Carbon 1994, 32, 759-769. https://doi.org/10.1016/0008-6223(94)90031-0
dc.relation.referencesen[26] Faria, P.C.C.; Orfao, J.J.M.; Pereyra, M.F.R. Adsorption of Anionic and Cationic Dyes on Activated Carbons with Different Surface Chemistries. Water Res. 2004, 38, 2043-2052. https://doi.org/10.1016/j.watres.2004.01.034
dc.relation.referencesen[27] Thommes, M.; Kaneko, K.; Neimark, A.V.; Olivier, J.P.; Rodriguez-Reinoso, F.; Jean Rouquerol, J.; Sing, K.S.W. Physisorption of Gases, with Special Reference to the Evaluation of Surface Area and Pore Size Distribution (IUPAC Technical Report). Pure Appl. Chem. 2015, 87, 1051–1069. https://doi.org/10.1515/pac-2014-1117
dc.relation.referencesen[28] Giles, C.H.; MacEwan, T.H.; Nakhwa, S.N.; Smith, D.A System of Classification of Solution Adsorption Isotherms, and its Use in Diagnosis of Adsorption Mechanisms and in Measurement of Specific Surface Areas of Solids. J. Chem. Soc. 1960, 14, 3973-3993. https://doi.org/10.1039/jr9600003973
dc.relation.referencesen[29] Garcıa-Araya, J.F.; Beltran, F.J.; Alvarez, P.; Masa, F.J. Activated Carbon Adsorption of Some Phenolic Compounds Present in Agroindustrial Wastewater. Adsorption 2003, 9, 107-115. https://doi.org/10.1023/A:1024228708675
dc.relation.referencesen[30] Garg, D.; Kumar, S.; Sharma, K.; Majumder, C.B. Application of Waste Peanut Shells to Form Activated Carbon and its Utilization for the Removal of Acid Yellow 36 from Wastewater. Groundw. Sustain. Dev. 2019, 8, 512-519. https://doi.org/10.1016/j.gsd.2019.01.010
dc.relation.referencesen[31] Aljeboree, A.M.; Alshirifi, A.N.; Alkaim, A.F. Kinetics and Equilibrium Study for the Adsorption of Textile Dyes on Coconut Shell Activated Carbon. Arab. J. Chem. 2017, 10, S3381-S3393. https://doi.org/10.1016/j.arabjc.2014.01.020
dc.relation.referencesen[32] Namasivayam, C.; Kavitha, D. Adsorptive Removal of 2,4‐Dichlorophenol from Aqueous Solution by Low‐Cost Carbon from an Agricultural Solid Waste: Coconut Coir Pith. Sep. Sci. Technol. 2005, 39, 1407-1425. https://doi.org/10.1081/SS-120030490
dc.relation.referencesen[33] Bansal, R.C.; Goyal, M. Activated Carbon Adsorption. CRC Press: Boca Raton, 2005. https://doi.org/10.1201/9781420028812
dc.relation.urihttps://inta.gob.ar/noticias/energia-limpia-para-un-ambiente-sano
dc.relation.urihttps://doi.org/10.1016/j.biortech.2007.04.012
dc.relation.urihttps://doi.org/10.1016/j.foodchem.2003.09.017
dc.relation.urihttps://doi.org/10.1177/0734242X10387313
dc.relation.urihttps://riha.cujae.edu.cu/index.php/riha/article/view/487
dc.relation.urihttps://doi.org/10.1016/j.biortech.2007.10.009
dc.relation.urihttps://doi.org/10.1016/j.watres.2006.07.018
dc.relation.urihttps://doi.org/10.1016/j.physa.2005.12.062
dc.relation.urihttps://doi.org/10.5935/0100-4042.20160013
dc.relation.urihttps://doi.org/10.1093/database/bas031
dc.relation.urihttps://doi.org/10.1093/database/bat070
dc.relation.urihttps://doi.org/10.1002/mnfr.201400494
dc.relation.urihttps://doi.org/10.1016/S0008-6223(01)00022-7
dc.relation.urihttp://dx.doi.org/10.1021/ja01145a126
dc.relation.urihttps://doi.org/10.1016/S0008-6223(97)00078-X
dc.relation.urihttps://doi.org/10.1016/0008-6223(94)90031-0
dc.relation.urihttps://doi.org/10.1016/j.watres.2004.01.034
dc.relation.urihttps://doi.org/10.1515/pac-2014-1117
dc.relation.urihttps://doi.org/10.1039/jr9600003973
dc.relation.urihttps://doi.org/10.1023/A:1024228708675
dc.relation.urihttps://doi.org/10.1016/j.gsd.2019.01.010
dc.relation.urihttps://doi.org/10.1016/j.arabjc.2014.01.020
dc.relation.urihttps://doi.org/10.1081/SS-120030490
dc.relation.urihttps://doi.org/10.1201/9781420028812
dc.rights.holder© Національний університет “Львівська політехніка”, 2022
dc.rights.holder© Caputo M., Aparicio F., Laurella S., Schiavoni M., 2022
dc.subjectбарда
dc.subjectадсорбція
dc.subjectфенольні сполуки
dc.subjectвідновлення
dc.subjectvinasse
dc.subjectadsorption
dc.subjectphenolic compounds
dc.subjectremediation
dc.titleArgentinian Sugar Cane Vinasse: Characterization of Phenolic Compounds and Evaluation of Adsorption as a Possible Remediation Technique
dc.title.alternativeАргентинська цукрова барда: характеристика фенольних сполук та оцінка адсорбції як можливого методу відновлення
dc.typeArticle

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