Friedel-Crafts Reaction of Vinyltrimethoxysilane with Styrene and Composite Materials on Their Base

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dc.citation.epage338
dc.citation.issue2
dc.citation.spage325
dc.contributor.affiliationIvane Javakhishvili Tbilisi State University
dc.contributor.affiliationGeorgian Technical University
dc.contributor.affiliationSokhumi State University
dc.contributor.authorMukbaniani, Omar
dc.contributor.authorTatrishvili, Tamara
dc.contributor.authorKvinikadze, Nikoloz
dc.contributor.authorBukia, Tinatin
dc.contributor.authorPachulia, Zurab
dc.contributor.authorPirtskheliani, Nana
dc.contributor.authorPetriashvili, Gia
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2024-02-12T08:30:30Z
dc.date.available2024-02-12T08:30:30Z
dc.date.created2023-03-16
dc.date.issued2023-03-16
dc.description.abstractЗдійснено алкілування стирену вінілтриметоксисиланом за реакцію Фріделя–Крафтса в присутності безводного AlCl3. Отримано алкокси(4-вінілфенетил)силан. Синтезовані продукти ідентифікували за допомогою 1H, 13C, COSY ЯМР та FTIR спектроскопії. Обговорено розрахунки з використанням методу квантово-хімічної неемпіричної теорії функціоналу густини (DFT) для реакції між вінілтриметоксисиланом і стиреном, здійсненої за орто-, мета- і пара-положеннями. Для теоретичного моделювання використовували програму онлайн-прогнозування “Priroda-04: A quantum-chemical program suite”. За різних температур і тисків методом гарячого пресування або екструзії були одержані композиційні матеріали на основі деревної тирси різної дисперсності та синтезованого триметоксисилілованого стирену як в'яжучого й армувального агента зі ступенями силілування (5 %) у присутності різноманітних органічних/неорганічних добавок, антипіренів та антиоксидантів. Досліджено фізико-механічні властивості композитів.
dc.description.abstractFriedel-Crafts alkylation reaction of vinyltrimethoxysilane with styrene was performed in the presence of anhydrous AlCl3. Alkoxy(4-vinylphenethyl)silane has been obtained. The synthesized products were identified by 1H, 13C, COSY NMR, and FTIR spectroscopy. Calculations using the quantum-chemical non-empirical density functional theory (DFT) method for the reaction between vinyltrimethoxysilane and styrene performed for ortho-, meta- and para-positions were discussed. For the theoretical modeling an online prediction program “Priroda-04: A quantum-chemical program suite” was used. Composite materials based on wood sawdust with various dispersion qualities and synthesized trimethoxysilylated styrene as a binding and reinforcing agent with degrees of silylation (5 %), in the presence of various organic/inorganic additives, fire retardants, and antioxidants, have been developed at different temperatures and pressures via hot press method or extrusion. The physico-mechanical properties of composites have been investigated.
dc.format.extent325-338
dc.format.pages14
dc.identifier.citationFriedel-Crafts Reaction of Vinyltrimethoxysilane with Styrene and Composite Materials on Their Base / Omar Mukbaniani, Tamara Tatrishvili, Nikoloz Kvinikadze, Tinatin Bukia, Zurab Pachulia, Nana Pirtskheliani, Gia Petriashvili // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2023. — Vol 17. — No 2. — P. 325–338.
dc.identifier.citationenFriedel-Crafts Reaction of Vinyltrimethoxysilane with Styrene and Composite Materials on Their Base / Omar Mukbaniani, Tamara Tatrishvili, Nikoloz Kvinikadze, Tinatin Bukia, Zurab Pachulia, Nana Pirtskheliani, Gia Petriashvili // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2023. — Vol 17. — No 2. — P. 325–338.
dc.identifier.doidoi.org/10.23939/chcht17.02.325
dc.identifier.issn1996-4196
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/61236
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 2 (17), 2023
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dc.rights.holder© Національний університет “Львівська політехніка”, 2023
dc.rights.holder© Mukbaniani O., Tatrishvili T., Kvinikadze N., Bukia T., Pachulia Z., Pirtskheliani N., Petriashvili G., 2023
dc.subjectтриметокси(4-вінілфенетил)силан
dc.subjectреакція алкілування
dc.subjectFTIR і ЯМР спектроскопія
dc.subjectDFT
dc.subjecttrimethoxy(4-vinylphenethyl)silane
dc.subjectalkylation reaction
dc.subjectFTIR and NMR spectroscopy
dc.subjectDFT
dc.titleFriedel-Crafts Reaction of Vinyltrimethoxysilane with Styrene and Composite Materials on Their Base
dc.title.alternativeРеакція Фріделя-Крафтса вінілтриметоксисилану зі стиреном та композитні матеріали на їхній основі
dc.typeArticle

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Chemistry & Chemical Technology. – 2023. – Vol. 17, No. 2