Improvement of homogeneous catalytic process of oxidation of alkylaromatic compounds by combination of binary catalytic systems and ultrasound treatment

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dc.citation.epage58
dc.citation.issue1
dc.citation.journalTitleChemistry, Technology and Application of Substance
dc.citation.spage54
dc.citation.volume1
dc.contributor.affiliationНаціональний університет ”Львівська політехніка”
dc.contributor.authorРеутський, В. В.
dc.contributor.authorГринчук, Ю. М.
dc.contributor.authorОлійник, Л. Р.
dc.contributor.authorReutskyy, V. V.
dc.contributor.authorHrynchuk, Y. M.
dc.contributor.authorOlijnyk, L. P.
dc.coverage.placenameLviv
dc.date.accessioned2019-05-21T12:54:25Z
dc.date.available2019-05-21T12:54:25Z
dc.date.created2018-02-26
dc.date.issued2018-02-26
dc.description.abstractДосліджено вплив сумісного застосування каталітичних систем на основі промислових каталізаторів окиснення та поверхнево-активних речовин різної природи (йонно- та нейонногенних) і ультразвукового оброблення реакційної суміші на процес рідиннофазного окиснення алкілароматичних сполук. Одержані результати дають змогу стверджувати, що сумісне застосування каталітичних систем та ультразвукового оброблення впливає на окиснення етилбензолу. Створені каталітичні системи не лише збільшують продуктивність реакційного обладнання за цільовими продуктами, але й здатні змінювати селективність процесу в бік утворення необхідного продукту.
dc.description.abstractArticle is devoted to research of impact of combined use of catalytic systems based on industrial oxidation catalysts and surface-active compounds of different nature (ion- and noniongenic) with ultrasonic treat ment of reaction mixture at alkylaromatic compounds liquidphase oxidation process. Obtained results showed that combined use of catalytic system and ultrasound has impact on ethylbenzene oxidation. Created catalytic systems not only increase productivity of reaction volume (for aim products), but also allow to shift process selectivity towards creation of desired product.
dc.format.extent54-58
dc.format.pages5
dc.identifier.citationReutskyy V. V. Improvement of homogeneous catalytic process of oxidation of alkylaromatic compounds by combination of binary catalytic systems and ultrasound treatment / V. V. Reutskyy, Y. M. Hrynchuk, L. P. Olijnyk // Chemistry, Technology and Application of Substance. — Lviv : Lviv Politechnic Publishing House, 2018. — Vol 1. — No 1. — P. 54–58.
dc.identifier.citationenReutskyy V. V. Improvement of homogeneous catalytic process of oxidation of alkylaromatic compounds by combination of binary catalytic systems and ultrasound treatment / V. V. Reutskyy, Y. M. Hrynchuk, L. P. Olijnyk // Chemistry, Technology and Application of Substance. — Lviv : Lviv Politechnic Publishing House, 2018. — Vol 1. — No 1. — P. 54–58.
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/45034
dc.language.isoen
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry, Technology and Application of Substance, 1 (1), 2018
dc.relation.references1. Melnyk Y. R., Reutskyy V. V., Mokryj E. M. The influence of crownethers by catalytic oxidation of cyclohexane // Reports of NAS of Ukraine, 1 (2001), 154–157.
dc.relation.references2. Melnyk Y. R., Reutskyy V. V., Mokryj E. M. Influence of polyglicols on catalytic oxidation of cyclohexane // Bulletin of NU“Lvivska politechnika”. Chemistry, technology of materials and their applications. 2001 426, 91–94.
dc.relation.references3. Emanuel N. M., GalD. Oxidation of ethylbenzene. (Model Rection). Moscow: Nauka, 1984. – 376 p.
dc.relation.references4. Reutskyy V. V., Melnyk Yu. R., Starchevskyy V. L. Influence of surface-active matters on ethylbenzene oxidation // Book of abstracts of 17 th International Symposium on Homogeneous Catalysis. Poznan, Poland, 2010, p. 201.
dc.relation.references5. Haifeng Xiong, Yuhua Zhang, Kongyong Liew, Jinlin Li Ruthenium promotion of Co/SBA catalysts with high cobalt loading for Fisher-Tropsh synthesis // Fuel Processing Technology, 90, Issue 2(2009), 237–246.
dc.relation.references6. Shanghong Zeng, Dongping Du, Fenghua Bai, Haiquan Su Bridging complexes of rare earth and cobalt cluster as catalyst precursor for Fisher-Tropsh synthesis // Journal of Rare Earths, 29, Issue 4(2011),349–353.
dc.relation.references7. Cancheng Guo, Quingjing Peng, Qiang Liu Selective oxidation of ethylbenzene with air catalyzed by simple μ-oxo dimeric metalloporphyrins under mild conditions in the absence of additives. // Journal of Molecular Catalysis A: Chemical, 192, Issues 1-2(2003), 295–302.
dc.relation.references8. Arshadi M., Ghiaci M., Rahmanian A., Ghaziaskar H., Gil A. Oxidation of ethylbenzene to acetophenone by a Mn catalyst supported on a modified nanosized SiO2/Al2O3 mixed-oxide in supercritical carbon dioxide // Applied Catalysis B: Environmental, 119–120(2012), 81–90.
dc.relation.references9. Xiao Gang Li, Jing Wang, Ren HeSelective oxidation of ethylbenzene catalyzed by fluorinated metalloporphyrins with molecular oxygen // Chinese Chemical Letters, 18, Issue 9 (2007), 1053–1056.
dc.relation.references10. Ahmadrez aEsmaeilbeig, Hamidreza Samouei, Sedigheh Abedanzadeh, Zahra Amirghofran Synthesis, characterization and antitumor activity study of some cyclometalatedorganoplatinum (II) complexes containing aromatic N-donor ligands. // Journal of Organometallic Chemistry, 696, Issue 20(2011), 3135–3142.
dc.relation.references11. Реутский В. В. Каталитическое окисление циклогексана в акустическом поле: дисс. ... канд. хим. наук. – Львов, 1988. – 119 с.
dc.relation.referencesen1. Melnyk Y. R., Reutskyy V. V., Mokryj E. M. The influence of crownethers by catalytic oxidation of cyclohexane, Reports of NAS of Ukraine, 1 (2001), 154–157.
dc.relation.referencesen2. Melnyk Y. R., Reutskyy V. V., Mokryj E. M. Influence of polyglicols on catalytic oxidation of cyclohexane, Bulletin of NU"Lvivska politechnika". Chemistry, technology of materials and their applications. 2001 426, 91–94.
dc.relation.referencesen3. Emanuel N. M., GalD. Oxidation of ethylbenzene. (Model Rection). Moscow: Nauka, 1984, 376 p.
dc.relation.referencesen4. Reutskyy V. V., Melnyk Yu. R., Starchevskyy V. L. Influence of surface-active matters on ethylbenzene oxidation, Book of abstracts of 17 th International Symposium on Homogeneous Catalysis. Poznan, Poland, 2010, p. 201.
dc.relation.referencesen5. Haifeng Xiong, Yuhua Zhang, Kongyong Liew, Jinlin Li Ruthenium promotion of Co/SBA catalysts with high cobalt loading for Fisher-Tropsh synthesis, Fuel Processing Technology, 90, Issue 2(2009), 237–246.
dc.relation.referencesen6. Shanghong Zeng, Dongping Du, Fenghua Bai, Haiquan Su Bridging complexes of rare earth and cobalt cluster as catalyst precursor for Fisher-Tropsh synthesis, Journal of Rare Earths, 29, Issue 4(2011),349–353.
dc.relation.referencesen7. Cancheng Guo, Quingjing Peng, Qiang Liu Selective oxidation of ethylbenzene with air catalyzed by simple m-oxo dimeric metalloporphyrins under mild conditions in the absence of additives., Journal of Molecular Catalysis A: Chemical, 192, Issues 1-2(2003), 295–302.
dc.relation.referencesen8. Arshadi M., Ghiaci M., Rahmanian A., Ghaziaskar H., Gil A. Oxidation of ethylbenzene to acetophenone by a Mn catalyst supported on a modified nanosized SiO2/Al2O3 mixed-oxide in supercritical carbon dioxide, Applied Catalysis B: Environmental, 119–120(2012), 81–90.
dc.relation.referencesen9. Xiao Gang Li, Jing Wang, Ren HeSelective oxidation of ethylbenzene catalyzed by fluorinated metalloporphyrins with molecular oxygen, Chinese Chemical Letters, 18, Issue 9 (2007), 1053–1056.
dc.relation.referencesen10. Ahmadrez aEsmaeilbeig, Hamidreza Samouei, Sedigheh Abedanzadeh, Zahra Amirghofran Synthesis, characterization and antitumor activity study of some cyclometalatedorganoplatinum (II) complexes containing aromatic N-donor ligands., Journal of Organometallic Chemistry, 696, Issue 20(2011), 3135–3142.
dc.relation.referencesen11. Reutskii V. V. Kataliticheskoe okislenie tsikloheksana v akusticheskom pole: diss. ... kand. khim. nauk, Lvov, 1988, 119 p.
dc.rights.holder© Національний університет „Львівська політехніка“, 2018
dc.rights.holder© Реутський В. В., Гринчук Ю. М., Олійник Л. П., 2018
dc.subjectокиснення
dc.subjectетилбензол
dc.subjectповерхнево-активні сполуки
dc.subjectкаталітичні системи
dc.subjectгідропероксид етилбензолу
dc.subjectацетофенон
dc.subjectультразвук
dc.subjectoxidation
dc.subjectethylbenzene
dc.subjectsurface active compounds
dc.subjectcatalytic systems
dc.subjecthydroperoxide of ethylbenzene
dc.subjectacetophenone
dc.subjectultrasound
dc.titleImprovement of homogeneous catalytic process of oxidation of alkylaromatic compounds by combination of binary catalytic systems and ultrasound treatment
dc.title.alternativeВдосконалення гомогенно-каталітичного процесу окиснення алкілароматичних сполук за допомогою поєднання бінарних каталітичних систем і ультразвукового оброблення
dc.typeArticle

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Chemistry, Technology and Application of Substances. – 2018. – Vol. 1, No. 1