Direct Synthesis and Characterization of Photo-Crosslinkable Biodegradable PLA-PEG-PLA Ttiblock Copolymer with Methacrylates Functions by Green Montmorillonite Clay Catalyst

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dc.citation.epage480
dc.citation.issue4
dc.citation.spage474
dc.contributor.affiliationUniversity of Oran 1 Ahmed Benbella
dc.contributor.affiliationUniversity of Abdelhamid Ibn Badis – Mostaganem
dc.contributor.authorBenachour, Mohamed
dc.contributor.authorEl-Kebir, Aslya
dc.contributor.authorHarrane, Amine
dc.contributor.authorMeghabar, Rachid
dc.contributor.authorBelbachir, Mohammed
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2023-12-13T10:03:00Z
dc.date.available2023-12-13T10:03:00Z
dc.date.created2010-03-16
dc.date.issued2010-03-16
dc.description.abstractДиметакриловані триблок-кополімери PLAPEG-PLA полілактиду (PLA) і поліетиленгліколю (PEG) синтезовані внаслідок одностадійної катіонної полімеризації в масі лактиду в присутності PEG з різними молекулярними масами. Мaghnite-H+, кислотна монтмориллонитова глина, використана як твердий нетоксичний каталізатор. За допомогою 1Н ЯМР і ДСК проведено аналіз одержаного диметакрилатного кополімеру. Досліджено вплив кількості Maghnite-H+ та середньої молекулярної маси PEG на виходи кополімеризації та метакрилування, а також на середню молекулярну масу отриманих кополімерів.
dc.description.abstractDi-methacrylated PLA-PEG-PLA triblock copolymers of polylactide and polyethylene glycol were synthesized in one-step process by bulk cationic polymerization of lactide in the presence of PEG with different average molecular weights, using Maghnite-H+, an acidic montmorillonite clay, as a solid non-toxic catalyst. The obtained di-methacrylated copolymer was analyzed by 1H NMR and DSC. The effect of MaghniteH+ proportions and PEG average molecular weight on the copolymerization and methacrylation yields and on average molecular weight of the resulting copolymers was studied.
dc.format.extent474-480
dc.format.pages7
dc.identifier.citationDirect Synthesis and Characterization of Photo-Crosslinkable Biodegradable PLA-PEG-PLA Ttiblock Copolymer with Methacrylates Functions by Green Montmorillonite Clay Catalyst / Mohamed Benachour, Aslya El-Kebir, Amine Harrane, Rachid Meghabar, Mohammed Belbachir // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2020. — Vol 14. — No 4. — P. 474–480.
dc.identifier.citationenDirect Synthesis and Characterization of Photo-Crosslinkable Biodegradable PLA-PEG-PLA Ttiblock Copolymer with Methacrylates Functions by Green Montmorillonite Clay Catalyst / Mohamed Benachour, Aslya El-Kebir, Amine Harrane, Rachid Meghabar, Mohammed Belbachir // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2020. — Vol 14. — No 4. — P. 474–480.
dc.identifier.doidoi.org/10.23939/chcht14.04.474
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/60576
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 4 (14), 2020
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dc.relation.urihttps://doi.org/10.1007/s11706-009-0017-0
dc.relation.urihttps://doi.org/10.1016/j.ejpb.2014.11.012
dc.relation.urihttps://doi.org/10.1016/j.colsurfb.2015.02.048
dc.relation.urihttps://doi.org/10.1016/j.colsurfb.2015.01.039
dc.relation.urihttps://doi.org/10.1016/j.ydbio.2015.08.020
dc.relation.urihttps://doi.org/10.1016/j.ijpharm.2009.12.013
dc.relation.urihttps://doi.org/10.1016/j.jconrel.2009.02.010
dc.relation.urihttps://doi.org/10.1016/j.reactfunctpolym.2012.11.003
dc.relation.urihttps://doi.org/10.1002/(SICI)1097-4628(20000328)75:13<1615::AID-APP7>3.0.CO;2-L
dc.relation.urihttps://doi.org/10.1016/S0378-5173(99)00153-2
dc.relation.urihttps://doi.org/10.1088/1748-6041/6/6/065006
dc.relation.urihttps://doi.org/10.1021/ma991181w
dc.relation.urihttps://doi.org/10.1016/j.clay.2014.02.001
dc.relation.urihttps://doi.org/10.5185/amlett.2015.5660
dc.relation.urihttps://doi.org/10.1680/jgrma.17.00040
dc.relation.urihttps://doi.org/10.1080/10601325.2015.980763
dc.relation.urihttps://doi.org/10.1007/s13369-015-1862-z
dc.relation.urihttps://doi.org/10.1016/j.ejpb.2015.02.011
dc.relation.urihttps://doi.org/10.1016/j.polymer.2015.09.067
dc.relation.urihttps://doi.org/10.1016/j.ijpharm.2010.08.037
dc.relation.urihttps://doi.org/10.1016/j.ijbiomac.2015.08.036
dc.relation.urihttps://doi.org/10.1590/1980-5373-MR-2015-0322
dc.rights.holder© Національний університет “Львівська політехніка”, 2020
dc.rights.holder© Benachour M., El-Kebir A., Harrane A., Meghabar R., Belbachir M., 2020
dc.subjectрозкриття кільця
dc.subjectполімеризація
dc.subjectблоккополімери
dc.subjectкатіонна полімеризація
dc.subjectметакрилатні кополімери
dc.subjectмонтморилоніт
dc.subjectringopening
dc.subjectpolymerization
dc.subjectblock copolymers
dc.subjectcationic polymerization
dc.subjectmethacrylate copolymers
dc.subjectmontmorillonite
dc.titleDirect Synthesis and Characterization of Photo-Crosslinkable Biodegradable PLA-PEG-PLA Ttiblock Copolymer with Methacrylates Functions by Green Montmorillonite Clay Catalyst
dc.title.alternativeПрямий синтез і характеристика фотозшитого біодеградабельного триблок-кополімера PLA-PEG-PLA з метакрилатними функційними групами в присутності каталізатора на основі зеленої монтморилонітової глини
dc.typeArticle

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Chemistry & Chemical Technology. – 2020. – Vol. 14, No. 4