A Modeling Study of Operating Conditions and Different Supports on Fe-Co-Ce Nanocatalyst and Optimizing of Light Olefins Selectivity in the Fischer-Tropsch Synthesis

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dc.citation.epage182
dc.citation.issue2
dc.citation.spage170
dc.contributor.affiliationUniversity of Sistan and Baluchestan
dc.contributor.affiliationResearch Institute of Petroleum Industry (RIPI)
dc.contributor.authorLari, Tahereh Taherzadeh
dc.contributor.authorMirzae, Ali Akbar
dc.contributor.authorAtashi, Hossein
dc.contributor.authorBozorgzadeh, Hamid Reza
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2024-01-09T10:19:09Z
dc.date.available2024-01-09T10:19:09Z
dc.date.created2021-03-16
dc.date.issued2021-03-16
dc.description.abstractДосліджено вплив чинників (Red-GHSV, H2/CO, Oprat-GHSV) та різних носіїв нанокаталізатора Fe-Co-Ce на перебіг синтезу Фішера-Тропша. З метою одержання вищої селективності за олефінами при синтезі застосована статистична модель з методологією поверхневої реакції, яка вказує на взаєммний вплив чинників один на одного. Визначено умови, за яких оптимізуються три чинники з метою максимізації олефінів та мінімізації парафінів і метану. Синтезовані нанокаталізатори з різними носіями досліджено методами дифракційного рентгенівського аналізу, скануючої мікроскопії та термопрограмованого відновлення.
dc.description.abstractThis study demonstrates the effect of operating conditions (Red-GHSV, inlet H2/CO, Oprat-GHSV) and the effect of Fe-Co-Ce nanocatalyst support. A statistical model using the response surface methodology (RSM) was applied with the target of achieving higher olefins selectivity in Fischer-Tropsch synthesis, which indicates the interaction effects of factors. The conditions under which three objectives optimization for maximizing olefins and minimizing paraffins and methane were determined. Synthesized nanocatalysts with various supports were characterized by XRD, SEM and TPR techniques.
dc.format.extent170-182
dc.format.pages13
dc.identifier.citationA Modeling Study of Operating Conditions and Different Supports on Fe-Co-Ce Nanocatalyst and Optimizing of Light Olefins Selectivity in the Fischer-Tropsch Synthesis / Tahereh Taherzadeh Lari, Ali Akbar Mirzae, Hossein Atashi, Hamid Reza Bozorgzadeh // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2021. — Vol 15. — No 2. — P. 170–182.
dc.identifier.citationenA Modeling Study of Operating Conditions and Different Supports on Fe-Co-Ce Nanocatalyst and Optimizing of Light Olefins Selectivity in the Fischer-Tropsch Synthesis / Tahereh Taherzadeh Lari, Ali Akbar Mirzae, Hossein Atashi, Hamid Reza Bozorgzadeh // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2021. — Vol 15. — No 2. — P. 170–182.
dc.identifier.doidoi.org/10.23939/chcht15.02.170
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/60724
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 2 (15), 2021
dc.relation.references[1] Zhyznevskiy V., Gumenetskiy V., Matskiv O., Shyshchak O.: Chem. Chem. Technol., 2013, 7, 15. https://doi.org/10.23939/chcht07.01.015
dc.relation.references[2] Babyak L., Matsyak O., Shevchuk V.: Chem. Chem. Technol., 2011, 5, 95. https://doi.org/10.23939/chcht05.01.095
dc.relation.references[3] Babyak L., Matsyak O., Shevchuk V. et al.: Chem. Chem. Technol., 2009, 3, 305.
dc.relation.references[4] Pielichowski J., Kowalski G., Zaikov G.: Chem. Chem. Technol., 2011, 5, 303. https://doi.org/10.23939/chcht05.03.303
dc.relation.references[5] Feyzi M., Yaghobi N., Eslamimanesh V.: Mater. Res. Bull., 2015, 72, 143. https://doi.org/doi:10.1016/j.materresbull.2015.07.039
dc.relation.references[6] Arsalanfar M., Mirzaei A., Bozorgzadeh H., Atashi H.: J. Ind. Eng. Chem, 2012, 18, 2092. https://doi.org/10.1016/j.jiec.2012.06.003
dc.relation.references[7] Jacobs G., Das T., Zhang Y. et al.: Appl. Catal. A, 2002, 233, 263. https://doi.org/10.1016/S0926-860X(02)00195-3
dc.relation.references[8] Atashi H., Rezaeian F.: Int. J. Hydrogen. Energ., 2017, 42, 15497. https://doi.org/10.1016/j.ijhydene.2017.04.224
dc.relation.references[9] Sun Y., Wei J., Ping Zhang J., G. Yang: J. Nat. Gas. Sci. Eng., 2016, 28, 173. https://doi.org/10.1016/j.jngse.2015.11.008
dc.relation.references[10] Gunaraj V., Murugan N.: J. Mater. Process. Technol., 1999, 88, 266. https://doi.org/10.1016/S0924-0136(98)00405-1
dc.relation.references[11] Tauster S., Fung S., Baker R., Horsley J.: Science, 1981, 211, 1121. https://doi.org/10.1126/science.211.4487.1121
dc.relation.references[12] Peddis D., Jonsson P., Laureti S., Varvaro G.: Front. Nanosci., 2014, 6, 129. https://doi.org/10.1016/B978-0-08-098353-0.00004-X
dc.relation.references[13] Khan A., Smimiotis P.: J. Mol. Catal. A, 2008, 280, 43. https://doi.org/10.1016/j.molcata.2007.10.022
dc.relation.references[14] Davies K., Wells S., Charles S.: J. Magn. Magn. Mater., 1993, 122, 24. https://doi.org/10.1016/0304-8853(93)91031-2
dc.relation.references[15] De Rivas B., Gutierrez-Ortiz J., Lopez-Fonseca R., Gonzalez Velasco J.: Appl. Catal. A, 2006, 314, 54. https://doi.org/10.1016/j.apcata.2006.08.005
dc.relation.references[16] Madon R., Iglesia E.: J. Catal., 1993, 139, 576. https://doi.org/10.1006/jcat.1993.1051
dc.relation.references[17] Atashi H., Razmjooei S., Khorashadizadeh M. et al.: J. Taiwan Inst. Chem. Eng., 2015, 54, 83. https://doi.org/10.1016/j.jtice.2015.03.017
dc.relation.referencesen[1] Zhyznevskiy V., Gumenetskiy V., Matskiv O., Shyshchak O., Chem. Chem. Technol., 2013, 7, 15. https://doi.org/10.23939/chcht07.01.015
dc.relation.referencesen[2] Babyak L., Matsyak O., Shevchuk V., Chem. Chem. Technol., 2011, 5, 95. https://doi.org/10.23939/chcht05.01.095
dc.relation.referencesen[3] Babyak L., Matsyak O., Shevchuk V. et al., Chem. Chem. Technol., 2009, 3, 305.
dc.relation.referencesen[4] Pielichowski J., Kowalski G., Zaikov G., Chem. Chem. Technol., 2011, 5, 303. https://doi.org/10.23939/chcht05.03.303
dc.relation.referencesen[5] Feyzi M., Yaghobi N., Eslamimanesh V., Mater. Res. Bull., 2015, 72, 143. https://doi.org/doi:10.1016/j.materresbull.2015.07.039
dc.relation.referencesen[6] Arsalanfar M., Mirzaei A., Bozorgzadeh H., Atashi H., J. Ind. Eng. Chem, 2012, 18, 2092. https://doi.org/10.1016/j.jiec.2012.06.003
dc.relation.referencesen[7] Jacobs G., Das T., Zhang Y. et al., Appl. Catal. A, 2002, 233, 263. https://doi.org/10.1016/S0926-860X(02)00195-3
dc.relation.referencesen[8] Atashi H., Rezaeian F., Int. J. Hydrogen. Energ., 2017, 42, 15497. https://doi.org/10.1016/j.ijhydene.2017.04.224
dc.relation.referencesen[9] Sun Y., Wei J., Ping Zhang J., G. Yang: J. Nat. Gas. Sci. Eng., 2016, 28, 173. https://doi.org/10.1016/j.jngse.2015.11.008
dc.relation.referencesen[10] Gunaraj V., Murugan N., J. Mater. Process. Technol., 1999, 88, 266. https://doi.org/10.1016/S0924-0136(98)00405-1
dc.relation.referencesen[11] Tauster S., Fung S., Baker R., Horsley J., Science, 1981, 211, 1121. https://doi.org/10.1126/science.211.4487.1121
dc.relation.referencesen[12] Peddis D., Jonsson P., Laureti S., Varvaro G., Front. Nanosci., 2014, 6, 129. https://doi.org/10.1016/B978-0-08-098353-0.00004-X
dc.relation.referencesen[13] Khan A., Smimiotis P., J. Mol. Catal. A, 2008, 280, 43. https://doi.org/10.1016/j.molcata.2007.10.022
dc.relation.referencesen[14] Davies K., Wells S., Charles S., J. Magn. Magn. Mater., 1993, 122, 24. https://doi.org/10.1016/0304-8853(93)91031-2
dc.relation.referencesen[15] De Rivas B., Gutierrez-Ortiz J., Lopez-Fonseca R., Gonzalez Velasco J., Appl. Catal. A, 2006, 314, 54. https://doi.org/10.1016/j.apcata.2006.08.005
dc.relation.referencesen[16] Madon R., Iglesia E., J. Catal., 1993, 139, 576. https://doi.org/10.1006/jcat.1993.1051
dc.relation.referencesen[17] Atashi H., Razmjooei S., Khorashadizadeh M. et al., J. Taiwan Inst. Chem. Eng., 2015, 54, 83. https://doi.org/10.1016/j.jtice.2015.03.017
dc.relation.urihttps://doi.org/10.23939/chcht07.01.015
dc.relation.urihttps://doi.org/10.23939/chcht05.01.095
dc.relation.urihttps://doi.org/10.23939/chcht05.03.303
dc.relation.urihttps://doi.org/doi:10.1016/j.materresbull.2015.07.039
dc.relation.urihttps://doi.org/10.1016/j.jiec.2012.06.003
dc.relation.urihttps://doi.org/10.1016/S0926-860X(02)00195-3
dc.relation.urihttps://doi.org/10.1016/j.ijhydene.2017.04.224
dc.relation.urihttps://doi.org/10.1016/j.jngse.2015.11.008
dc.relation.urihttps://doi.org/10.1016/S0924-0136(98)00405-1
dc.relation.urihttps://doi.org/10.1126/science.211.4487.1121
dc.relation.urihttps://doi.org/10.1016/B978-0-08-098353-0.00004-X
dc.relation.urihttps://doi.org/10.1016/j.molcata.2007.10.022
dc.relation.urihttps://doi.org/10.1016/0304-8853(93)91031-2
dc.relation.urihttps://doi.org/10.1016/j.apcata.2006.08.005
dc.relation.urihttps://doi.org/10.1006/jcat.1993.1051
dc.relation.urihttps://doi.org/10.1016/j.jtice.2015.03.017
dc.rights.holder© Національний університет “Львівська політехніка”, 2021
dc.rights.holder© Lari T., Mirzaei A., Atashi H., Bozorgzadeh H., 2021
dc.subjectмоделювання
dc.subjectрежим процесу
dc.subjectнанокаталізатор Fe-Co-Ce
dc.subjectносій
dc.subjectоптимізація
dc.subjectсинтез Фішера-Тропша
dc.subjectmodeling study
dc.subjectoperating conditions
dc.subjectFe-Co-Ce nanocatalyst
dc.subjectsupport
dc.subjectoptimization
dc.subjectFischer-Tropsch synthesis
dc.titleA Modeling Study of Operating Conditions and Different Supports on Fe-Co-Ce Nanocatalyst and Optimizing of Light Olefins Selectivity in the Fischer-Tropsch Synthesis
dc.title.alternativeМоделювання режиму процесу і носіїв каталізатора Fe-Co-Ce та оптимізація селективності легких олефінів при синтезі Фішера-Тропша
dc.typeArticle

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Chemistry & Chemical Technology. – 2021. – Vol. 15, No. 2