Initiating and Cross-Linking Properties of Urea-Formaldehyde Oligomers with Peroxide Groups

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dc.citation.epage417
dc.citation.issue3
dc.citation.spage411
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.authorAstakhova, Olena
dc.contributor.authorMykhailo Bratychak Jr.
dc.contributor.authorKohut, Ananiy
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2024-01-22T12:00:15Z
dc.date.available2024-01-22T12:00:15Z
dc.date.created2022-03-16
dc.date.issued2022-03-16
dc.description.abstractВивчені ініціюючі властивості пероксидних сечовино-формальдегідних олігомерів. Для порівняння вивчено ініціюючу активність у процесі полімеризації стирену пероксидним олігомером на основі епоксидного олігомеру Epidian-5 та трет.-бутилгідропероксиду. Структуруючі властивості сечовино-формальдегідних олігомерів з пероксидними групами вивчено на прикладі ненасичених олігоестерів. Хімізм процесу утворення продуктів просторово-зшитої будови досліджено з використанням ІЧ-спектроскопії.
dc.description.abstractThe initiating properties of urea-formaldehyde oligomers with peroxide groups have been studied. For comparison, the initiating activity has been examined for the polymerization of styrene by the peroxide oligomer based on the epoxy oligomer Epidian-5 and tert-butyl hydroperoxide. The cross-linking properties of the urea-formaldehyde oligomers with peroxide groups have been investigated using unsaturated oligoesters as a model. The chemistry of the formation of the substances with a cross-linked structure has been studied using IR spectroscopy.
dc.format.extent411-417
dc.format.pages7
dc.identifier.citationAstakhova O. Initiating and Cross-Linking Properties of Urea-Formaldehyde Oligomers with Peroxide Groups / Olena Astakhova, Mykhailo Bratychak Jr., Ananiy Kohut // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2022. — Vol 16. — No 3. — P. 411–417.
dc.identifier.citationenAstakhova O. Initiating and Cross-Linking Properties of Urea-Formaldehyde Oligomers with Peroxide Groups / Olena Astakhova, Mykhailo Bratychak Jr., Ananiy Kohut // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2022. — Vol 16. — No 3. — P. 411–417.
dc.identifier.doidoi.org/10.23939/chcht16.03.411
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/61006
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 3 (16), 2022
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dc.relation.references[9] Piesowicz, E.; Irska, I.; Bryll, K.; Gawdzinska, K.; Bratychak, M. Poly(butyleneterephthalate) Carbon Nanotubes Nanocomposites. Part II. Structure and Properties. Polimery 2016, 61(1), 24-30. https://doi.org/10.14314/polimery.2016.024
dc.relation.references[10] Piesowicz, E.; Irska, I.; Bratychak, M.; Roslaniec, Z. Poly(butylene terephthalate) Carbon Nanotubes Nanocomposites. Part I. Carbon Nanotubes Functionalization and in Situ Synthesis. Polimery 2015, 60(11-12), 680-685. https://doi.org/10.14314/polimery.2015.680
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dc.relation.references[13] Varvarenko, S.; Samaryk, V.; Nosova, N.; Puzko, N.; Taras, R.; Tarnavchyk, I.; Voronov, A.; Kohut, A.; Voronov, S. Prediction of Interfacial Interactions between Polymer Layers. Macromol Symp. 2010, 298(1), 72-78. https://doi.org/10.1002/masy.201000037
dc.relation.references[14] Bratychak, Mic.; Donchak, V.; Astakhova, O; Bratychak, Mik.; Shyshchak, O. Synthesis of Nitrogen-Containing Peroxy Oligomers Based on Epoxy Resins. Oxid. Commun. 2014, 37(1), 321-333. http://www.scopus.com/inward/record.url?eid=2-s2.0-84898659490&partnerID...
dc.relation.references[15] Bratychak, Mic.; Bratychak, Mih.; Brostow, W.; Shyshchak, O. Synthesis and Properties of Peroxy Derivatives of Epoxy Resins Based on Bisphenol A: Effects of the Presence of Boron Trifluoride Etherate. Mater. Res. Innov. 2002, 6(1), 24-30. https://doi.org/10.1007/s10019-002-0157-7
dc.relation.references[16] Zubyk, H.; Plonska-Brzezinska, M.; Shyshchak, O.; Astakhova, O.; Bratychak, M. Study of Phenol-Formaldehyde Oligomers Derivatives Structure by IR- and NMR-Spectroscopy. Chem. Chem. Technol. 2015, 9(4), 435-443. https://doi.org/10.23939/chcht09.04.435
dc.relation.references[17] Papathanassiou, A.; Sulikowski, B.; Bratychak, M.; Zubyk, H.; Mykhailiv, O.; Zambrzycka-Szelewa, E.; Plonska-Brzezinska, M. A Phenol-Formaldehyde Polymeric Network to Generate Organic Aerogels: Synthesis, Physicochemical Characteristics and Potential Applications. J. Mater. Chem. A 2018, 6(3), 845-852. http://dx.doi.org/10.1039/C7TA08814K
dc.relation.references[18] Astakhova, O.; Shyshchak, O.; Bratychak, M. Synthesis and Structure of Urea-Formaldehyde Oligomers with Peroxide Groups. Chem. Chem. Technol. 2021, 15(3), 369-376. https://doi.org/10.23939/chcht15.03.369
dc.relation.references[19] Astakhova, O.; Shyshchak, O.; Bratychak, M. Synthesis and Cross-Linking Properties of Melamine Formaldehyde Oligomers with Peroxy Groups. Chem. Chem. Technol. 2021, 15(4), 512-519. https://doi.org/10.23939/chcht15.04.512
dc.relation.references[20] Hawkins, E.G.E. Organic Peroxides: Their Formation and Reactions; E. & F.N. Spon: London, 1961.
dc.relation.references[21] Emanuel, N.M.; Knorre, D.G. Kurs khimicheskoi kinetiki. Vyshaya shkola: Moskva, 1984.
dc.relation.references[22] Tsvetkov, N.S.; Markovskaya, R.F. Kinetika termicheskogo razlozheniya polimernoi perekisi sebatsinovoi kisloty v tverdoi faze. Vysokomol. Soed. A 8(7), 1299-1304.
dc.relation.referencesen[1] Popadyuk, A.; Tarnavchyk, I.; Popadyuk, N.; Kohut, A.; Samaryk, V.; Voronov, S.; Voronov, A. A Novel Copolymer of N-[(tert-butylperoxy)methyl]acrylamide and Maleic Andydride for Use as a Reactive Surfactant in Emulsion Polymerization. React. Funct. Polym. 2013, 73(9), 1290-1298. https://doi.org/10.1016/j.reactfunctpolym.2013.07.002
dc.relation.referencesen[2] Nosova, N.; Roiter, Y.; Samaryk, V.; Varvarenko, S.; Stetsyshyn, Y.; Minko, S.; Stamm, M.; Voronov, S. Polypropylene Surface Peroxidation with Heterofunctional Polyperoxides. Macromol Symp. 2004, 210(1), 339-348. https://doi.org/10.1002/masy.200450638
dc.relation.referencesen[3] Samaryk, V.; Voronov, A.; Tarnavchyk, I.; Varvarenko, S.; Nosova, N.; Kohut, A.; Voronov, S. Interface Radical Reactions of Functional Polyperoxides for Fabrication of Three-Dimensional Polymeric Structures. In Radical Polymerization: New Developments; Paulauskas, I.O.; Urbonas, L.O., Eds.; Nova Sci., New York, 2012; pp 1-57.
dc.relation.referencesen[4] Varvarenko, S.; Voronov, A.; Samaryk, V.; Tarnavchyk, I.; Roiter, Y.; Minko, S.; Nosova, N.; Kohut, A.; Voronov, S. Polyolefin Surface Activation by Grafting of Functional Polyperoxide. React. Funct. Polym. 2011, 71(2), 210-218. https://doi.org/10.1016/j.reactfunctpolym.2010.11.028
dc.relation.referencesen[5] Bratychak, M.; Astakhova, O.; Shyshchak, O.; Zubal, O.; Sienkiewich, M.; Ivashkiv, O. Epoxy Composites Filled with Natural Calcium Carbonate. 1. Epoxy Composites Obtained in the Presence of Monoperoxy Derivate of Epidian-6 Epoxy Resin. Chem. Chem. Technol. 2019, 13(3), 360-364. https://doi.org/10.23939/chcht13.03.360
dc.relation.referencesen[6] Bratychak, M.; Bashta, B.; Astakhova, O.; Shyshchak, O.; Zubal, O. Synthesis, Mechanism and Properties of Epoxy Resins Modified with Adipinic Acid. Chem. Chem. Technol. 2019, 13(1), 52-58. https://doi.org/10.23939/chcht13.01.052
dc.relation.referencesen[7] Ivashkiv, O.; Namiesnik, Ja.; Astakhova, O.; Shyshchak, O.; Bratychak, M. Synthesis and Application of Oligomer with Hydroxy Groups Based on Peroxy Derivative of ED-24 Epoxy Resin and PolyTHT-2000 Oligoether. Chem. Chem. Technol. 2015, 9(3), 313-318. https://doi.org/10.23939/chcht09.03.313
dc.relation.referencesen[8] Iatsyshyn, O.; Astakhova, O.; Shyshchak, O.; Lazorko, O.; Bratychak, M. Monomethacrylate Derivative of ED-24 Epoxy Resin and its Application. Chem. Chem. Technol. 2013, 7(1), 73-77. https://doi.org/10.23939/chcht07.01.073
dc.relation.referencesen[9] Piesowicz, E.; Irska, I.; Bryll, K.; Gawdzinska, K.; Bratychak, M. Poly(butyleneterephthalate) Carbon Nanotubes Nanocomposites. Part II. Structure and Properties. Polimery 2016, 61(1), 24-30. https://doi.org/10.14314/polimery.2016.024
dc.relation.referencesen[10] Piesowicz, E.; Irska, I.; Bratychak, M.; Roslaniec, Z. Poly(butylene terephthalate) Carbon Nanotubes Nanocomposites. Part I. Carbon Nanotubes Functionalization and in Situ Synthesis. Polimery 2015, 60(11-12), 680-685. https://doi.org/10.14314/polimery.2015.680
dc.relation.referencesen[11] Bratychak, M.M.; Bratychak, Mykh.Mykh. Peroksydni pokhidni epoksydnykh smol; Lvivska politekhnika: Lviv, 2003.
dc.relation.referencesen[12] Roiter, Y.; Samaryk, V.; Varvarenko, S.; Nosova, N.; Tarnavchyk, I.; Pionteck, I.; Pötschke, P; Peroxide-containing Compatibilizer for Polypropylene Blends with other Polymers. Macromol Symp. 2004, 210(1), 209-217. https://doi.org/10.1002/masy.200450624
dc.relation.referencesen[13] Varvarenko, S.; Samaryk, V.; Nosova, N.; Puzko, N.; Taras, R.; Tarnavchyk, I.; Voronov, A.; Kohut, A.; Voronov, S. Prediction of Interfacial Interactions between Polymer Layers. Macromol Symp. 2010, 298(1), 72-78. https://doi.org/10.1002/masy.201000037
dc.relation.referencesen[14] Bratychak, Mic.; Donchak, V.; Astakhova, O; Bratychak, Mik.; Shyshchak, O. Synthesis of Nitrogen-Containing Peroxy Oligomers Based on Epoxy Resins. Oxid. Commun. 2014, 37(1), 321-333. http://www.scopus.com/inward/record.url?eid=2-s2.0-84898659490&partnerID...
dc.relation.referencesen[15] Bratychak, Mic.; Bratychak, Mih.; Brostow, W.; Shyshchak, O. Synthesis and Properties of Peroxy Derivatives of Epoxy Resins Based on Bisphenol A: Effects of the Presence of Boron Trifluoride Etherate. Mater. Res. Innov. 2002, 6(1), 24-30. https://doi.org/10.1007/s10019-002-0157-7
dc.relation.referencesen[16] Zubyk, H.; Plonska-Brzezinska, M.; Shyshchak, O.; Astakhova, O.; Bratychak, M. Study of Phenol-Formaldehyde Oligomers Derivatives Structure by IR- and NMR-Spectroscopy. Chem. Chem. Technol. 2015, 9(4), 435-443. https://doi.org/10.23939/chcht09.04.435
dc.relation.referencesen[17] Papathanassiou, A.; Sulikowski, B.; Bratychak, M.; Zubyk, H.; Mykhailiv, O.; Zambrzycka-Szelewa, E.; Plonska-Brzezinska, M. A Phenol-Formaldehyde Polymeric Network to Generate Organic Aerogels: Synthesis, Physicochemical Characteristics and Potential Applications. J. Mater. Chem. A 2018, 6(3), 845-852. http://dx.doi.org/10.1039/P.7TA08814K
dc.relation.referencesen[18] Astakhova, O.; Shyshchak, O.; Bratychak, M. Synthesis and Structure of Urea-Formaldehyde Oligomers with Peroxide Groups. Chem. Chem. Technol. 2021, 15(3), 369-376. https://doi.org/10.23939/chcht15.03.369
dc.relation.referencesen[19] Astakhova, O.; Shyshchak, O.; Bratychak, M. Synthesis and Cross-Linking Properties of Melamine Formaldehyde Oligomers with Peroxy Groups. Chem. Chem. Technol. 2021, 15(4), 512-519. https://doi.org/10.23939/chcht15.04.512
dc.relation.referencesen[20] Hawkins, E.G.E. Organic Peroxides: Their Formation and Reactions; E. & F.N. Spon: London, 1961.
dc.relation.referencesen[21] Emanuel, N.M.; Knorre, D.G. Kurs khimicheskoi kinetiki. Vyshaya shkola: Moskva, 1984.
dc.relation.referencesen[22] Tsvetkov, N.S.; Markovskaya, R.F. Kinetika termicheskogo razlozheniya polimernoi perekisi sebatsinovoi kisloty v tverdoi faze. Vysokomol. Soed. A 8(7), 1299-1304.
dc.relation.urihttps://doi.org/10.1016/j.reactfunctpolym.2013.07.002
dc.relation.urihttps://doi.org/10.1002/masy.200450638
dc.relation.urihttps://doi.org/10.1016/j.reactfunctpolym.2010.11.028
dc.relation.urihttps://doi.org/10.23939/chcht13.03.360
dc.relation.urihttps://doi.org/10.23939/chcht13.01.052
dc.relation.urihttps://doi.org/10.23939/chcht09.03.313
dc.relation.urihttps://doi.org/10.23939/chcht07.01.073
dc.relation.urihttps://doi.org/10.14314/polimery.2016.024
dc.relation.urihttps://doi.org/10.14314/polimery.2015.680
dc.relation.urihttps://doi.org/10.1002/masy.200450624
dc.relation.urihttps://doi.org/10.1002/masy.201000037
dc.relation.urihttp://www.scopus.com/inward/record.url?eid=2-s2.0-84898659490&partnerID..
dc.relation.urihttps://doi.org/10.1007/s10019-002-0157-7
dc.relation.urihttps://doi.org/10.23939/chcht09.04.435
dc.relation.urihttp://dx.doi.org/10.1039/C7TA08814K
dc.relation.urihttps://doi.org/10.23939/chcht15.03.369
dc.relation.urihttps://doi.org/10.23939/chcht15.04.512
dc.rights.holder© Національний університет “Львівська політехніка”, 2022
dc.rights.holder© Astakhova O., Bratychak Jr, M., Kohut A., 2022
dc.subjectсечовино-формальдегідні олігомери
dc.subjectпероксид
dc.subjectстирен
dc.subjectненасичені олігоестери
dc.subjectEpidian-5
dc.subjectініціюючі та структуруючи властивості
dc.subjectЕПР-метод
dc.subjectІЧ-спектроскопія
dc.subjecturea-formaldehyde oligomers
dc.subjectperoxide
dc.subjectstyrene
dc.subjectunsaturated oligoesters
dc.subjectEpidian-5
dc.subjectinitiating and cross-linking properties
dc.subjectEPR method
dc.subjectIR spectroscopy
dc.titleInitiating and Cross-Linking Properties of Urea-Formaldehyde Oligomers with Peroxide Groups
dc.title.alternativeІніціюючі та структуруючі властивості сечовино-формальдегідних олігомерів з пероксидними групами
dc.typeArticle

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Chemistry & Chemical Technology. – 2022. – Vol. 16, No. 3