Linear Hexane Isomerization Over Bimetallic Zeolite Catalysts

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dc.citation.epage335
dc.citation.issue3
dc.citation.spage330
dc.contributor.affiliationV. P. Kukhar Institute of Bioorganic Chemistry and Petrochemistry of National Academy of Sciences of Ukraine
dc.contributor.authorPatrylak, Lyubov
dc.contributor.authorPertko, Oleksandra
dc.contributor.authorVoloshyna, Yuliya
dc.contributor.authorYakovenko, Angela
dc.contributor.authorPovazhnyi, Volodymyr
dc.contributor.authorMelnychuk, Oleksandr
dc.contributor.authorZlochevskyi, Kostyantyn
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2024-01-09T11:31:47Z
dc.date.available2024-01-09T11:31:47Z
dc.date.created2021-03-16
dc.date.issued2021-03-16
dc.description.abstractПроведено оцінювання активності та селективності в ізомеризації н-гексану біметалічних цеолітних каталізаторів, що окрім паладію містять перехідний метал нікель. Синтезовано біметалічні біфункціональні каталізатори ізомеризації лінійних алканів на основі водневої форми цеоліту MFI. Пористі властивості зразків досліджено методом низькотемпературної адсорбції/десорбції азоту, розміри металічної компоненти – ТЕМ, а каталітичні властивості – у мікроімпульсній ізомеризації н-гексану. Знайдено антибатну залежність температури максимального виходу ізомерів гексану від кількості нікелю у зразку за сталого вмісту паладію. Показано, що введення нікелю дає можливість понизити оптимальну температуру процесу з 598 до 523 К.
dc.description.abstractThe aim of this study was to evaluate the activity and selectivity in isomerization of n-hexane of bimetallic zeolite catalysts containing a nickel transition metal in addition to palladium. Bimetallic bifunctional linear alkane isomerization catalysts based on the hydrogen form of MFI zeolite have been synthesized. The porous properties of the samples were investigated by means of low-temperature nitrogen adsorption/desorption, the size of the metal component – by TEM, and the catalytic properties – in the micro-pulse isomerization of n-hexane. Antisymbatic correlation between the temperature of the maximum yield of hexane isomers and the amount of nickel in the sample was found for a stable palladium content. The introduction of nickel allows to reduce the optimum process temperature from 598 to 523 K.
dc.format.extent330-335
dc.format.pages6
dc.identifier.citationLinear Hexane Isomerization Over Bimetallic Zeolite Catalysts / Lyubov Patrylak, Oleksandra Pertko, Yuliya Voloshyna, Angela Yakovenko, Volodymyr Povazhnyi, Oleksandr Melnychuk, Kostyantyn Zlochevskyi // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2021. — Vol 15. — No 3. — P. 330–335.
dc.identifier.citationenLinear Hexane Isomerization Over Bimetallic Zeolite Catalysts / Lyubov Patrylak, Oleksandra Pertko, Yuliya Voloshyna, Angela Yakovenko, Volodymyr Povazhnyi, Oleksandr Melnychuk, Kostyantyn Zlochevskyi // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2021. — Vol 15. — No 3. — P. 330–335.
dc.identifier.doidoi.org/10.23939/chcht15.03.330
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/60748
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 3 (15), 2021
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dc.relation.referencesen[3] Liu S., Ren J., Zhang H. et al., J. Catal., 2016, 335, 11. https://doi.org/10.1016/j.jcat.2015.12.009
dc.relation.referencesen[4] Dhar A., Vekariya R., Sharma P., Petroleum, 2017, 3, 489. https://doi.org/10.1016/j.petlm.2017.02.001
dc.relation.referencesen[5] Izutsu Y., Oku Y., Hidaka Y. et al., Catal. Lett., 2013, 143, 486. https://doi.org/10.1007/s10562-013-0973-y
dc.relation.referencesen[6] Ghouri A., Usman M., J. Chem. Soc. Pak., 2017, 39, 919.
dc.relation.referencesen[7] Dhar A., Vekariya R., Bhadja P., Cogent Chemistry, 2018, 4, 1514686. https://doi.org/10.1080/23312009.2018.1514686
dc.relation.referencesen[8] Yoshioka C., Garetto T., Cardoso D., Catal. Today, 2005, 107–108, 693. https://doi.org/10.1016/j.cattod.2005.07.056
dc.relation.referencesen[9] Jordao M., Simoes V., Cardoso D., Appl. Catal. A-Gen., 2007, 319, 1. https://doi.org/10.1016/j.apcata.2006.09.039
dc.relation.referencesen[10] Lima P., Garetto T., Cavalcante C. et al., Catal. Today, 2011, 172, 195. https://doi.org/10.1016/j.cattod.2011.02.031
dc.relation.referencesen[11] Martins G., dos Santos E., Rodrigues M. et al., Modern Res. Catal., 2013, 2, 119. https://doi.org/10.4236/mrc.2013.24017
dc.relation.referencesen[12] Patrylak K., Patrylak L., Manza I., Taranookha O., Petrol. Chem., 2001, 41, 383.
dc.relation.referencesen[13] Patrylak L., Krylova M., Pertko O. et al., J. Porous Mater., 2019, 26, 861. https://doi.org/10.1007/s10934-018-0685-1
dc.relation.referencesen[14] Patrylak L., Likhnyovskyi R., Vypyraylenko V. et al., Adsorpt. Sci. Technol., 2001, 19, 525. https://doi.org/10.1260/0263617011494376
dc.relation.referencesen[15] Rouquerol F., Rouquerol J., Sing K., Adsorption by Powders and Porous solids. Principles, Methodology and Applications. Academic Press, San Diego 1999.
dc.relation.referencesen[16] Cychosz K., Guillet-Nicolas R., García-Martínez J., Thommes M., Chem. Soc. Rev., 2017, 46, 389. https://doi.org/10.1039/P.6CS00391E
dc.relation.referencesen[17] Thommes M., Chemie Ingenieur Technik, 2010, 82, 1059. https://doi.org/10.1002/cite.201000064
dc.relation.referencesen[18] Hernández M., Rojas F., Lara V., J. Porous Mater., 2000, 7, 443. https://doi.org/10.1023/A:1009662408173
dc.relation.referencesen[19] Sing S., Williams R., Adsorpt. Sci. Technol., 2004, 22, 773. https://doi.org/10.1260/0263617053499032
dc.relation.referencesen[20] Wan W., Su J., Zou X., Willhammar T., Inorg. Chem. Front., 2018, 5, 2836. https://doi.org/10.1039/P.8QI00806J
dc.relation.referencesen[21] Juneau M., Liu R., Peng Y. et al., Chem. Cat. Chem., 2020, 12, 1826. https://doi.org/10.1002/cctc.201902039
dc.relation.referencesen[22] Peron D., Zholobenko V., de la Rocha M. et al., J. Mater. Sci., 2019, 54, 5399. https://doi.org/10.1007/s10853-018-03250-59
dc.relation.referencesen[23] Mazaheri O., Kalbasi R., RSC Adv., 2015, 5, 34398. https://doi.org/10.1039/P.5RA02349A
dc.relation.referencesen[24] Patrylak L., Krylova M., Pertko O. et al., Chem. Chem. Technol., 2020, 14, 234. https://doi.org/10.23939/chcht14.02.234
dc.relation.referencesen[25] Voloshyna Yu., Pertko O., Krylova M. et al., Kataliz ta Naftohimia, 2019, 28, 20. https://doi.org/10.15407/kataliz2019.28.020
dc.relation.referencesen[26] Voloshyna Yu., Pertko O., Patrylak L., Yakovenko A., Voprosy Khimii i Khimicheskoi Technologii, 2020, 6, 26. https://doi.org/10.32434/0321-4095-2020-133-6-26-32
dc.relation.referencesen[27] Karakoulia S., Heracleous E., Lappas A., Catal. Today, 2019, in press. https://doi.org/10.1016/j.cattod.2019.04.072
dc.relation.referencesen[28] Bhavani A., Pandurangan A., J. Mol. Catal. A-Chem., 2007, 267, 209. https://doi.org/10.1016/j.molcata.2006.11.044
dc.relation.referencesen[29] Barsi F., Cardoso D., Braz. J. Chem. Eng., 2009, 26, 353. https://doi.org/10.1590/S0104-66322009000200012
dc.relation.referencesen[30] Patrylak L., Manza I., Vypirailenko V. et al., Theor. Experim. Chem., 2003, 39, 263. https://doi.org/10.1023/A:1025729530977
dc.relation.urihttps://doi.org/10.2478/s11532-013-0354-9
dc.relation.urihttps://doi.org/10.1039/C3CS60394F
dc.relation.urihttps://doi.org/10.1016/j.jcat.2015.12.009
dc.relation.urihttps://doi.org/10.1016/j.petlm.2017.02.001
dc.relation.urihttps://doi.org/10.1007/s10562-013-0973-y
dc.relation.urihttps://doi.org/10.1080/23312009.2018.1514686
dc.relation.urihttps://doi.org/10.1016/j.cattod.2005.07.056
dc.relation.urihttps://doi.org/10.1016/j.apcata.2006.09.039
dc.relation.urihttps://doi.org/10.1016/j.cattod.2011.02.031
dc.relation.urihttps://doi.org/10.4236/mrc.2013.24017
dc.relation.urihttps://doi.org/10.1007/s10934-018-0685-1
dc.relation.urihttps://doi.org/10.1260/0263617011494376
dc.relation.urihttps://doi.org/10.1039/C6CS00391E
dc.relation.urihttps://doi.org/10.1002/cite.201000064
dc.relation.urihttps://doi.org/10.1023/A:1009662408173
dc.relation.urihttps://doi.org/10.1260/0263617053499032
dc.relation.urihttps://doi.org/10.1039/C8QI00806J
dc.relation.urihttps://doi.org/10.1002/cctc.201902039
dc.relation.urihttps://doi.org/10.1007/s10853-018-03250-59
dc.relation.urihttps://doi.org/10.1039/C5RA02349A
dc.relation.urihttps://doi.org/10.23939/chcht14.02.234
dc.relation.urihttps://doi.org/10.15407/kataliz2019.28.020
dc.relation.urihttps://doi.org/10.32434/0321-4095-2020-133-6-26-32
dc.relation.urihttps://doi.org/10.1016/j.cattod.2019.04.072
dc.relation.urihttps://doi.org/10.1016/j.molcata.2006.11.044
dc.relation.urihttps://doi.org/10.1590/S0104-66322009000200012
dc.relation.urihttps://doi.org/10.1023/A:1025729530977
dc.rights.holder© Національний університет “Львівська політехніка”, 2021
dc.rights.holder© Patrylak L., Pertko O., Voloshyna Y., Yakovenko A., Povazhnyi V., Melnychuk O., Zlochevskyi K., 2021
dc.subjectпентасил
dc.subjectнікель
dc.subjectпаладій
dc.subjectізомеризація гексану
dc.subjectpentasil zeolite
dc.subjectnickel
dc.subjectpalladium
dc.subjecthexane isomerization
dc.titleLinear Hexane Isomerization Over Bimetallic Zeolite Catalysts
dc.title.alternativeІзомеризація лінійного гексану на біметалічних цеолітних каталізаторах
dc.typeArticle

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Chemistry & Chemical Technology. – 2021. – Vol. 15, No. 3