Method for Obtaining Isothermal Diagrams of the Liquid - Vapor Equilibrium for the System as Dimethyl Zinc - Dimethyl Telluride

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dc.citation.epage480
dc.citation.issue3
dc.citation.spage469
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.authorGerasymchuk, Serhiy
dc.contributor.authorPoliuzhyn, Ihor
dc.contributor.authorSerheyev, Valentyn
dc.contributor.authorHnativ, Tetiana
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2024-02-12T08:51:54Z
dc.date.available2024-02-12T08:51:54Z
dc.date.created2023-02-28
dc.date.issued2023-02-28
dc.description.abstractЗа отриманими експериментальними температурними залежностями тиску насиченої пари розчинів диметилцинк – диметилтелурид з вмістом диметилцинку 50,0 та 70,32 % (мольн.) зроблено ізотермічні перерізи (280, 290, 300, 310 та 320 К ). На основі обмеженого набору експе¬риментальних даних для рівноваги “рідина–пара” проведено розрахунок складу пари за рівнянням Дюгема – Маргулеса, а також парціальних тисків та коефіцієнту розподілу системи диметилцинк – диметилтелурид.
dc.description.abstractAccording to the obtained experimental temperature dependences of the saturated vapor pressure on dimethylzinc – dimethyltelluride solutions with dimethylzinc content of 50.0 and 70.32 mol. %, isothermal sections (280, 290, 300, 310, and 320 K) were made. For the dimethylzinc – dimethyltelluride system based on a limited set of experimental data for the “liquid-vapor” equilibrium, the vapor composition was calculated according to the Duhem – Margules equation, as well as the partial pressures and the distribution coefficient.
dc.format.extent469-480
dc.format.pages12
dc.identifier.citationMethod for Obtaining Isothermal Diagrams of the Liquid - Vapor Equilibrium for the System as Dimethyl Zinc - Dimethyl Telluride / Serhiy Gerasymchuk, Ihor Poliuzhyn, Valentyn Serheyev, Tetiana Hnativ // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2023. — Vol 17. — No 3. — P. 469–480.
dc.identifier.citationenMethod for Obtaining Isothermal Diagrams of the Liquid - Vapor Equilibrium for the System as Dimethyl Zinc - Dimethyl Telluride / Serhiy Gerasymchuk, Ihor Poliuzhyn, Valentyn Serheyev, Tetiana Hnativ // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2023. — Vol 17. — No 3. — P. 469–480.
dc.identifier.doidoi.org/10.23939/chcht17.03.469
dc.identifier.issn1196-4196
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/61260
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 3 (17), 2023
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dc.relation.referencesen[1] Serheyev, V. Enthalpies of Mixing Methylmethacrylate with Some Organic Solvents. Chem. Chem. Technol. 2012, 6, 15-18. https://doi.org/10.23939/chcht06.01.015
dc.relation.referencesen[2] Serheyev, V. The Enthalpy of Mixing of the Laurylmethacrylate with Some Organic Solvents. Chem. Chem. Technol. 2015, 9, 1-4. https://doi.org/10.23939/chcht09.01.001
dc.relation.referencesen[3] Serheyev, V. Densities, Excess Volumes, and Partial Molar Volumes of Butyl Methacrylate Solutions in Some Organic Sol-vents. Chem. Chem. Technol. 2023, 17, 1-6. https://doi.org/10.23939/chcht17.01.001
dc.relation.referencesen[4] Serheyev, V.; Kos, Yu.; Van-Chin-Syan, Yu. Thermodynamic Properties of Solutions of Ethacrylic Acid in Acetonitrile and Acetic Acid. Chem. Chem. Technol. 2015, 9, 131-135. https://doi.org/10.23939/chcht09.02.131
dc.relation.referencesen[5] Serheyev, V.; Tran Van Thanh. Thermodynamic Properties of Butyl Methacrylate Solutions in Organic Solvents. Chem. Chem. Technol. 2018, 12, 7-12. https://doi.org/10.23939/chcht12.01.007
dc.relation.referencesen[6] Poling, B.E.; Prausnitz, J.M.; OConnell, J.P. The properties of gases and liquids. (5th Edition); New York: McGraw Hill, 2001
dc.relation.referencesen[7] Gerasymchuk, S.I.; Poliuzhyn, I.P.; Melnyk, H.V.; Pavlovskyi, Y.P.; Sergeyev, V.V. Phase Vapor–Liquid Equilibrium for the Solutions of Dimethylzinc and Dimethyl Selenide. Chem. Technol. Appl. Substan. 2019, 2, 1-6. https://doi.org/10.23939/ctas2019.02.001
dc.relation.referencesen[8] Gerasimchuk, S.I.; Poliuzhyn, I.P.; Melnyk, H.V.; Pavlovskyi, Y.P.; Serheyev, V.V. Rhase Vapor–Liquid Equilibrium for the Solutions of Dimethyltelluride and Dimethylcadmium. Chem. Tech-nol. Appl. Substan. 2020, 3, 1-8. https://doi.org/10.23939/ctas2020.01.001
dc.relation.referencesen[9] Gerasymchuk, S.I.; Poliuzhyn, I.P.; Melnyk, H.V.; Pavlovskyi, Y.P.; Serheyev, V.V. Phase Vapor–Liquid Equilibrium for the Solutions of Diethyl Selenide and Diethylzinc. Chem. Technol. Appl. Substan. 2021, 4, 10-16. https://doi.org/10.23939/ctas2021.02.010
dc.relation.referencesen[10] Gerasymchuk, S.I.; Poliuzhyn, I.P.; Oliynyk, L.P.; Hnativ, T.B. Evaporation Thermodynamics for Solutions of Dimethylzinc and Dimethyltelluride. Chem. Technol. Appl. Substan. 2022, 5, 37-46. https://doi.org/10.23939/ctas2022.02.037
dc.relation.referencesen[11] Dimethyl telluride. NIST Chemistry Webbook, SRD 69. https://webbook.nist.gov/cgi/cbook.cgi?Formula=P.2h6Te&NoIon=on&Units=SI&...
dc.relation.referencesen[12] Gerasymchuk, S.I. Thermodynamics of evaporation for alkyl compounds of zinc, selenium, tellurium and their solutions. Ph.D. Thesis, Lviv Polytechnic Institute, Lviv, Ukraine, 1991.
dc.relation.referencesen[13] Search for Species Data by Chemical Formula. NIST Chemi-stry Webbook, SRD 69. https://webbook.nist.gov/chemistry/.
dc.relation.referencesen[14] Glantz, S.A.; Slinker, B.K.; Neilands, T.B. Primer of Applied Regression & Analysis of variance; McGraw-Hill Education: New York, 2016.
dc.relation.urihttps://doi.org/10.23939/chcht06.01.015
dc.relation.urihttps://doi.org/10.23939/chcht09.01.001
dc.relation.urihttps://doi.org/10.23939/chcht17.01.001
dc.relation.urihttps://doi.org/10.23939/chcht09.02.131
dc.relation.urihttps://doi.org/10.23939/chcht12.01.007
dc.relation.urihttps://doi.org/10.23939/ctas2019.02.001
dc.relation.urihttps://doi.org/10.23939/ctas2020.01.001
dc.relation.urihttps://doi.org/10.23939/ctas2021.02.010
dc.relation.urihttps://doi.org/10.23939/ctas2022.02.037
dc.relation.urihttps://webbook.nist.gov/cgi/cbook.cgi?Formula=c2h6Te&NoIon=on&Units=SI&..
dc.relation.urihttps://webbook.nist.gov/chemistry/
dc.rights.holder© Національний університет “Львівська політехніка”, 2023
dc.rights.holder© Gerasymchuk S., Poliuzhyn I., Serheyev V., Hnativ T., 2023
dc.subjectдіаграми стану
dc.subjectрівноваги рідина–пара
dc.subjectдиметилцинк–диметилтелурид
dc.subjectтиск пари
dc.subjectdiagrams of state
dc.subjectliquid-vapor equilibria
dc.subjectdimethyl zinc – dimethyl telluride
dc.subjectvapor pressure
dc.titleMethod for Obtaining Isothermal Diagrams of the Liquid - Vapor Equilibrium for the System as Dimethyl Zinc - Dimethyl Telluride
dc.title.alternativeМетод отримання ізотермічних діаграм рівноваги рідина–пара системи диметил цинк–диметил телурид
dc.typeArticle

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Chemistry & Chemical Technology. – 2023. – Vol. 17, No. 3