Study on Chemistry of Oxidative Desulfurization Process of High Sulfur Straight-Run Oil Fraction

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dc.citation.epage422
dc.citation.issue3
dc.citation.spage414
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.affiliationNational Technical University, Kharkiv Polytechnic Institute
dc.contributor.affiliationResearch Initiative for Sustainable Energy Technologies
dc.contributor.authorPyshyev, Serhiy
dc.contributor.authorKorchak, Bohdan
dc.contributor.authorMiroshnichenko, Denis
dc.contributor.authorNyakuma, Bemgba Bevan
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2024-01-09T11:31:43Z
dc.date.available2024-01-09T11:31:43Z
dc.date.created2021-03-16
dc.date.issued2021-03-16
dc.description.abstractПроаналізовано хімізм процесу некаталітичного оксидаційного знесірчення дистилятних нафтових фракцій. Проведено дослідження характеристик високосірчистої прямогонної дизельного фракції вузького складу (593–623 К) до і після окиснення повітрям за 453–493 К та тиску 3,0 МПа. Визначено груповий склад сірчистих сполук у фракції вихідної сировини. Показано, що прямогонні фракції вихідної сировини можуть також містити сульфоксиди, які є продуктами окиснення сірчаноорганічних сполук і утворюються при зберіганні нафтопродуктів. На основі ІЧ-спектроскопічних досліджень вихідної сировини, окиснених продуктів та модельних сумішей проаналізовано глибину перетворення у вищезгаданому процесі сірчистих сполук фр. 593–623 К, які розподіляються у вигляді сульфонів та сульфоксидів у твердих і рідких продуктах окиснення й частково залишаються в очищеному паливі.
dc.description.abstractIn the article the chemistry of the noncatalytic oxidative desulfurization process of distillate oil fractions is analyzed. The study involves the characteristics of high-sulfur straight-run diesel fraction of narrow composition (593–623 K) before and after oxidation by air at 453–493 K and a pressure of 3.0 MPa. The composition of sulfur compounds in the raw material fraction was determined. It is shown that straight-run fractions of raw materials may also contain sulfoxides, which are products of oxidation of organosulfur compounds and are formed during storage of petroleum products. On the basis of IR spectroscopic studies of raw materials, oxidized products and model mixtures, the transformation depth of fr. 593–623 K sulfur compounds, which are distributed in the form of sulfones and sulfoxides in solid and liquid oxidation products, and partially remain in the purified fuel, was analyzed in the above-mentioned process.
dc.format.extent414-422
dc.format.pages9
dc.identifier.citationStudy on Chemistry of Oxidative Desulfurization Process of High Sulfur Straight-Run Oil Fraction / Serhiy Pyshyev, Bohdan Korchak, Denis Miroshnichenko, Bemgba Bevan Nyakuma // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2021. — Vol 15. — No 3. — P. 414–422.
dc.identifier.citationenStudy on Chemistry of Oxidative Desulfurization Process of High Sulfur Straight-Run Oil Fraction / Serhiy Pyshyev, Bohdan Korchak, Denis Miroshnichenko, Bemgba Bevan Nyakuma // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2021. — Vol 15. — No 3. — P. 414–422.
dc.identifier.doidoi.org/10.23939/chcht15.03.414
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/60739
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 3 (15), 2021
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dc.relation.referencesen[1] Ismagilov Z., Yashnik S., Kerzhentsev M. et al., Cat. Rev. Sci. Eng., 2011, 53, 199. https://doi.org/10.1080/01614940.2011.596426
dc.relation.referencesen[2] U.S.EPA Regulatory Impact Analysis: Heavy-Duty Engine and Vehicle Standards and Highway Diesel Fuel Sulfur Control Requirements. EPA 420-R-00-026. December 2000.
dc.relation.referencesen[3] Directive 98/70/EC of the European Parliament and of the Council of 13 October 1998 relating to the quality of petrol and diesel fuels and amending Council Directive 93/12/EEC.
dc.relation.referencesen[4] Directive 2009/30/EC of the European Parliament and of the Council of 23rd April 2009 amending Directive 98/70/EC as regards the specification of petrol, diesel and gas-oil and introducing a mechanism to monitor and reduce greenhouse gas emissions and amending Council Directive 1999/32/EC as regards the specification of fuel used by inland waterway vessels and repealing Directive 93/12/EEC.
dc.relation.referencesen[5] EN 590:2009. Automotive fuels. Diesel. Requirements and test methods.
dc.relation.referencesen[6] https://www.epa.gov/sites/production/files/2015-08/documents/peg.pdf
dc.relation.referencesen[7] https://www.oica.net/wp-content/uploads/2007/06/wwfc-fourth-edition-sep-...
dc.relation.referencesen[8] DSTU 8705:2017. Diesel fuel for long-term storage. Specification.
dc.relation.referencesen[9] DSTU 7688:2015. Diesel fuel EURO. Specification.
dc.relation.referencesen[10] DSTU 4840:2007. Diesel fuel of improved quality. Specification.
dc.relation.referencesen[11] Link D., Baltrus J., Rothenberger K. et al., Energy Fuels, 2003, 17, 1292. https://doi.org/10.1021/ef0300747
dc.relation.referencesen[12] http://large.stanford.edu/courses/2017/ph240/chhoa1/docs/exxon-2008.pdf
dc.relation.referencesen[13] Huaming L., Lining H., Jidong L. et al., Energy Fuels, 2009, 23, 1354. https://doi.org/10.1021/ef800797n
dc.relation.referencesen[14] van Rheinberg O., Klaus L., Heinrich K. et al., Fuel, 2008, 87, 2988. https://doi.org/10.1016/j.fuel.2008.03.020
dc.relation.referencesen[15] Babich I., Moulijn J., Fuel, 2003, 82, 607. https://doi.org/10.1016/S0016-2361(02)00324-1
dc.relation.referencesen[16] Banisharif F., Dehghani M., Capel-Sánchez M., Campos-Martin J., Ind. Eng. Chem. Res., 2017, 56, 3839. https://doi.org/10.1021/acs.iecr.7b00089
dc.relation.referencesen[17] Chen L.-J., Li F.-T., Pet. Sci. Technol., 2015, 33, 196. https://doi.org/10.1080/10916466.2014.974817
dc.relation.referencesen[18] Julião D., Mirante F. et al., Fuel, 2019, 241, 616. https://doi.org/10.1016/j.fuel.2018.11.095
dc.relation.referencesen[19] Liu W., Li T., Yu G. et al., Fuel, 2020, 265, 116967. https://doi.org/10.1016/j.fuel.2019.116967
dc.relation.referencesen[20] Mirante F., Alves A. et al., Fuel, 2020, 259, 116213. https://doi.org/10.1016/j.fuel.2019.116213
dc.relation.referencesen[21] Jatav S., Srivastava V., Pet. Sci. Technol., 2019, 37, 633. https://doi.org/10.1080/10916466.2018.1560323
dc.relation.referencesen[22] Wan Mokhtar W., Wan Azelee Wan Abu Bakar et al., Pet. Sci. Technol., 2018, 36:21, 1741. https://doi.org/10.1080/10916466.2018.1511581
dc.relation.referencesen[23] Wang B., Dai B., Kang L., Zhu M., Fuel, 2020, 265, 117029. https://doi.org/10.1016/j.fuel.2020.117029
dc.relation.referencesen[24] Tang X.-D., Wang C., Li J.-J. et al., Pet. Sci. Technol., 2020, 38, 723. https://doi.org/10.1080/10916466.2020.1771365
dc.relation.referencesen[25] Zhao D., H. Ren, Y. Zhao & J. Jia., Petroleum Science and Technology, 2009, 27:12, 1338. https://doi.org/10.1080/10916460802105682
dc.relation.referencesen[26] Pysh’yev S., Bratychak M., Lazorko O., Shyshchak O., Pol. J. Environ. Stud., 2005, 14, 123.
dc.relation.referencesen[27] Pysh’yev S., Lazorko O., Bratychak M., Chem. Chem. Technol., 2009, 3, 77.
dc.relation.referencesen[28] Lazorko O., Pysh’yev S., Bratychak M., Chem. Chem. Technol., 2008, 2, 309.
dc.relation.referencesen[29] Pysh’yev S., Lazorko O., Bratychak M., Chem. Chem. Technol., 2009, 3, 163.
dc.relation.referencesen[30] Paniv P., Pysh’yev S., Haivanovych V., Lazorko O., Chem. Tech. Fuels Oils, 2006, 3, 7.
dc.relation.referencesen[31] Pysh’yev S., Chem. Chem. Technol., 2012, 6, 229. https://doi.org/10.23939/chcht06.02.229
dc.relation.referencesen[32] Korchak B., Grynyshyn O., Chervinskyy T. et al., Chem. Chem. Technol., 2020, 14, 129. https://doi.org/10.23939/chcht14.01.129
dc.relation.referencesen[33] Pysh’yev S., Bratychak M., Chem. Chem. Technol., 2020, 14, 403. https://doi.org/10.23939/chcht14.03.403
dc.relation.referencesen[34] Oae S., Organic Chemistry of Sulfur. Springer 1977. https://doi.org/10.1007/978-1-4684-2049-4
dc.relation.referencesen[35] Collins F., Lucy A., Sharp Ch., J. Mol. Catal. A., 1997, 117, 397. https://doi.org/10.1016/S1381-1169(96)00251-8
dc.relation.referencesen[36] Nakanishi K., Infrared Absorption Spectroscopy – Practical. Holden-Day, Inc., San Francisco 1964.
dc.relation.referencesen[37] Bolshakov G., Sulfur Reports, 1986, 5, 103. https://doi.org/10.1080/01961772.1986.10878150
dc.relation.referencesen[38] Bolshakov G., Infrakrasnye Spectry Arenov. Monograph. Nauka, Novosibirsk 1989.
dc.relation.referencesen[39] Bellamy L., The Infra-Red Spectra of Complex Molecules. Springer, Netherlands 1975. https://doi.org/10.1007/978-94-011-6017-9
dc.relation.referencesen[40] Kazitsina L., Kupletskaya N., Primenenie UF-, IK-, YMR- i Mass-spektroskopii v Organicheskoi Khimii. Khimia, Moskva 1997.
dc.relation.referencesen[41] Bolshakov G., Glebovskaya E., Kaplan Z., Spektry i Radiogrammy Heteroorganicheskykh Soedinenii. Khimia, Leningrad 1967.
dc.relation.referencesen[42] Wartewig S., IR and Raman Spectroscopy Fundamental Processing. Wiley-VCH Verlag GmbH, Weinheim 2003. https://doi.org/10.1002/3527601635
dc.relation.referencesen[43] Karaulova E., Khimia Neftianykh Sulfidov. Nauka, Moskva 1970.
dc.relation.referencesen[44] Odinokov V., Kukovinets O., Ishmuratov G. et al., Neftekhimia, 1979, 19, 103.
dc.relation.urihttps://doi.org/10.1080/01614940.2011.596426
dc.relation.urihttps://www.epa.gov/sites/production/files/2015-08/documents/peg.pdf
dc.relation.urihttps://www.oica.net/wp-content/uploads/2007/06/wwfc-fourth-edition-sep-..
dc.relation.urihttps://doi.org/10.1021/ef0300747
dc.relation.urihttp://large.stanford.edu/courses/2017/ph240/chhoa1/docs/exxon-2008.pdf
dc.relation.urihttps://doi.org/10.1021/ef800797n
dc.relation.urihttps://doi.org/10.1016/j.fuel.2008.03.020
dc.relation.urihttps://doi.org/10.1016/S0016-2361(02)00324-1
dc.relation.urihttps://doi.org/10.1021/acs.iecr.7b00089
dc.relation.urihttps://doi.org/10.1080/10916466.2014.974817
dc.relation.urihttps://doi.org/10.1016/j.fuel.2018.11.095
dc.relation.urihttps://doi.org/10.1016/j.fuel.2019.116967
dc.relation.urihttps://doi.org/10.1016/j.fuel.2019.116213
dc.relation.urihttps://doi.org/10.1080/10916466.2018.1560323
dc.relation.urihttps://doi.org/10.1080/10916466.2018.1511581
dc.relation.urihttps://doi.org/10.1016/j.fuel.2020.117029
dc.relation.urihttps://doi.org/10.1080/10916466.2020.1771365
dc.relation.urihttps://doi.org/10.1080/10916460802105682
dc.relation.urihttps://doi.org/10.23939/chcht06.02.229
dc.relation.urihttps://doi.org/10.23939/chcht14.01.129
dc.relation.urihttps://doi.org/10.23939/chcht14.03.403
dc.relation.urihttps://doi.org/10.1007/978-1-4684-2049-4
dc.relation.urihttps://doi.org/10.1016/S1381-1169(96)00251-8
dc.relation.urihttps://doi.org/10.1080/01961772.1986.10878150
dc.relation.urihttps://doi.org/10.1007/978-94-011-6017-9
dc.relation.urihttps://doi.org/10.1002/3527601635
dc.rights.holder© Національний університет “Львівська політехніка”, 2021
dc.rights.holder© Pyshyev S., Korchak B., Miroshnichenko D., Bevan Nyakuma B., 2021
dc.subjectсірка
dc.subjectдизельне паливо
dc.subjectоксидаційна десульфуризація
dc.subjectсульфоксид
dc.subjectсульфон
dc.subjectsulfur
dc.subjectdiesel fuel
dc.subjectoxidative desulfurization
dc.subjectsulfoxide
dc.subjectsulfone
dc.titleStudy on Chemistry of Oxidative Desulfurization Process of High Sulfur Straight-Run Oil Fraction
dc.title.alternativeВивчення хімізму процесу оксидаційної десульфуризації високосірчистої прямогонної нафтової фракції
dc.typeArticle

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Chemistry & Chemical Technology. – 2021. – Vol. 15, No. 3