Synthesis, Characterization and Application of a Diatomite-Based Composite for the Adsorption of Anionic Dyes in Aqueous Solutions

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dc.citation.epage388
dc.citation.issue3
dc.citation.spage377
dc.contributor.affiliationMustapha Stambouli University
dc.contributor.affiliationDjillali Liabes University
dc.contributor.affiliationScientific and Technical Research Center on Physical and Chemical Analyses (CRAPC), Industrial Zone Bou-Ismail
dc.contributor.authorChentouf, Sadek
dc.contributor.authorKacha, Smail
dc.contributor.authorMarouf, Réda
dc.contributor.authorBenhafsa, Fouad Mekhalef
dc.contributor.authorLeboukh, Abdelkader
dc.contributor.authorYahiaoui, Ahmed
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2024-01-09T11:31:49Z
dc.date.available2024-01-09T11:31:49Z
dc.date.created2021-03-16
dc.date.issued2021-03-16
dc.description.abstractКомпозит поліанілін-діатоміт (ПАД) синтезовано in-situ полімеризацією аніліну та визначено його характеристику і показано застосування при адсорбції барвників реактивного червоного 120 (RR 120) та кислотно-синього (AB). Для одержання композиту очищений діатоміт змішували з розчином, що містить анілін, розчинений у 2М хлорній кислоті за кімнатної температури. Характеристику отриманого твердого продукту проведено за допомогою скануючої електронної мікроскопії, рентгенівського аналізу та Фур‘є-спектроскопії. За допомогою кінетичної моделі псевдодругого порядку описано кінетичну адсорбцію барвників. Показано, що ізотерма адсорбції барвника RR 120 відповідає адсорбціній моделі Фрейндліха, а ізотерма барвника AB може краще відповідає моделі БЕТ.
dc.description.abstractSynthesis, characterization and application of the polyaniline-diatomite (PAD) composite in the adsorption of Reactive Red 120 (RR 120) and Acid Blue (AB) dyes were carried out. The composite was prepared by the in situ polymerization of aniline. Mass of purified diatomite was mixed with a solution containing aniline dissolved in 2M hydrochloric acid at room temperature. The solid obtained was characterized using the SEM, XRD and FTIR analyses. The kinetic adsorption of dyes was described using the pseudo-second order kinetic model. The adsorption isotherm of the RR 120 dye can be fitted by the Freundlich adsorption isotherm model. However, the adsorption isotherm of the AB dye can be better fitted by the BET model.
dc.format.extent377-388
dc.format.pages12
dc.identifier.citationSynthesis, Characterization and Application of a Diatomite-Based Composite for the Adsorption of Anionic Dyes in Aqueous Solutions / Sadek Chentouf, Smail Kacha, Réda Marouf, Fouad Mekhalef Benhafsa, Abdelkader Leboukh, Ahmed Yahiaoui // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2021. — Vol 15. — No 3. — P. 377–388.
dc.identifier.citationenSynthesis, Characterization and Application of a Diatomite-Based Composite for the Adsorption of Anionic Dyes in Aqueous Solutions / Sadek Chentouf, Smail Kacha, Réda Marouf, Fouad Mekhalef Benhafsa, Abdelkader Leboukh, Ahmed Yahiaoui // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2021. — Vol 15. — No 3. — P. 377–388.
dc.identifier.doidoi.org/10.23939/chcht15.03.377
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/60754
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 3 (15), 2021
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dc.relation.referencesen[4] Gupta V., Suhas K., J. Environ. Manag., 2009, 90, 2313. https://doi.org/10.1016/j.jenvman.2008.11.017
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dc.relation.referencesen[6] Dabrowski A., Adv. Colloid Int. Sci., 2001, 93, 135. https://doi.org/10.1016/S0001-8686(00)00082-8
dc.relation.referencesen[7] Aivalioti M., Vamvasakis I., Gidarakos E., J. Hazard. Mater., 2010, 178, 136. https://doi.org/10.1016/j.jhazmat.2010.01.053
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dc.relation.referencesen[16] Jian Z., Qingwei P., Meihong N. et al., Appl. Clay Sci., 2013, 83-84, 12. https://doi.org/10.1016/j.clay.2013.08.008
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dc.relation.urihttps://doi.org/10.1016/j.watres.2003.12.028
dc.relation.urihttps://doi.org/10.1016/j.biortech.2005.05.001
dc.relation.urihttps://doi.org/10.1016/j.jenvman.2008.11.017
dc.relation.urihttps://doi.org/10.1016/j.jhazmat.2005.07.016
dc.relation.urihttps://doi.org/10.1016/S0001-8686(00)00082-8
dc.relation.urihttps://doi.org/10.1016/j.jhazmat.2010.01.053
dc.relation.urihttps://doi.org/10.1016/S0955-2219(03)00038-4
dc.relation.urihttps://doi.org/10.3923/ajmskr.2010.121.136
dc.relation.urihttps://doi.org10.15680/IJIRSET.2015.0403021
dc.relation.urihttps://doi.org/10.5004/dwt.2009.934
dc.relation.urihttps://www.jstor.org/stable/25045657
dc.relation.urihttps://doi.org/10.1016/j.watres.2004.12.008
dc.relation.urihttps://doi.org/10.1016/j.clay.2013.08.008
dc.relation.urihttps://doi.org/10.1016/S0169-4332(03)00010-2
dc.relation.urihttps://doi.org/10.1016/j.matchemphys.2006.11.014
dc.relation.urihttps://doi.org/10.1016/j.jhazmat.2011.01.008
dc.relation.urihttps://doi.org/10.1016/j.apsusc.2005.02.119
dc.relation.urihttps://doi.org/10.7202/1006107ar
dc.relation.urihttps://doi.org/10.1016/S0956-053X(00)00076-3
dc.relation.urihttps://doi.org/10.1016/j.jhazmat.2008.10.018
dc.relation.urihttps://doi.org/10.1016/S0032-9592(98)00112-5
dc.relation.urihttps://doi.org/10.1016/j.cej.2010.05.054
dc.relation.urihttps://doi.org/10.1016/j.jhazmat.2009.02.097
dc.relation.urihttps://doi.org/10.1016/j.jhazmat.2004.11.026
dc.rights.holder© Національний університет “Львівська політехніка”, 2021
dc.rights.holder© Chentouf S., Kacha S., Marouf R., Benhafsa F., Leboukh A., Yahiaoui A., 2021
dc.subjectадсорбція
dc.subjectаніонні барвники
dc.subjectхарактеристика
dc.subjectдіатоміт
dc.subjectполіанілін
dc.subjectсинтез
dc.subjectadsorption
dc.subjectanionic dyes
dc.subjectcharacterization
dc.subjectdiatomite
dc.subjectpolyaniline
dc.subjectsynthesis
dc.titleSynthesis, Characterization and Application of a Diatomite-Based Composite for the Adsorption of Anionic Dyes in Aqueous Solutions
dc.title.alternativeСинтез, характеристика і застосування композита на основі діатоміту для адсорбції аніонних барвників у водних розчинах
dc.typeArticle

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Chemistry & Chemical Technology. – 2021. – Vol. 15, No. 3