Green Synthesis of Functionalized Poly(3-Glycidoxypropyl-Trimethoxysilane) Using an Eco-Catalyst (Treated Montmorillonite)

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dc.citation.epage69
dc.citation.issue1
dc.citation.spage60
dc.contributor.affiliationUniversité Oran 1
dc.contributor.authorEmbarek, Nadia
dc.contributor.authorSahli, Nabahat
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2024-02-09T10:29:44Z
dc.date.available2024-02-09T10:29:44Z
dc.date.created2023-02-28
dc.date.issued2023-02-28
dc.description.abstractКатіонною полімеризацією з відкриттям кільця 3-гліцидоксипропілтриметоксисілану і використанням ангідридів (оцтового ангідриду (АА) та метакрилового ангідриду (МА)), за відсутності розчинників, синтезований телехельний полі(3-гліцидоксипропілтриметоксисилан) з кінцевими ацетатними та метакрилатними групами. Замість електрофільних каталізаторів, таких як кислоти Бронстеда та Льюїса, дуже шкідливих та корозійних, як каталізатор процесу використано екологічний твердий Magnite-H+ (Mag-H+), який є йонообмінною силікатною глиною з монтморилоніту. Структуру отриманих макромономерів підтверджено методами інфрачервоної спектроскопії Фур'є, ядерно-магнітного резонансу та УФ-спектроскопії. Наявність кінцевих груп біс-макромономерів метакрилату визначено за допомогою УФ-спектроскопії. Встановлено оптимальні умови реакції, досліджено вплив часу реакції та кількості ангідридів (АА та МА) на вихід макромономерів.
dc.description.abstractTelechelic poly(3-glycidoxypropyltrimetho¬xysilane) (PGPTMS) with acetate and methacrylate end groups was successfully synthesized by an efficient and solvent-free approach, with anhydrides (acetic anhydride (AA) and methacrylic anhydride (MA)), by cationic ring-opening polymerization of 3 glycidoxypropyltrimetho-xysilane (GPTMS), using an ecologic solid catalyst Maghnite-H+ (Mag-H+), instead of electrophilic catalysts, such as, Bronsted and Lewis acids which are very noxious and corrosive. Mag-H+ is a montmorillonite sheet silicate clay exchanged with protons. The structure of the obtained macromonomers was confirmed by Fourier transform infrared spectroscopy (FT-IR), nuclear magnetic resonance (NMR) and UV-visible spectroscopy. The presence of the methacrylate end groups of bis-macromonomers was determined by UV-visible spectroscopy. In order to find the optimal reaction conditions, effects of reaction time and the amount of anhydrides (AA and MA) on the yield of macromonomers were investigated.
dc.format.extent60-69
dc.format.pages10
dc.identifier.citationEmbarek N. Green Synthesis of Functionalized Poly(3-Glycidoxypropyl-Trimethoxysilane) Using an Eco-Catalyst (Treated Montmorillonite) / Nadia Embarek, Nabahat Sahli // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2023. — Vol 17. — No 1. — P. 60–69.
dc.identifier.citationenEmbarek N. Green Synthesis of Functionalized Poly(3-Glycidoxypropyl-Trimethoxysilane) Using an Eco-Catalyst (Treated Montmorillonite) / Nadia Embarek, Nabahat Sahli // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2023. — Vol 17. — No 1. — P. 60–69.
dc.identifier.doidoi.org/10.23939/chcht17.01.060
dc.identifier.issn1196-4196
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/61230
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 1 (17), 2023
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dc.rights.holder© Національний університет “Львівська політехніка”, 2023
dc.rights.holder© Embarek N., Sahli N., 2023
dc.subjectфункціональний полімер
dc.subject3-гліцидоксипропілтриметоксисилан
dc.subjectмонтморилоніт
dc.subjectекокаталізатор
dc.subjectкатіонна полімеризація
dc.subjectfunctionalized polymer
dc.subject3-glycidoxypropyltrimetoxysilane
dc.subjectmontmorillonite
dc.subjecteco-catalyst
dc.subjectcationic polymerization
dc.titleGreen Synthesis of Functionalized Poly(3-Glycidoxypropyl-Trimethoxysilane) Using an Eco-Catalyst (Treated Montmorillonite)
dc.title.alternativeЗелений синтез функціоналізованого полі(3-гліцидоксипропіл-триметоксисилану) з використанням екокаталізатора (оброблений монтморилоніт)
dc.typeArticle

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Chemistry & Chemical Technology. – 2023. – Vol. 17, No. 1