Synthesis of Copolymer from 1,3,5-Trioxane and e-Caprolactone Catalysed by Treated Bentonite as Eco-Catalyst

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dc.citation.epage87
dc.citation.issue1
dc.citation.spage81
dc.contributor.affiliationUniversity Oran 1
dc.contributor.authorHanane, Benmoussa Mahi
dc.contributor.authorFerrahi, Mohammed Issam
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2024-02-09T10:29:28Z
dc.date.available2024-02-09T10:29:28Z
dc.date.created2023-02-28
dc.date.issued2023-02-28
dc.description.abstractУ цій роботі наведено новий зелений метод кополімеризації 1,3,5-триоксану з ε капролактоном. У цій методиці використано Maghnite-H+ (Mag H+) як об’ємний зелений каталізатор. Різні методики були використані для підтвердження будови отриманого кополімеру. Також досліджено фактори, які впливають на реакцію кополімеризації. Одержані результати показали, що найкращий вихід кополімеру (46,3 %) отримано для полімеризації в блоці за температури 353 K протягом 8 годин.
dc.description.abstractThis study presents a novel green method for copolymerizing 1,3,5-trioxane (TOX) with ε caprolactone (CL). This technique uses Maghnite-H+ (Mag-H+) as a bulk green catalyst. Various techniques were used to confirm the structure of the resulting copolymer. The influencing factors on the copolymerization reaction were also studied. The results show that the best copolymer yield (46.3 %) was obtained via bulk copolymerization at a temperature of 353 K for a reaction time of 8 h.
dc.format.extent81-87
dc.format.pages7
dc.identifier.citationHanane B. M. Synthesis of Copolymer from 1,3,5-Trioxane and e-Caprolactone Catalysed by Treated Bentonite as Eco-Catalyst / Benmoussa Mahi Hanane, Mohammed Issam Ferrahi // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2023. — Vol 17. — No 1. — P. 81–87.
dc.identifier.citationenHanane B. M. Synthesis of Copolymer from 1,3,5-Trioxane and e-Caprolactone Catalysed by Treated Bentonite as Eco-Catalyst / Benmoussa Mahi Hanane, Mohammed Issam Ferrahi // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2023. — Vol 17. — No 1. — P. 81–87.
dc.identifier.doidoi.org/10.23939/chcht17.01.081
dc.identifier.issn1196-4196
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/61207
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 1 (17), 2023
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dc.relation.references[5] Belbachir, M.; Bensaoula, A. Composition and Method for Catalysis Using Bentonite. US 7094823 B2, 2006.
dc.relation.references[6] Belmokhtar, A.; Sahli, N.; Yahiaoui, A.; Belbachir, M. Polycondensation of Pyrrole and Benzaldehyde Catalyzed by Ma-ghnite–H+. Express Polym. Lett. 2007, 7, 443-449. https://doi.org/10.3144/expresspolymlett.2007.62
dc.relation.references[7] Mekki, H.; Belbachir, M. Preparation of Vinyl Chloride – Vinyl Ether Copolymers via Partial Etherification from PVC. Express Polym. Lett. 2007, 1, 495-498. https://doi.org/10.3144/expresspolymlett.2007.70
dc.relation.references[8] Yahiaoui, A.; Hachemaoui, A.; Belbachir, M. Synthesis of Hydrosoluble Polymers of Oxazoline Using Maghnite-H as Catalyst. J. Appl. Polym. Sci. 2007, 104, 1792-1800. https://doi.org/10.1002/app.25829
dc.relation.references[9] Harrane, A.; Meghabar, R.; Belbachir, M. A Protons Exchanged Montmorillonite Clay as an Efficient Catalyst for the Reaction of Isobutylene Polymerization. Int. J. Mol. Sci. 2002, 3, 790-800. https://doi.org/10.3390/i3070790
dc.relation.references[10] Bennabi, S.; Sahli, N.; Belbachir, M.; Brachais, C.-H.; Boni, G.; Couvercelle, J.-P. A New Approach for the Synthesis of Poly(ethylglyoxylate) Using Mag-H+, an Algerian Proton Exchanged Montmorillonite Clay, as an Eco-Catalyst. J. Macromol. Sci. A 2017, 54, 843-852. https://doi.org/10.1080/10601325.2017.1339558
dc.relation.references[11] Derdar, H.; Belbachir, M.; Harrane, A. A Green Synthesis of Polylimonene Using Mag-H+, an Exchanged Montmorillonite Clay, as Eco-Catalyst. Bull. Chem. React. Eng. Catal. 2019, 14, 69-78. https://doi.org/10.9767/bcrec.14.1.2692.69-78
dc.relation.references[12] Reguieg, F.; Sahli, N.; Belbachir, M. Nanocomposite Hydrogels Based on Water Soluble Polymer and Montmorillonite-Na+. Orient. J. Chem. 2015, 31, 1645-1657. http://dx.doi.org/10.13005/ojc/310343
dc.relation.references[13] Reguieg, F.; Sahli, N.; Belbachir, M.; Lutz, P.J. One-Step Synthesis of Bis‐Macromonomers of Poly(1,3-dioxolane) Catalyzed by Maghnite‐H+. J. Appl. Polym. Sci. 2006, 99, 3147-3152. https://doi.org/10.1002/app.22935
dc.relation.references[14] Belbachir, M.; Bensaoula, A. Composition and Method for Catalysis Using Bentonites. US 0069446 A1, 2003.
dc.relation.references[15] Derdar, H.; Belbachir, M.; Hennaoui F.; Akeb, M.; Harranem, A. Green Copolymerization of Limonene with β-Pinene Catalyzed by an Eco-Catalyst Maghnite-H+. Polym. Sci. Ser. B+ 2018, 60, 555-562. https://doi.org/10.1134/S1560090418050056
dc.relation.references[16] Górniak, K.; Szydłak, T.; Gaweł, A.; Klimek, A.; Tomczyk, A.; Motyka, J.; Bahranowski, K. Smectite-, Silica- and Zeolites-Bearing Raw Materials (Hliník nad Hronom bentonite, Slovakia) - A New Approach Using Integrated Petrographic and Mineralogical Studies. Appl. Clay Sci. 2017, 141, 180-191. https://doi.org/10.1016/j.clay.2017.02.032
dc.relation.references[17] Beloufa, K.; Sahli, N.; Belbachir, M. Synthesis of Copolymer from 1,3,5‐Trioxane and 1,3‐Dioxolane Catalyzed by Maghnite‐H+. J. Appl. Polym. Sci. 2010, 115, 2820-2827. https://doi.org/10.1002/app.30901
dc.relation.references[18] Lam, K.L.; Abu Bakar, A.; Ishak, Z.A.M.; Karger-Kocsis, J. Amorphous Copolyester/Polyoxymethylene Blends: Thermal, Mechanical and Morphological Properties. Kautschuk Gummi Kunststoffe 2004, 57, 570-578.
dc.relation.references[19] Mu, Y.; Jia, M.; Jiang, W.; Wan, X. A Novel Branched Poly-oxymethylene Synthesized by Cationic Copolymerization of 1,3,5-Trioxane with 3-(Alkoxymethyl)-3-ethyloxetane. Macromol. Chem. Phys. 2013, 214, 2752-2760. https://doi.org/10.1002/macp.201300473
dc.relation.references[20] Belbachir, M.; Bensaoula, A. Composition and Method for Catalysis Using Bentonites. US 6274527 B1, 2001.
dc.relation.referencesen[1] Schweitzer, C.E.; Macdonald, R.N.; Punderson, J.O. Thermally Stable High Molecular Weight Polyoxymethylenes. J. Appl. Polym. Sci. 1959, 1, 158-163. https://doi.org/10.1002/app.1959.070010205
dc.relation.referencesen[2] Matsuzaki, K.; Hata, T.; Sone, T.; Masamoto, J. New Polyacetal Process from Formaldehyde Polymerization in the Presence of a Chain Transfer Agent. Bull. Chem. Soc. Jpn. 1994, 67, 2560-2566. https://doi.org/10.1246/bcsj.67.2560
dc.relation.referencesen[3] Yamasaki, N.; Kanaori, K.; Masamoto, J. Analysis of Ethylene Oxide Sequences of the Acetal Copolymer from Trioxane and Ethylene Oxide. J. Polym. Sci. A Polym. Chem. 2001, 39, 3239-3245. http://dx.doi.org/10.1002/pola.1306
dc.relation.referencesen[4] Yamasaki, N.; Masamoto, J. Novel Reaction between Cyclic Formal and Ethylene Oxide. J. Polym. Sci. A Polym. Chem. 2004, 42, 520-533. https://doi.org/10.1002/pola.10861
dc.relation.referencesen[5] Belbachir, M.; Bensaoula, A. Composition and Method for Catalysis Using Bentonite. US 7094823 B2, 2006.
dc.relation.referencesen[6] Belmokhtar, A.; Sahli, N.; Yahiaoui, A.; Belbachir, M. Polycondensation of Pyrrole and Benzaldehyde Catalyzed by Ma-ghnite–H+. Express Polym. Lett. 2007, 7, 443-449. https://doi.org/10.3144/expresspolymlett.2007.62
dc.relation.referencesen[7] Mekki, H.; Belbachir, M. Preparation of Vinyl Chloride – Vinyl Ether Copolymers via Partial Etherification from PVC. Express Polym. Lett. 2007, 1, 495-498. https://doi.org/10.3144/expresspolymlett.2007.70
dc.relation.referencesen[8] Yahiaoui, A.; Hachemaoui, A.; Belbachir, M. Synthesis of Hydrosoluble Polymers of Oxazoline Using Maghnite-H as Catalyst. J. Appl. Polym. Sci. 2007, 104, 1792-1800. https://doi.org/10.1002/app.25829
dc.relation.referencesen[9] Harrane, A.; Meghabar, R.; Belbachir, M. A Protons Exchanged Montmorillonite Clay as an Efficient Catalyst for the Reaction of Isobutylene Polymerization. Int. J. Mol. Sci. 2002, 3, 790-800. https://doi.org/10.3390/i3070790
dc.relation.referencesen[10] Bennabi, S.; Sahli, N.; Belbachir, M.; Brachais, C.-H.; Boni, G.; Couvercelle, J.-P. A New Approach for the Synthesis of Poly(ethylglyoxylate) Using Mag-H+, an Algerian Proton Exchanged Montmorillonite Clay, as an Eco-Catalyst. J. Macromol. Sci. A 2017, 54, 843-852. https://doi.org/10.1080/10601325.2017.1339558
dc.relation.referencesen[11] Derdar, H.; Belbachir, M.; Harrane, A. A Green Synthesis of Polylimonene Using Mag-H+, an Exchanged Montmorillonite Clay, as Eco-Catalyst. Bull. Chem. React. Eng. Catal. 2019, 14, 69-78. https://doi.org/10.9767/bcrec.14.1.2692.69-78
dc.relation.referencesen[12] Reguieg, F.; Sahli, N.; Belbachir, M. Nanocomposite Hydrogels Based on Water Soluble Polymer and Montmorillonite-Na+. Orient. J. Chem. 2015, 31, 1645-1657. http://dx.doi.org/10.13005/ojc/310343
dc.relation.referencesen[13] Reguieg, F.; Sahli, N.; Belbachir, M.; Lutz, P.J. One-Step Synthesis of Bis‐Macromonomers of Poly(1,3-dioxolane) Catalyzed by Maghnite‐H+. J. Appl. Polym. Sci. 2006, 99, 3147-3152. https://doi.org/10.1002/app.22935
dc.relation.referencesen[14] Belbachir, M.; Bensaoula, A. Composition and Method for Catalysis Using Bentonites. US 0069446 A1, 2003.
dc.relation.referencesen[15] Derdar, H.; Belbachir, M.; Hennaoui F.; Akeb, M.; Harranem, A. Green Copolymerization of Limonene with b-Pinene Catalyzed by an Eco-Catalyst Maghnite-H+. Polym. Sci. Ser. B+ 2018, 60, 555-562. https://doi.org/10.1134/S1560090418050056
dc.relation.referencesen[16] Górniak, K.; Szydłak, T.; Gaweł, A.; Klimek, A.; Tomczyk, A.; Motyka, J.; Bahranowski, K. Smectite-, Silica- and Zeolites-Bearing Raw Materials (Hliník nad Hronom bentonite, Slovakia) - A New Approach Using Integrated Petrographic and Mineralogical Studies. Appl. Clay Sci. 2017, 141, 180-191. https://doi.org/10.1016/j.clay.2017.02.032
dc.relation.referencesen[17] Beloufa, K.; Sahli, N.; Belbachir, M. Synthesis of Copolymer from 1,3,5‐Trioxane and 1,3‐Dioxolane Catalyzed by Maghnite‐H+. J. Appl. Polym. Sci. 2010, 115, 2820-2827. https://doi.org/10.1002/app.30901
dc.relation.referencesen[18] Lam, K.L.; Abu Bakar, A.; Ishak, Z.A.M.; Karger-Kocsis, J. Amorphous Copolyester/Polyoxymethylene Blends: Thermal, Mechanical and Morphological Properties. Kautschuk Gummi Kunststoffe 2004, 57, 570-578.
dc.relation.referencesen[19] Mu, Y.; Jia, M.; Jiang, W.; Wan, X. A Novel Branched Poly-oxymethylene Synthesized by Cationic Copolymerization of 1,3,5-Trioxane with 3-(Alkoxymethyl)-3-ethyloxetane. Macromol. Chem. Phys. 2013, 214, 2752-2760. https://doi.org/10.1002/macp.201300473
dc.relation.referencesen[20] Belbachir, M.; Bensaoula, A. Composition and Method for Catalysis Using Bentonites. US 6274527 B1, 2001.
dc.relation.urihttps://doi.org/10.1002/app.1959.070010205
dc.relation.urihttps://doi.org/10.1246/bcsj.67.2560
dc.relation.urihttp://dx.doi.org/10.1002/pola.1306
dc.relation.urihttps://doi.org/10.1002/pola.10861
dc.relation.urihttps://doi.org/10.3144/expresspolymlett.2007.62
dc.relation.urihttps://doi.org/10.3144/expresspolymlett.2007.70
dc.relation.urihttps://doi.org/10.1002/app.25829
dc.relation.urihttps://doi.org/10.3390/i3070790
dc.relation.urihttps://doi.org/10.1080/10601325.2017.1339558
dc.relation.urihttps://doi.org/10.9767/bcrec.14.1.2692.69-78
dc.relation.urihttp://dx.doi.org/10.13005/ojc/310343
dc.relation.urihttps://doi.org/10.1002/app.22935
dc.relation.urihttps://doi.org/10.1134/S1560090418050056
dc.relation.urihttps://doi.org/10.1016/j.clay.2017.02.032
dc.relation.urihttps://doi.org/10.1002/app.30901
dc.relation.urihttps://doi.org/10.1002/macp.201300473
dc.rights.holder© Національний університет “Львівська політехніка”, 2023
dc.rights.holder© Hanane B. M., Ferrahi M. I., 2023
dc.subjectкополімеризація
dc.subject1
dc.subject3
dc.subject5-триоксан
dc.subjectMaghnite-H+
dc.subjectполіоксиметилен
dc.subjectε-капролактон
dc.subjectcopolymerization
dc.subject1
dc.subject3
dc.subject5-Trioxane
dc.subjectMaghniteH+
dc.subjectpolyoxymethylene
dc.subjectε-caprolactone
dc.titleSynthesis of Copolymer from 1,3,5-Trioxane and e-Caprolactone Catalysed by Treated Bentonite as Eco-Catalyst
dc.title.alternativeСинтез кополімеру з 1,3,5-триоксану й ε-капролактону, каталізований обробленим бентонітом як екокаталізатором
dc.typeArticle

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Chemistry & Chemical Technology. – 2023. – Vol. 17, No. 1