An Oligomer with Terminal Unsaturated Double Bonds Based on Epidian 5 and Ethylacrylic Acid

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dc.citation.epage80
dc.citation.issue1
dc.citation.spage70
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.authorAstakhova, Olena
dc.contributor.authorJr, Mykhailo Bratychak
dc.contributor.authorKohut, Ananiy
dc.contributor.authorChervinskyy, Taras
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2024-02-09T10:29:44Z
dc.date.available2024-02-09T10:29:44Z
dc.date.created2023-02-28
dc.date.issued2023-02-28
dc.description.abstractЗ використанням епоксидної смоли Epidian 5 та етилакрилової кислоти отримано олігомер з кінцевими ненасиченими подвійними зв’язками (ненасичений олігомер, НО). Вивчено вплив природи каталізатора, температури та тривалості процесу на перебіг реакції між смолою та кис-лотою. Запропоновано методику синтезу НО. НО охарактеризовано хімічним та ІЧ-спектроскопічним методами дослідження. НО вивчено в процесах структурування з олігоестеракрилатами ГТМ-3 й МГФ-9 та ненасиченим поліестром ПЕ-246. З метою одержання структурнозабарвлених плівок додатково використані ненасичені азобарвники. Як ініціювальну систему в процесі структурування таких сумішей використано суміш гідропероксиду кумолу та нафтенату кобальту, розчиненого в стирені. З використанням ІЧ-спектроскопії визначено хімізм процесу формування просторовозшитих структур олігоестерних сумішей в присутності НО.
dc.description.abstractAn oligomer with terminal unsaturated double bonds (unsaturated oligomer, UO) has been synthesized from epoxy resin Epidian 5 and ethylacrylic acid. The impact of the catalyst nature, temperature, and reaction duration on the progress of the reaction between the resin and the acid has been studied. A synthetic technique is proposed for producing the UO. The UO has been characterized by chemical and FTIR-spectroscopic analyses. The UO has been examined in the cross-linking processes with oligoesteracrylates TGM 3 and MGP 9 as well as unsaturated polyester PE 246. In order to prepare structurally colored films, unsaturated azo dyes have been additionally used. A mixture of cumene hydroperoxide and cobalt naphthenate dissolved in styrene has been utilized as an initiating system for the cross-linking of the formulations. By using FTIR-spectroscopy, the chemistry of the development of the cross-linked structures of the oligoester mixtures in the presence of the UO has been revealed.
dc.format.extent70-80
dc.format.pages11
dc.identifier.citationAn Oligomer with Terminal Unsaturated Double Bonds Based on Epidian 5 and Ethylacrylic Acid / Olena Astakhova, Mykhailo Bratychak Jr, Ananiy Kohut, Taras Chervinskyy // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2023. — Vol 17. — No 1. — P. 70–80.
dc.identifier.citationenAn Oligomer with Terminal Unsaturated Double Bonds Based on Epidian 5 and Ethylacrylic Acid / Olena Astakhova, Mykhailo Bratychak Jr, Ananiy Kohut, Taras Chervinskyy // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2023. — Vol 17. — No 1. — P. 70–80.
dc.identifier.doidoi.org/10.23939/chcht17.01.070
dc.identifier.issn1196-4196
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/61231
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 1 (17), 2023
dc.relation.references[1] Chudzik, J.; Bieliński, D.M.; Demchuk, Y.; Bratychak, M.; Astakhova, O. Influence of Modified Epoxy Dian Resin on Properties of Nitrile-Butadiene Rubber (NBR). Materials 2022, 15, 2766. https://doi.org/10.3390/ma15082766
dc.relation.references[2] Chudzik, J.; Bieliński, D.M.; Bratychak, M.; Demchuk, Y.; Astakhova, O.; Jędrzejczyk, M.; Celichowski, G. Influence of Modified Epoxy Resins on Peroxide Curing, Mechanical Properties and Adhesion of SBR, NBR and XNBR to Silver Wires—Part II: Application of Carboxy-Containing Peroxy Oligomer (CPO). Materials 2021, 14, 1285. https://doi.org/10.3390/ma14051285
dc.relation.references[3] Chudzik, J.; Bieliński, D. M.; Bratychak, M.; Demchuk, Y.; Astakhova, O.; Jędrzejczyk, M.; Celichowski, G. Influence of Modified Epoxy Resins on Peroxide Curing, Mechanical Proper-ties and Adhesion of SBR, NBR and XNBR to Silver Wires. Part I: Application of Monoperoxy Derivative of Epoxy Resin (PO). Materials 2021, 14, 1320. https://doi.org/10.3390/ma14051320
dc.relation.references[4] Piesowicz, E.; Irska, I.; Bryll, K.; Gawdzinska, K.; Bratychak, M. Poly(butyleneterephthalate) Carbon Nanotubes Nanocomposites. Part II. Structure and Properties. Polimery 2016, 61, 24-30. https://doi.org/10.14314/polimery.2016.024
dc.relation.references[5] Papathanassiou, A.; Sulikowski, B.; Bratychak, M.; Zubyk, H.; Mykhailiv, O.; Zambrzycka-Szelewa, E.; Plonska-Brzezinska, M. A Phenol-Formaldehyde Polymeric Network to Generate Organic Aerogels: Synthesis, Physicochemical Characteristics and Potential Applications. J. Mater. Chem. A 2018, 6, 845-852. https://doi.org/10.1039/C7TA08814K
dc.relation.references[6] Voronov, S.; Kohut, A.; Tarnavchyk, I.; Voronov, A. Advances in Reactive Polymeric Surfactants for Interface Modification. Curr. Opin. Colloid Interface Sci. 2014, 19, 95-121. https://doi.org/10.1016/j.cocis.2014.03.010
dc.relation.references[7] Varvarenko, S.;Voronov, A.; Samaryk, V.; Tarnavchyk, I.; Nosova, N.; Kohut, A.; Voronov, S. Covalent Grafting of Polyacrylamide-Based Hydrogels to a Polypropylene Surface Acti-vated with Functional Polyperoxide. React. Funct. Polym. 2010, 70, 647-655. https://doi.org/10.1016/j.reactfunctpolym.2010.05.014
dc.relation.references[8] Brozowski, Z.K.; Szymanska, E.; Bratychak, M.M. New Epoxy-Unsaturated Polyester Resin Copolymers. React. Funct. Polym. 1997, 33, 217-224. https://doi.org/10.1016/S1381-5148(97)00045-X
dc.relation.references[9] Bratychak, M.; Astakhova, O.; Shyshchak, O. Epoxy Compo-sites Filled with Natural Calcium Carbonate. 3. Epoxy Composites Obtained in the Presence of Monocarboxylic Derivative of Epidian-6 Epoxy Resin. Chem. Chem. Technol. 2020, 14, 504-513. https://doi.org/10.23939/chcht14.04.504
dc.relation.references[10] Bratychak, M.M.; Bratychak, Mykh.Mykh. Peroksydni pokhidni epoksydnykh smol; Publishing House of Lviv Polytechnic National University: Lviv, 2003.
dc.relation.references[11] Bratychak, M.; Brostow, W.; Castano, V.M.; Donchak, V.; Gargai, H. Crosslinking Agents of Unsaturated Polymers: Evalua-tion of the Agent Efficiency. Mater. Res. Innov. 2002, 6, 153-159. https://doi.org/10.1080/14328917.2002.11784726
dc.relation.references[12] Bashta, B.; Astakhova, O.; Shyshchak, O.; Bratychak, M. Epoxy Resins Chemical Modification by Dibasic Acids. Chem. Chem. Technol. 2014, 8, 309 – 316]. https://doi.org/10.23939/chcht08.03.309
dc.relation.references[13] Bratychak, M.; Bashta, B.; Bruzdziak, P.; Astakhova, O.; Shyshchak, O. Cross–linking of Epoxy-Oligoesteric Mixtures in the Presence of Carboxy-Containing Derivative of ED-24 Epoxy Resin. Chem. Chem. Technol. 2013, 7, 41-46. https://doi.org/10.23939/chcht07.01.041
dc.relation.references[14] Bratychak, M.M.; Ivashkiv, O.P.; Astakhova, O.T. Khimichna modyfikacia epoksydnoho olihomeru ED-20 1,4-butandiolom. Dopovidi NAN Ukrainy 2014, 8, 97-102. http://dspace.nbuv.gov.ua/handle/123456789/88149
dc.relation.references[15] Dukh, O.І.; Bratychak, M.M. Olihoefirni kompozytsii na osnovi dianovoi epoksydnoi smoly, modyfikovanoi nenasychenymy kyslotamy. Ukrainski khimichnyi zhurnal 1997, 63, 51-55.
dc.relation.references[16] Boutevin, B.; Pietrasanta, Y.; Parisi, J.P. Synthèse de composéas photoréticulables, 8. Réaction des téalomères du méthac-rylate d'époxy-2,3 propyle avec l'acide acrylique et cinnamique. Macromol. Chem. Phys. 1987, 188, 1621-1629. https://doi.org/10.1002/macp.1987.021880708
dc.relation.references[17] Iatsyshyn, O.; Astakhova, O.; Shyshchak, O.; Lazorko, O.; Bratychak, M. Monomethacrylate Derivative of ED-24 Epoxy Resin and its Application. Chem. Chem. Technol. 2013, 7, 73-77. https://doi.org/10.23939/chcht07.01.073
dc.relation.references[18] Bratychak, M.M.; Iatsyshyn, O.I.; Mitina, N.Ye.; Zaichenko, O.S. Kopolimeryzatsia monometakrylatnoi pokhidnoi dyhlitsydy-lovoho eteru dioksydiphenilpropanu iz styrolom. Ukrainski khimichnyi zhurnal 2015, 81, 122-128.
dc.relation.references[19] Bratychak, M.M.; Dukh, O.I.; Brzozowski, Z.K. Synthesis of Oligomers with Unsaturated End-Groups Based on Dianic Epoxy Resin and Crotonic Acid. J. Macromol. Sci. - Pure Appl. 1997, 34, 389-396. https://doi.org/10.1080/10601329708014965
dc.relation.references[20] Chikanishi, K.; Isuruta, T. Reactivity of α-Alkylacrylic Esters. I. Homopolymerization Behaviours of Methyl α-Alkylacrylates. Macromol. Chem. Phys. 1965, 81, 198-210. https://doi.org/10.1002/macp.1965.020810122
dc.relation.references[21] Pikh, Z. Selektyvne okyslennia nenasychenukh spoluk zv`iazannym kysnem. D.Sc. Thesis, Lviv Polytechnic National University, Lviv, 1994.
dc.relation.references[22] Nomenclature of Organic Chemistry : IUPAC Recommendations and Preferred Names 2013; Royal Society of Chemistry: Cambridge, England, 2014.
dc.relation.references[23] Lipatov, Yu.; Nesterov, T. Spravochnik po Khimii Polimerov; Naukova dumka: Kiev, 1971.
dc.relation.references[24] Lange's Handbook of Chemistry; Dean, J.A., Ed.; McGraw-Hill: New York, 1999.
dc.relation.references[25] Metody vyznachennia iodnoho chysla. http://online.budstandart.com/ua/catalog/doc-page?id_doc=92574
dc.relation.references[26] Bratychak, M.; Shyshchak, O.; Astakhova, O.; Ivashkiv, O. Oligomers with Functional Groups Based on Epoxy Resins. Synthesis, Properties and Application; Publishing House of Lviv Polytechnic National University: Lviv, 2019.
dc.relation.referencesen[1] Chudzik, J.; Bieliński, D.M.; Demchuk, Y.; Bratychak, M.; Astakhova, O. Influence of Modified Epoxy Dian Resin on Properties of Nitrile-Butadiene Rubber (NBR). Materials 2022, 15, 2766. https://doi.org/10.3390/ma15082766
dc.relation.referencesen[2] Chudzik, J.; Bieliński, D.M.; Bratychak, M.; Demchuk, Y.; Astakhova, O.; Jędrzejczyk, M.; Celichowski, G. Influence of Modified Epoxy Resins on Peroxide Curing, Mechanical Properties and Adhesion of SBR, NBR and XNBR to Silver Wires-Part II: Application of Carboxy-Containing Peroxy Oligomer (CPO). Materials 2021, 14, 1285. https://doi.org/10.3390/ma14051285
dc.relation.referencesen[3] Chudzik, J.; Bieliński, D. M.; Bratychak, M.; Demchuk, Y.; Astakhova, O.; Jędrzejczyk, M.; Celichowski, G. Influence of Modified Epoxy Resins on Peroxide Curing, Mechanical Proper-ties and Adhesion of SBR, NBR and XNBR to Silver Wires. Part I: Application of Monoperoxy Derivative of Epoxy Resin (PO). Materials 2021, 14, 1320. https://doi.org/10.3390/ma14051320
dc.relation.referencesen[4] Piesowicz, E.; Irska, I.; Bryll, K.; Gawdzinska, K.; Bratychak, M. Poly(butyleneterephthalate) Carbon Nanotubes Nanocomposites. Part II. Structure and Properties. Polimery 2016, 61, 24-30. https://doi.org/10.14314/polimery.2016.024
dc.relation.referencesen[5] Papathanassiou, A.; Sulikowski, B.; Bratychak, M.; Zubyk, H.; Mykhailiv, O.; Zambrzycka-Szelewa, E.; Plonska-Brzezinska, M. A Phenol-Formaldehyde Polymeric Network to Generate Organic Aerogels: Synthesis, Physicochemical Characteristics and Potential Applications. J. Mater. Chem. A 2018, 6, 845-852. https://doi.org/10.1039/P.7TA08814K
dc.relation.referencesen[6] Voronov, S.; Kohut, A.; Tarnavchyk, I.; Voronov, A. Advances in Reactive Polymeric Surfactants for Interface Modification. Curr. Opin. Colloid Interface Sci. 2014, 19, 95-121. https://doi.org/10.1016/j.cocis.2014.03.010
dc.relation.referencesen[7] Varvarenko, S.;Voronov, A.; Samaryk, V.; Tarnavchyk, I.; Nosova, N.; Kohut, A.; Voronov, S. Covalent Grafting of Polyacrylamide-Based Hydrogels to a Polypropylene Surface Acti-vated with Functional Polyperoxide. React. Funct. Polym. 2010, 70, 647-655. https://doi.org/10.1016/j.reactfunctpolym.2010.05.014
dc.relation.referencesen[8] Brozowski, Z.K.; Szymanska, E.; Bratychak, M.M. New Epoxy-Unsaturated Polyester Resin Copolymers. React. Funct. Polym. 1997, 33, 217-224. https://doi.org/10.1016/S1381-5148(97)00045-X
dc.relation.referencesen[9] Bratychak, M.; Astakhova, O.; Shyshchak, O. Epoxy Compo-sites Filled with Natural Calcium Carbonate. 3. Epoxy Composites Obtained in the Presence of Monocarboxylic Derivative of Epidian-6 Epoxy Resin. Chem. Chem. Technol. 2020, 14, 504-513. https://doi.org/10.23939/chcht14.04.504
dc.relation.referencesen[10] Bratychak, M.M.; Bratychak, Mykh.Mykh. Peroksydni pokhidni epoksydnykh smol; Publishing House of Lviv Polytechnic National University: Lviv, 2003.
dc.relation.referencesen[11] Bratychak, M.; Brostow, W.; Castano, V.M.; Donchak, V.; Gargai, H. Crosslinking Agents of Unsaturated Polymers: Evalua-tion of the Agent Efficiency. Mater. Res. Innov. 2002, 6, 153-159. https://doi.org/10.1080/14328917.2002.11784726
dc.relation.referencesen[12] Bashta, B.; Astakhova, O.; Shyshchak, O.; Bratychak, M. Epoxy Resins Chemical Modification by Dibasic Acids. Chem. Chem. Technol. 2014, 8, 309 – 316]. https://doi.org/10.23939/chcht08.03.309
dc.relation.referencesen[13] Bratychak, M.; Bashta, B.; Bruzdziak, P.; Astakhova, O.; Shyshchak, O. Cross–linking of Epoxy-Oligoesteric Mixtures in the Presence of Carboxy-Containing Derivative of ED-24 Epoxy Resin. Chem. Chem. Technol. 2013, 7, 41-46. https://doi.org/10.23939/chcht07.01.041
dc.relation.referencesen[14] Bratychak, M.M.; Ivashkiv, O.P.; Astakhova, O.T. Khimichna modyfikacia epoksydnoho olihomeru ED-20 1,4-butandiolom. Dopovidi NAN Ukrainy 2014, 8, 97-102. http://dspace.nbuv.gov.ua/handle/123456789/88149
dc.relation.referencesen[15] Dukh, O.I.; Bratychak, M.M. Olihoefirni kompozytsii na osnovi dianovoi epoksydnoi smoly, modyfikovanoi nenasychenymy kyslotamy. Ukrainski khimichnyi zhurnal 1997, 63, 51-55.
dc.relation.referencesen[16] Boutevin, B.; Pietrasanta, Y.; Parisi, J.P. Synthèse de composéas photoréticulables, 8. Réaction des téalomères du méthac-rylate d'époxy-2,3 propyle avec l'acide acrylique et cinnamique. Macromol. Chem. Phys. 1987, 188, 1621-1629. https://doi.org/10.1002/macp.1987.021880708
dc.relation.referencesen[17] Iatsyshyn, O.; Astakhova, O.; Shyshchak, O.; Lazorko, O.; Bratychak, M. Monomethacrylate Derivative of ED-24 Epoxy Resin and its Application. Chem. Chem. Technol. 2013, 7, 73-77. https://doi.org/10.23939/chcht07.01.073
dc.relation.referencesen[18] Bratychak, M.M.; Iatsyshyn, O.I.; Mitina, N.Ye.; Zaichenko, O.S. Kopolimeryzatsia monometakrylatnoi pokhidnoi dyhlitsydy-lovoho eteru dioksydiphenilpropanu iz styrolom. Ukrainski khimichnyi zhurnal 2015, 81, 122-128.
dc.relation.referencesen[19] Bratychak, M.M.; Dukh, O.I.; Brzozowski, Z.K. Synthesis of Oligomers with Unsaturated End-Groups Based on Dianic Epoxy Resin and Crotonic Acid. J. Macromol. Sci, Pure Appl. 1997, 34, 389-396. https://doi.org/10.1080/10601329708014965
dc.relation.referencesen[20] Chikanishi, K.; Isuruta, T. Reactivity of α-Alkylacrylic Esters. I. Homopolymerization Behaviours of Methyl α-Alkylacrylates. Macromol. Chem. Phys. 1965, 81, 198-210. https://doi.org/10.1002/macp.1965.020810122
dc.relation.referencesen[21] Pikh, Z. Selektyvne okyslennia nenasychenukh spoluk zv`iazannym kysnem. D.Sc. Thesis, Lviv Polytechnic National University, Lviv, 1994.
dc.relation.referencesen[22] Nomenclature of Organic Chemistry : IUPAC Recommendations and Preferred Names 2013; Royal Society of Chemistry: Cambridge, England, 2014.
dc.relation.referencesen[23] Lipatov, Yu.; Nesterov, T. Spravochnik po Khimii Polimerov; Naukova dumka: Kiev, 1971.
dc.relation.referencesen[24] Lange's Handbook of Chemistry; Dean, J.A., Ed.; McGraw-Hill: New York, 1999.
dc.relation.referencesen[25] Metody vyznachennia iodnoho chysla. http://online.budstandart.com/ua/catalog/doc-page?id_doc=92574
dc.relation.referencesen[26] Bratychak, M.; Shyshchak, O.; Astakhova, O.; Ivashkiv, O. Oligomers with Functional Groups Based on Epoxy Resins. Synthesis, Properties and Application; Publishing House of Lviv Polytechnic National University: Lviv, 2019.
dc.relation.urihttps://doi.org/10.3390/ma15082766
dc.relation.urihttps://doi.org/10.3390/ma14051285
dc.relation.urihttps://doi.org/10.3390/ma14051320
dc.relation.urihttps://doi.org/10.14314/polimery.2016.024
dc.relation.urihttps://doi.org/10.1039/C7TA08814K
dc.relation.urihttps://doi.org/10.1016/j.cocis.2014.03.010
dc.relation.urihttps://doi.org/10.1016/j.reactfunctpolym.2010.05.014
dc.relation.urihttps://doi.org/10.1016/S1381-5148(97)00045-X
dc.relation.urihttps://doi.org/10.23939/chcht14.04.504
dc.relation.urihttps://doi.org/10.1080/14328917.2002.11784726
dc.relation.urihttps://doi.org/10.23939/chcht08.03.309
dc.relation.urihttps://doi.org/10.23939/chcht07.01.041
dc.relation.urihttp://dspace.nbuv.gov.ua/handle/123456789/88149
dc.relation.urihttps://doi.org/10.1002/macp.1987.021880708
dc.relation.urihttps://doi.org/10.23939/chcht07.01.073
dc.relation.urihttps://doi.org/10.1080/10601329708014965
dc.relation.urihttps://doi.org/10.1002/macp.1965.020810122
dc.relation.urihttp://online.budstandart.com/ua/catalog/doc-page?id_doc=92574
dc.rights.holder© Національний університет “Львівська політехніка”, 2023
dc.rights.holder© Astakhova O., Bratychak Jr M., Kohut A., Chervinskyy T., 2023
dc.subjectEpidian 5
dc.subjectетилакрилова кислота
dc.subjectкаталізатори
dc.subjectненасичений олігомер
dc.subjectолігоестеракрилати
dc.subjectолігомерні суміші
dc.subjectІЧ-спектроскопія
dc.subjectEpidian 5
dc.subjectethylacrylic acid
dc.subjectcatalysts
dc.subjectunsaturated oligomer
dc.subjectoligoesteracrylates
dc.subjectoligomeric mixtures
dc.subjectFTIR-spectroscopy
dc.titleAn Oligomer with Terminal Unsaturated Double Bonds Based on Epidian 5 and Ethylacrylic Acid
dc.title.alternativeОлігомер з кінцевими ненасиченими подвійними зв’язками на основі epidian 5 та етилакрилової кислоти
dc.typeArticle

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Chemistry & Chemical Technology. – 2023. – Vol. 17, No. 1