Influence of electrode material on the electrochemical behavior of the absorbing solution of the quinhydrone method of gases purification from hydrogen sulfide

dc.citation.epage59
dc.citation.issue1
dc.citation.spage53
dc.contributor.affiliationНаціональний університет “Львівська політехніка”
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.authorСлюзар, А. В.
dc.contributor.authorМерцало, Іванна Павлівна
dc.contributor.authorКозуб, М. І.
dc.contributor.authorМилютина, П. В.
dc.contributor.authorЯкименко, Я. О.
dc.contributor.authorSlyuzar, A. V.
dc.contributor.authorMertsalo, I. P.
dc.contributor.authorKozub, M. I.
dc.contributor.authorMyliutyna, P. V.
dc.contributor.authorYakymenko, Ya. O.
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2024-01-22T08:14:56Z
dc.date.available2024-01-22T08:14:56Z
dc.date.created2021-03-16
dc.date.issued2021-03-16
dc.description.abstractМетодом циклічної вольтамперометрії (ЦВА) досліджено електрохімічну поведінку карбонатних розчинів хінгідрону 1, 5, 10, 20 та 30 г/дм 3 під час його вистоювання 0–12 діб на різних електродних матеріалах – Ni та Au. Виявлено відмінні від нікелю каталітичні властивості золота в реакціях анодного окиснення хінгідронного каталізатора.
dc.description.abstractThe electrochemical behavior of carbonate solutions of the quinhydrone at different concentrations 1, 5, 10, 20, and 30 g/dm3 at the exposure time 0…12 days on different electrode materials – Ni and Au were studied by the cyclic voltammetry (CV) method. The catalytic properties of gold different from nickel in the anodic oxidation reactions of the quinhydrone catalyst are noted.
dc.format.extent53-59
dc.format.pages7
dc.identifier.citationInfluence of electrode material on the electrochemical behavior of the absorbing solution of the quinhydrone method of gases purification from hydrogen sulfide / A. V. Slyuzar, I. P. Mertsalo, M. I. Kozub, P. V. Myliutyna, Ya. O. Yakymenko // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2021. — Vol 4. — No 1. — P. 53–59.
dc.identifier.citationenInfluence of electrode material on the electrochemical behavior of the absorbing solution of the quinhydrone method of gases purification from hydrogen sulfide / A. V. Slyuzar, I. P. Mertsalo, M. I. Kozub, P. V. Myliutyna, Ya. O. Yakymenko // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2021. — Vol 4. — No 1. — P. 53–59.
dc.identifier.doidoi.org/ 10.23939/ctas2021.01.053
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/60872
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry, Technology and Application of Substances, 1 (4), 2021
dc.relation.references1. Mokhatab, S., Poe, W. A., Mak, J. Y. (2019). Sulfur Recovery and Handling. Handbook of Natural Gas Transmission and Processing, 271–305. https://doi.org/10.1016/b978-0-12-815817-3.00008-3
dc.relation.references2. Slyuzar, A. V., Znak, Z. O., Kalymon, Ya. A., Bukliv, R. L. (2019). Metody ochyshhennja i pereroblennja sirkovoden'vmisnyh gaziv (ogljad) [Methods of purification and processing of hydrogen sulfide-containing gases (review)].. Voprosy Khimi i Khimicheskoi Tekhnologii – Issues of Chemistry and Chemical Technology, 3, 83–97. DOI: 10.32434/ 0321-4095-2019-124-3-83-97 (in Ukrainian).
dc.relation.references3. Slyuzar, A., Znak, Z., Kalymon, Y., Helesh, A. (2020). Study of Oxygen Chemisorption During Regeneration of Quinhydrone Absorbing Solution in the Apparatus with a Continuous Bubbling Layer. Chemistry and Chemical Technology, 14 (2), 257–263. https://doi.org/10.23939/chcht14.02.257
dc.relation.references4. Yavorskyi, V. T., Slyuzar, A. V., Kalymon, Ya. A., Mertsalo, I. P., Tryhuba, O. O. (2006). Elektroliz vidpratsovanoho pohlynalnoho rozchynu khinhidronnoho metodu ochyshchennia haziv vid sirkovodniu. [Electrolysis of the spent absorbing solution of the quinhydrone method of gases purification from hydrogen sulfide]. Voprosy Khimii i Khimicheskoi Tekhnologii –Issues of Chemistry and Chemical Technology, 6, 99–101 (in Ukrainian).
dc.relation.references5. Kalymon, Ya. A., Yavorskyi, V. T., Chaiko, N. I., Znak, Z. O. (2001). Pohlynalni rozchyny na osnovi khinhidronu dlia ochyshchennia haziv vid sirkovodniu. [Absorbing solutions based on quinhydrone for gases purification from hydrogen sulfide]. Visnyk NTU –Bulletin of NTU “Kharkiv Polytechnic Institute”, 18, 145–150. (in Ukrainian).
dc.relation.references6. Znak, Z. O., Yavorskyi, V. T., Lievashova, V. L. (1990). Protsess polimerizacii quinhydronea v shchelochnoj srede. [The process of quinhydrone polymerization in an alkaline environment]. Kinetics and catalysis, 31(1), 197–202. (in Russian).
dc.relation.references7. Slyuzar, A. V., Khomyak, S. V., Kalymon, Ya. A. (2019). The influence of exposure time on changing of the properties of the soda solution of quinhydrone during the quinhydrone catalyst preparation. Chemistry, Technology and Application of Substances, 2(2), 68–72. https://doi.org/10.23939/ctas2019.02.068.
dc.relation.references8. Yavorskiy, V. T., Kalymon, Ya. A., Znak, Z. O., Chajko, N. Y. (2000). Tehnologija prygotuvannja poglynalnogo rozchynu na osnovi quinhydroneu dlja ochyshhennja gaziv vid sirkovodnju [The technology of preparation of absorbent solution based on quinhydrone for gases purification from hydrogen sulfide]. Ekotehnology and resource-saving, 5, 56–59. (in Ukrainian).
dc.relation.references9. Yavorskyi, V. T., Slyuzar, A. V., Kalymon, Ya. A., Mertsalo, I. P. (2005). Elektrokhimichni vlastyvosti khinhidronu v luzhnomu rozchyni. [Electrochemical properties of quinhydrone in alkaline solution]. [Electrochemical properties of quinhydrone in alkaline solution]. Visnyk NTU – Bulletin of NTU “Kharkiv Polytechnic Institute”, 16, 166–169. (in Ukrainian)
dc.relation.references10. Mazanko, A. F., Kamar'yan, A. F., Romashin, O. P. (1989). Promyshlennyj membrannyj elektroliz [Industrial membrane electrolysis]. Moskva: Himiya. (in Russian).
dc.relation.references11. Barsukov, V. Z. (Ed.), Borysenko, Yu. V., Buket, O. I., & Khomenko, V. G. (2016). Promising Materials and Processes in Technical Electrochemistry. monograph. Kyiv: KNUTD. https://www.researchgate.net/publication/331821560.
dc.relation.references12. Pokhmurskii, V. I., & Khoma, M. S. (2008). Koroziinavtomametaliv ta splaviv.[Corrosion fatigue of metals and alloys]. Lviv: SPOLOM. (in Ukrainian).
dc.relation.references13. Slyuzar, A. V., Kalymon, Ya. A. (2020). Vplyv komponentiv na okysno-vidnovni vlastyvosti khinhidronnoho pohlynalnoho rozchynu [Influence of components on the redox properties of quinhydrone absorption solution]. Voprosy Khimii i Khimicheskoi Tekhnologii – Issues of Chemistry and Chemical Technology, 5 (132), 88–97. http://dx.doi.org/10.32434/0321-405-2020-132-5-88-97
dc.relation.references14. Guin, P. S., Das, S., Mandal, P. C. (2011) Electrochemical Reduction of Quinones in Different Media: A Review. International Journal of Electrochemistry, 2011, 1–22. DOI:10.4061/2011/816202
dc.relation.references15. Gouws, S., Barton, B., Loyson, P. L. R., Zeelie, B. (2008). Electrochemical production of alkoxysubstituted phenols. Electrochimica Acta, 53(13), 4544–4549. DOI:10.1016/j.electacta. 2008.01.047
dc.relation.references16. Rafiee M., Nematollahi D. (2007). Voltammetry of Electroinactive Species Using Quinone/Hydroquinone Redox: A Known Redox System Viewed in a New Perspective. Electroanalysis, 19(13), 1382–1386. DOI: 10.1002/elan.200703864.
dc.relation.references17. Astudillo, L. R., Rivera, L., Brito-Gómez, R., Tremont, R. J. (2010). Еlectrochemical study of 1,4-benzoquinone on gold surface modified. Journal of Electroanalytical Chemistry, 640(1–2), 56–60. https://doi.org/10.1016/j.jelechem.2010.01.005
dc.relation.references18. Chaudhari, V. R., Bhat, M. A., Ingole, P. P., Haram, S. K. (2009). Self electro-catalysis of hydroquinone on gold electrode in aqueous un-buffered media. Electrochemistry Communications, 11(5), 994–996. DOI: 10.1016/j.elecom.2009.02.046.
dc.relation.references19. Fang, F. L., Win, W. X., Dong, G. M., Tian, G. Y. (2007). Cobalt hydroxide film deposited on glassy carbon electrode for electrocatalitic oxidation of hydroquinone. Electrochimica Acta, 52(11), 3654–3659. https://doi.org/10.1016/j.electacta.2006.10.027
dc.relation.references20. Danylov F. Y., Protsenko V. S. (2016). Liniina ta tsyklichnavoltamperometriia. Knyga 1. [Linear and cyclic voltammetry. Book. 1]. Dnipro: Lira. (in Ukrainian).
dc.relation.referencesen1. Mokhatab, S., Poe, W. A., Mak, J. Y. (2019). Sulfur Recovery and Handling. Handbook of Natural Gas Transmission and Processing, 271–305. https://doi.org/10.1016/b978-0-12-815817-3.00008-3
dc.relation.referencesen2. Slyuzar, A. V., Znak, Z. O., Kalymon, Ya. A., Bukliv, R. L. (2019). Metody ochyshhennja i pereroblennja sirkovoden'vmisnyh gaziv (ogljad) [Methods of purification and processing of hydrogen sulfide-containing gases (review)].. Voprosy Khimi i Khimicheskoi Tekhnologii – Issues of Chemistry and Chemical Technology, 3, 83–97. DOI: 10.32434/ 0321-4095-2019-124-3-83-97 (in Ukrainian).
dc.relation.referencesen3. Slyuzar, A., Znak, Z., Kalymon, Y., Helesh, A. (2020). Study of Oxygen Chemisorption During Regeneration of Quinhydrone Absorbing Solution in the Apparatus with a Continuous Bubbling Layer. Chemistry and Chemical Technology, 14 (2), 257–263. https://doi.org/10.23939/chcht14.02.257
dc.relation.referencesen4. Yavorskyi, V. T., Slyuzar, A. V., Kalymon, Ya. A., Mertsalo, I. P., Tryhuba, O. O. (2006). Elektroliz vidpratsovanoho pohlynalnoho rozchynu khinhidronnoho metodu ochyshchennia haziv vid sirkovodniu. [Electrolysis of the spent absorbing solution of the quinhydrone method of gases purification from hydrogen sulfide]. Voprosy Khimii i Khimicheskoi Tekhnologii –Issues of Chemistry and Chemical Technology, 6, 99–101 (in Ukrainian).
dc.relation.referencesen5. Kalymon, Ya. A., Yavorskyi, V. T., Chaiko, N. I., Znak, Z. O. (2001). Pohlynalni rozchyny na osnovi khinhidronu dlia ochyshchennia haziv vid sirkovodniu. [Absorbing solutions based on quinhydrone for gases purification from hydrogen sulfide]. Visnyk NTU –Bulletin of NTU "Kharkiv Polytechnic Institute", 18, 145–150. (in Ukrainian).
dc.relation.referencesen6. Znak, Z. O., Yavorskyi, V. T., Lievashova, V. L. (1990). Protsess polimerizacii quinhydronea v shchelochnoj srede. [The process of quinhydrone polymerization in an alkaline environment]. Kinetics and catalysis, 31(1), 197–202. (in Russian).
dc.relation.referencesen7. Slyuzar, A. V., Khomyak, S. V., Kalymon, Ya. A. (2019). The influence of exposure time on changing of the properties of the soda solution of quinhydrone during the quinhydrone catalyst preparation. Chemistry, Technology and Application of Substances, 2(2), 68–72. https://doi.org/10.23939/ctas2019.02.068.
dc.relation.referencesen8. Yavorskiy, V. T., Kalymon, Ya. A., Znak, Z. O., Chajko, N. Y. (2000). Tehnologija prygotuvannja poglynalnogo rozchynu na osnovi quinhydroneu dlja ochyshhennja gaziv vid sirkovodnju [The technology of preparation of absorbent solution based on quinhydrone for gases purification from hydrogen sulfide]. Ekotehnology and resource-saving, 5, 56–59. (in Ukrainian).
dc.relation.referencesen9. Yavorskyi, V. T., Slyuzar, A. V., Kalymon, Ya. A., Mertsalo, I. P. (2005). Elektrokhimichni vlastyvosti khinhidronu v luzhnomu rozchyni. [Electrochemical properties of quinhydrone in alkaline solution]. [Electrochemical properties of quinhydrone in alkaline solution]. Visnyk NTU – Bulletin of NTU "Kharkiv Polytechnic Institute", 16, 166–169. (in Ukrainian)
dc.relation.referencesen10. Mazanko, A. F., Kamar'yan, A. F., Romashin, O. P. (1989). Promyshlennyj membrannyj elektroliz [Industrial membrane electrolysis]. Moskva: Himiya. (in Russian).
dc.relation.referencesen11. Barsukov, V. Z. (Ed.), Borysenko, Yu. V., Buket, O. I., & Khomenko, V. G. (2016). Promising Materials and Processes in Technical Electrochemistry. monograph. Kyiv: KNUTD. https://www.researchgate.net/publication/331821560.
dc.relation.referencesen12. Pokhmurskii, V. I., & Khoma, M. S. (2008). Koroziinavtomametaliv ta splaviv.[Corrosion fatigue of metals and alloys]. Lviv: SPOLOM. (in Ukrainian).
dc.relation.referencesen13. Slyuzar, A. V., Kalymon, Ya. A. (2020). Vplyv komponentiv na okysno-vidnovni vlastyvosti khinhidronnoho pohlynalnoho rozchynu [Influence of components on the redox properties of quinhydrone absorption solution]. Voprosy Khimii i Khimicheskoi Tekhnologii – Issues of Chemistry and Chemical Technology, 5 (132), 88–97. http://dx.doi.org/10.32434/0321-405-2020-132-5-88-97
dc.relation.referencesen14. Guin, P. S., Das, S., Mandal, P. C. (2011) Electrochemical Reduction of Quinones in Different Media: A Review. International Journal of Electrochemistry, 2011, 1–22. DOI:10.4061/2011/816202
dc.relation.referencesen15. Gouws, S., Barton, B., Loyson, P. L. R., Zeelie, B. (2008). Electrochemical production of alkoxysubstituted phenols. Electrochimica Acta, 53(13), 4544–4549. DOI:10.1016/j.electacta. 2008.01.047
dc.relation.referencesen16. Rafiee M., Nematollahi D. (2007). Voltammetry of Electroinactive Species Using Quinone/Hydroquinone Redox: A Known Redox System Viewed in a New Perspective. Electroanalysis, 19(13), 1382–1386. DOI: 10.1002/elan.200703864.
dc.relation.referencesen17. Astudillo, L. R., Rivera, L., Brito-Gómez, R., Tremont, R. J. (2010). Electrochemical study of 1,4-benzoquinone on gold surface modified. Journal of Electroanalytical Chemistry, 640(1–2), 56–60. https://doi.org/10.1016/j.jelechem.2010.01.005
dc.relation.referencesen18. Chaudhari, V. R., Bhat, M. A., Ingole, P. P., Haram, S. K. (2009). Self electro-catalysis of hydroquinone on gold electrode in aqueous un-buffered media. Electrochemistry Communications, 11(5), 994–996. DOI: 10.1016/j.elecom.2009.02.046.
dc.relation.referencesen19. Fang, F. L., Win, W. X., Dong, G. M., Tian, G. Y. (2007). Cobalt hydroxide film deposited on glassy carbon electrode for electrocatalitic oxidation of hydroquinone. Electrochimica Acta, 52(11), 3654–3659. https://doi.org/10.1016/j.electacta.2006.10.027
dc.relation.referencesen20. Danylov F. Y., Protsenko V. S. (2016). Liniina ta tsyklichnavoltamperometriia. Knyga 1. [Linear and cyclic voltammetry. Book. 1]. Dnipro: Lira. (in Ukrainian).
dc.relation.urihttps://doi.org/10.1016/b978-0-12-815817-3.00008-3
dc.relation.urihttps://doi.org/10.23939/chcht14.02.257
dc.relation.urihttps://doi.org/10.23939/ctas2019.02.068
dc.relation.urihttps://www.researchgate.net/publication/331821560
dc.relation.urihttp://dx.doi.org/10.32434/0321-405-2020-132-5-88-97
dc.relation.urihttps://doi.org/10.1016/j.jelechem.2010.01.005
dc.relation.urihttps://doi.org/10.1016/j.electacta.2006.10.027
dc.rights.holder© Національний університет “Львівська політехніка”, 2021
dc.subjectхінгідронний окисник
dc.subjectелектрохімічна поведінка
dc.subjectчас вистоювання
dc.subjectелектродний матеріал
dc.subjectциклічна вольтамперометрія
dc.subjectquinhydrone oxidant
dc.subjectelectrochemical behavior
dc.subjectexposure time
dc.subjectelectrode material
dc.subjectcyclic voltammetry
dc.titleInfluence of electrode material on the electrochemical behavior of the absorbing solution of the quinhydrone method of gases purification from hydrogen sulfide
dc.title.alternativeВплив електродного матеріалу на електрохімічну поведінку поглинального розчину хінгідронного методу очищення газів від сірководню
dc.typeArticle

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