Compositional Fibers Based on Coal Tar Mesophase Pitch Obtained by Electrospinning Method

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dc.citation.epage407
dc.citation.issue3
dc.citation.spage403
dc.contributor.affiliationKazakh National University named after al-Farabi
dc.contributor.affiliationInstitute of Combustion Problems
dc.contributor.affiliationUniversity of Texas at Dallas
dc.contributor.affiliationBekturov Institute of Chemical Sciences
dc.contributor.authorImangazy, Aldan
dc.contributor.authorSmagulova, Gaukhar
dc.contributor.authorKaidar, Bayan
dc.contributor.authorMansurov, Zulkhair
dc.contributor.authorKerimkulova, Almagul
dc.contributor.authorUmbetkaliev, Kuanysh
dc.contributor.authorZakhidov, Anvar
dc.contributor.authorVorobyev, Pavel
dc.contributor.authorJumadilov, Talkybek
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2024-01-09T11:31:42Z
dc.date.available2024-01-09T11:31:42Z
dc.date.created2021-03-16
dc.date.issued2021-03-16
dc.description.abstractДосліджено можливість використання відходів перероблення вугілля родовища Шубарколь (Казахстан) для отримання таких корисних матеріалів, як вуглецеві волокна. Термічним обробленням кам’яновугільної смоли за 773 К одержано мезофазний пек. Приготовлено спініговий розчин подрібненням мезофазного пеку з додаванням полі(метилметакрилату) як волокноутворюючого матеріалу та 1,2-дихлоретану як розчинника. За допомогою елементного аналізу підтверджено, що термооброблення за 773 К приводить до повного видалення сірковмісних компонентів, які впливають на утворення мезофази (хімічний склад мезофазного пеку С – 91,48 %; О – 8,52 %; S – 0,00 %). Присутність вуглецевих матеріалів і зв'язків C–H підтверджено даними раманівської спектроскопії (пікі D (1366 см-1) та G (1605 см-1), пік при 2900 см-1, відповідно). Методом електроспіннінгу в лабораторних умовах одержано вуглецеві волокна діаметром 0,8–1,75 мкм.
dc.description.abstractThis research examines the use of coal-processing wastes of Shubarkol deposit (Kazakhstan) in obtaining useful materials such as carbon fibers. For our experiments, mesophase pitch was obtained by coal tar heat treatment at 773 K. Spinnable solution was prepared by crushing mesophase pitch into the pieces with adding poly(methylmethacrylate) as a fiber-forming material and 1,2-dichloroethane as a solvent. Elemental analysis revealed that the chemical composition of mesophase pitch (С – 91.48 %; О – 8.52 %; S – 0.00 %) showed that heat treatment up to 773 K leads to the complete removal of sulfur-containing components which affect the mesophase formation. Raman data of the obtained pitch revealed the appearance of D (1366 cm-1) and G (1605 cm-1) peaks, which are responsible for carbon materials; another peak at 2900 cm-1 shows the presence of C–H bonds. Carbon fibers with the diameter of 0.8–1.75 μm were obtained by electrospinning method in laboratory settings.
dc.format.extent403-407
dc.format.pages5
dc.identifier.citationCompositional Fibers Based on Coal Tar Mesophase Pitch Obtained by Electrospinning Method / Aldan Imangazy, Gaukhar Smagulova, Bayan Kaidar, Zulkhair Mansurov, Almagul Kerimkulova, Kuanysh Umbetkaliev, Anvar Zakhidov, Pavel Vorobyev, Talkybek Jumadilov // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2021. — Vol 15. — No 3. — P. 403–407.
dc.identifier.citationenCompositional Fibers Based on Coal Tar Mesophase Pitch Obtained by Electrospinning Method / Aldan Imangazy, Gaukhar Smagulova, Bayan Kaidar, Zulkhair Mansurov, Almagul Kerimkulova, Kuanysh Umbetkaliev, Anvar Zakhidov, Pavel Vorobyev, Talkybek Jumadilov // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2021. — Vol 15. — No 3. — P. 403–407.
dc.identifier.doidoi.org/10.23939/chcht15.03.403
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/60737
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 3 (15), 2021
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dc.relation.referencesen[5] Derbyshire F., Andrews R., Jacques D. et al., Fuel, 2001, 80, 345. https:/doi.org/10.1016/S0016-2361(00)00099-5
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dc.relation.referencesen[7] Forintos N., Czigány T., Compos. Part B-Eng., 2019, 162, 331. https://doi.org/10.1016/j.compositesb.2018.10.098
dc.relation.referencesen[8] Aldosari S., Khan M., Rahatekar S., J. Mater. Res. Technol., 2020, 9, 7786. https://doi.org/10.1016/j.jmrt.2020.05.037
dc.relation.referencesen[9] Doshlov O., Kondrat’ev V., Ugap’ev A. et al., Coke Chem., 2015, 58, 32. https://doi.org/10.3103/S1068364X15010020
dc.relation.referencesen[10] Frank E., Steudle L., Ingildeev D. et al., Angew. Chem. Int. Ed., 2014, 53, 5262. https://doi.org/10.1002/anie.201306129
dc.relation.referencesen[11] Yang K., Kim B., Yoon S., Carbon Lett., 2014, 15, 162. https://doi.org/10.5714/CL.2014.15.3.162
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dc.relation.referencesen[13] Zhiyuan C., He J., Fengwen Z. et al., J. Serb. Chem. Soc., 2014, 79, 587. https://doi.org/10.2298/jsc130702150z
dc.relation.referencesen[14] Yoo M., Ko H., Lim Y., Kim M., Carbon Lett., 2014, 15, 247. https://doi.org/10.5714/CL.2014.15.4.247
dc.relation.referencesen[15] Yermagambet B., Kazankapova M., Nauryzbaeva A. et al., News of the Academy of Science of the Republik of Kazakhstan, 2019, 4, 436. https://doi.org/10.32014/2019.2518-170X.101
dc.relation.referencesen[16] Park S.-J., Carbon Fibers. Springer, Dordrecht 2015. https://doi.org/10.1007/978-94-017-9478-7
dc.relation.referencesen[17] Singer L., Lewis I., Carbon, 1978, 16, 417. https://doi.org/10.1016/0008-6223(78)90086-6
dc.relation.referencesen[18] Martinez-Flores R., Camporredondo-Saucedo J., Moreno-C H. et al., Chem. Chem. Technol., 2017, 11, 230. https://doi.org/10.23939/chcht11.02.230
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dc.relation.urihttps://doi.org/10.5714/CL.2017.22.096
dc.relation.urihttps://doi.org/10.2174/1385272811317130013
dc.relation.urihttps://doi.org/10.5714/CL.2013.14.2.094
dc.relation.urihttps://www.erg.kz/ru/news/693
dc.relation.urihttps://www.bp.com/content/dam/bp/business-sites/en/global/corporate/pdf..
dc.relation.urihttps://doi.org/10.1016/j.compositesb.2018.10.098
dc.relation.urihttps://doi.org/10.1016/j.jmrt.2020.05.037
dc.relation.urihttps://doi.org/10.3103/S1068364X15010020
dc.relation.urihttps://doi.org/10.1002/anie.201306129
dc.relation.urihttps://doi.org/10.5714/CL.2014.15.3.162
dc.relation.urihttps://doi.org/10.1007/BF01174704
dc.relation.urihttps://doi.org/10.2298/jsc130702150z
dc.relation.urihttps://doi.org/10.5714/CL.2014.15.4.247
dc.relation.urihttps://doi.org/10.32014/2019.2518-170X.101
dc.relation.urihttps://doi.org/10.1007/978-94-017-9478-7
dc.relation.urihttps://doi.org/10.1016/0008-6223(78)90086-6
dc.relation.urihttps://doi.org/10.23939/chcht11.02.230
dc.relation.urihttps://doi.org/10.1039/c2cs35083a
dc.relation.urihttps://doi.org/10.5714/CL.2016.19.072
dc.relation.urihttp://nano.msu.ru/files/master/I/materials/electromolding.pdf
dc.relation.urihttp://igkrc.ru/assets/publication/trudy-2014-1-p115-134.pdf
dc.rights.holder© Національний університет “Львівська політехніка”, 2021
dc.rights.holder© Imangazy A., Smagulova G., Kaidar B., Mansurov Z., Kerimkulova A., Umbetkaliev K., Zakhidov A., Vorobyev P., Jumadilov T., 2021
dc.subjectкам'яновугільна смола
dc.subjectмезофазна смола
dc.subjectелектроспінінг
dc.subjectвуглецеве волокно
dc.subjectcoal tar
dc.subjectmesophase pitch
dc.subjectelectrospinning
dc.subjectcarbon fiber
dc.titleCompositional Fibers Based on Coal Tar Mesophase Pitch Obtained by Electrospinning Method
dc.title.alternativeКомпозиційні волокна на основі мезофазного пеку кам‘яновугільної смоли, отриманих методом електроспінінгу
dc.typeArticle

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Chemistry & Chemical Technology. – 2021. – Vol. 15, No. 3