Photochemical Water Oxidation by Mn/V Heterobimetallic Complexes as Catalysts
| dc.contributor.author | Pavliuk, Mariia | |
| dc.contributor.author | Mishyn, Vladyslav | |
| dc.date.accessioned | 2015-04-20T12:38:51Z | |
| dc.date.available | 2015-04-20T12:38:51Z | |
| dc.date.issued | 2013 | |
| dc.description.abstract | In this work we investigate heterometallic Mn/V compounds and their ability to catalyze photochemical water oxidation. A novel synthetic route is proposed for the preparation of Mn/V complexes in a one-pot reaction, following the “direct synthesis” approach, using water as a solvent. Two Mn/V compounds, (NH4)2[Mn2(HGly)(H2O)10 [V10O28]∙(HGly)∙2H2O (1) and (NH4)2[Mn( -HAla)(H2O)5]2[V10O28]∙2H2O (2) have been synthesized and characterized by single crystal X-Ray analysis, FTIR and EPR spectroscopy. For 1 and 2 photochemical water oxidation has been investigated in a system using Ru(bpy)3 2+ as a photosensitizer. | uk_UA |
| dc.identifier.citation | Pavliuk M. Photochemical Water Oxidation by Mn/V Heterobimetallic Complexes as Catalysts / Mariia Pavliuk, Vladyslav Mishyn // Хімія та хімічні технології : матеріали IІI Міжнародної конференції молодих вчених CCT-2013, 21–23 листопада 2013 року, Україна, Львів / Національний університет "Львівська політехніка". – Львів : Видавництво Львівської політехніки, 2013. – С. 134–135. – (4-й Міжнародний молодіжний фестиваль науки "Litteris et Artibus"). – Bibliography: 6 titles. | uk_UA |
| dc.identifier.uri | https://ena.lpnu.ua/handle/ntb/27042 | |
| dc.language.iso | en | uk_UA |
| dc.publisher | Видавництво Львівської політехніки | uk_UA |
| dc.subject | Manganese | uk_UA |
| dc.subject | Vanadium | uk_UA |
| dc.subject | Direct synthesis | uk_UA |
| dc.subject | Artificial photosynthesis | uk_UA |
| dc.subject | Bimetallic compounds | uk_UA |
| dc.title | Photochemical Water Oxidation by Mn/V Heterobimetallic Complexes as Catalysts | uk_UA |
| dc.type | Article | uk_UA |