Resins with Oxygen-Containing Functional Groups Obtained from Products of Fossil Fuels Processing: A Review of Achievements

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dc.citation.epage591
dc.citation.issue3
dc.citation.spage574
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.authorPrysiazhnyi, Yuriy
dc.contributor.authorGrynyshyn, Oleg
dc.contributor.authorPyshyev, Serhiy
dc.contributor.authorKorchak, Bohdan
dc.contributor.authorBratychak, Michael
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2024-02-12T08:51:56Z
dc.date.available2024-02-12T08:51:56Z
dc.date.created2023-02-28
dc.date.issued2023-02-28
dc.description.abstractДля синтезу смол з кисневмісними функційними групами використовували фракції С9 піролізу вуглеводнів, важку бензинову і легку фракцію кам’яновугільної смоли, що отримувалися з рідких продуктів коксування вугілля (РПКВ). Використовуючи вищевказані нецільові та/або побічні продукти переробки органічної сировини, різного роду ініціатори й промислові мономери, отримано: методом ініційованої олігомеризації (з фракцій С9) – нафтополімерні смоли з функційними групами; методом радикальної коолігомеризації (з РПКВ) – кумарон-інденові смоли з функційними групами. Вивчено вплив основних чинників керування процесом синтезу смол з функційними групами на їхні кількісні і якісні характеристики, зокрема, досліджено вплив температури процесу, його тривалості і складу реакційної суміші. Використовуючи ІЧ-спектроскопію, проаналізовано структуру синтезованих смол і підтверджено присутність у них функційних груп: епоксидних, карбоксильних, гідроксильних і метакрилатних.
dc.description.abstractTo synthesize resins with oxygen-containing functional groups the C9 fractions of hydrocarbon pyrolysis, heavy gasoline, and light coal tar fraction obtained from coal coking liquid products (CCLP) were used. Various types of initiators and industrial monomers were obtained using the above-mentioned non-target and/or by-products of organic raw materials processing: by the initiated oligomerization method (from C9 fractions) – petroleum polymer resins with functional groups; by radical cooligomerization (from CCLP) (with RPKV) – coumarone-indene resins with functional groups. The influence of the main factors controlling the synthesis process of resins with functional groups on their quantitative and qualitative characteristics was studied, including the process temperature, duration, and the reaction mixture composition. The structure of the synthesized resins was analyzed by IR spectroscopy, and the presence of epoxy, carboxyl, hydroxyl, and methacrylate functional groups was confirmed.
dc.format.extent574-591
dc.format.pages18
dc.identifier.citationResins with Oxygen-Containing Functional Groups Obtained from Products of Fossil Fuels Processing: A Review of Achievements / Yuriy Prysiazhnyi, Oleg Grynyshyn, Serhiy Pyshyev, Bohdan Korchak, Michael Bratychak // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2023. — Vol 17. — No 3. — P. 574–591.
dc.identifier.citationenResins with Oxygen-Containing Functional Groups Obtained from Products of Fossil Fuels Processing: A Review of Achievements / Yuriy Prysiazhnyi, Oleg Grynyshyn, Serhiy Pyshyev, Bohdan Korchak, Michael Bratychak // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2023. — Vol 17. — No 3. — P. 574–591.
dc.identifier.doidoi.org/10.23939/chcht17.03.574
dc.identifier.issn1196-4196
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/61263
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 3 (17), 2023
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dc.relation.references[2] Kumar, S.; Krishnan, S.; Mohanty, S.; Kumar Nayak, S. Synthesis and Characterization of Petroleum and Biobased Epoxy Resins: A Review. Polym. Int. 2018, 67, 815-839. https://doi.org/10.1002/pi.5575
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dc.relation.references[5] Bratychak, М.М. Osnovy promyslovoi naftokhimii; Publishing House of Lviv Polytechnic: Lviv, 2008.
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dc.relation.references[11] Bratychak, M.M.; Hunka, V.M. Khimia nafty i hasu; Publish-ing House of Lviv Polytechnic: Lviv, 2020.
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dc.relation.references[13] Bratyczak, M.; Brozozowski, Z. Cwiczenia laboratoryjne z Chemii i technologii polimerow. Oficyna Wydawnicza Politechniki Warszawskiej: Warszawa, 1997.
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dc.relation.references[19] Bratichak, M.M.; Gagin, M.B.; Bratichak, M.M.; Grinishin, O.B. Epoxy-Containing Peroxide Initiated Copolymerization of Hydrocarbon Pyrolysis C9 Fraction. Ukrainskii Khimicheskii Zhur-nal 2003, 69, 60-63.
dc.relation.references[20] Bratychak, M.; Brostow, W.; Grynyshyn, O.; Shyshchak, O. Synthesis and Characterization of Petroleum Resins with Epoxy Groups. Mater. Res. Innov. 2003, 7, 167-171. https://doi.org/10.1007/s10019-003-0243-5
dc.relation.references[21] Grynyshyn, O.B.; Almauri, S.; Bratychak, M.M. Olihomery z hidroksylnymy hrupamy na osnovi ridkykh produktiv pirolizu vuhlevodniv. Visnyk DU”LP” Khimiia, tekhnolohiia rechovyn ta yikh zastosuvannia 1997, 333, 157-160.
dc.relation.references[22] Grynyshyn, O.B.; Bratychak, M.M.; Almauri, S. Naftopoli-merni smoly z hidroksylnymy hrupamy na osnovi ridkykh produktiv pirolizu dyzelnoho palyva. Naftova i gazova promyslovist 1999, 3, 59-60.
dc.relation.references[23] Grynyshyn, O.; Skibitskiy, V.; Bratychak, M.; Waclawek, W. Obtaining of Petroleum Resins Using Pyrolysis By-Products. 4. Resins with Carboxy Groups. Ecol. Chem. Eng. S 2004, 11, 41-51.
dc.relation.references[24] Bratychak, M.; Astakhova, O.; Shyshchak, O.; Namiesnik, J.; Ripak, O.; Pyshyev, S. Obtaining of Coumarone-Indene Resins Based on Light Fraction of Coal Tar 1. Coumarone-Indene Resins with Carboxy Groups. Chem. Chem. Technol. 2017, 11, 509-516. https://doi.org/10.23939/chcht11.04.509
dc.relation.references[25] Astakhova, O.; Shved, M.; Zubal, O.; Shyshchak, O.; Pry-siazhnyi, Y.; Bruździak, P.; Bratychak, M. Obtaining of Couma-rone-Indene Resins Based on Light Fraction of Coal Tar. 4. Bitu-men-Polymer Blends with Participation of Coumarone-Indene Resins with Epoxy Groups. Chem. Chem. Technol. 2019, 13, 112-120. https://doi.org/10.23939/chcht13.01.112
dc.relation.references[26] Bratychak, M.; Astakhova, O.; Prysiazhnyi, Y.; Shved, M.; Shyshchak, O.; Namiesnik, J.; Plonska-Brzezinska, M. Obtaining of Coumarone-Indene Resins Based on Light Fraction of Coal Tar 3. Coumarone-Indene Resins with Methacrylic Fragments. Chem. Chem. Technol. 2018, 12, 379-385. https://doi.org/10.23939/chcht12.03.379
dc.relation.referencesen[1] Chang, T.; Huang, Y.; Yang, W. Waste to Treasure: Prepara-tion of Functional Polymeric Particles from Waste Olefins in Car-bolic Oil by Self-Stabilized Precipitation Polymerization. ACS Appl. Polym. Mater. 2023, 5, 2807-2815. https://doi.org/10.1021/acsapm.3c00050
dc.relation.referencesen[2] Kumar, S.; Krishnan, S.; Mohanty, S.; Kumar Nayak, S. Synthesis and Characterization of Petroleum and Biobased Epoxy Resins: A Review. Polym. Int. 2018, 67, 815-839. https://doi.org/10.1002/pi.5575
dc.relation.referencesen[3] Hassanpour, M. A Review of Four Kinds of Resin Production Technologies Based On Recent Developments. Int. J. Ind. Eng. 2021, 8, 1-12. http://www.internationaljournalssrg.org/IJIE/paper-details?Id=81
dc.relation.referencesen[4] Bratychak, M.M.; Grynyshyn, O.B. Tekhnolohiia nafty i hazu; Publishing House of Lviv Polytechnic: Lviv, 2013.
dc.relation.referencesen[5] Bratychak, M.M. Osnovy promyslovoi naftokhimii; Publishing House of Lviv Polytechnic: Lviv, 2008.
dc.relation.referencesen[6] Hetmanchuk, Yu.P.; Bratychak, M.M. Khimiia ta tekhnolohiia polimeriv; Beskyd Bit: Lviv, 2006.
dc.relation.referencesen[7] Bratychak, M.M.; Pyshyev, S.V.; Rudkevych, M.I. Khimiia ta tekhnolohiia pererobky vuhillia; Beskyd Bit: Lviv, 2006.
dc.relation.referencesen[8] Pyshyev, S.; Prysiazhnyi, Yu.; Sidun, Iu.; Shved, M.; Bor-beyiyong, G.I.; Korsh, D. Obtaining of Resins Based on Model Mixtures with Indene, Coumarone and Styrene and their Usage as Bitumen Modifiers. Petroleum & Coal 2020, 62, 341-346.
dc.relation.referencesen[9] Topilnytskyy, P.; Romanchuk, V.; Boichenko, S.; Golych, Y. Physico-Chemical Properties and Efficiency of Demulsifiers Based on Block Copolymers of Ethylene and Propylene Oxides. Chem. Chem. Technol. 2014, 8, 211–218. https://doi.org/10.23939/chcht08.02.211
dc.relation.referencesen[10] NIIR Board of Consultants & Engineers. Modern Technology of Synthetic Resins & Their Applications; Asia Pacific Business Press Inc., 2018.
dc.relation.referencesen[11] Bratychak, M.M.; Hunka, V.M. Khimia nafty i hasu; Publish-ing House of Lviv Polytechnic: Lviv, 2020.
dc.relation.referencesen[12] http://online.budstandart.com/ua/catalog/doc-page?id_doc=53602 (accessed 2006-10-01).
dc.relation.referencesen[13] Bratyczak, M.; Brozozowski, Z. Cwiczenia laboratoryjne z Chemii i technologii polimerow. Oficyna Wydawnicza Politechniki Warszawskiej: Warszawa, 1997.
dc.relation.referencesen[14] http://online.budstandart.com/ua/catalog/doc-page.html?id_doc=27130 (accessed 1997-07-01).
dc.relation.referencesen[15] ISO 2554:1997 https://www.iso.org/standard/27071.html (accessed 1997-03-06).
dc.relation.referencesen[16] http://online.budstandart.com/ua/catalog/doc-page.html?id_doc=27125 (accessed 2001-07-01).
dc.relation.referencesen[17] http://online.budstandart.com/ua/catalog/doc-page.html?id_doc=78301 (accessed 2019-06-01).
dc.relation.referencesen[18] Bratychak, M.M.; Grynyshyn, O.B.; Prysiazhnyi, Y.V.; Pushak, A.P. Naftopolimerni smoly z funktsiinymy hrupamy. Syntez, vlastyvosti, zastosuvannia; Publishing House of Lviv Polytechnic: Lviv, 2016.
dc.relation.referencesen[19] Bratichak, M.M.; Gagin, M.B.; Bratichak, M.M.; Grinishin, O.B. Epoxy-Containing Peroxide Initiated Copolymerization of Hydrocarbon Pyrolysis P.9 Fraction. Ukrainskii Khimicheskii Zhur-nal 2003, 69, 60-63.
dc.relation.referencesen[20] Bratychak, M.; Brostow, W.; Grynyshyn, O.; Shyshchak, O. Synthesis and Characterization of Petroleum Resins with Epoxy Groups. Mater. Res. Innov. 2003, 7, 167-171. https://doi.org/10.1007/s10019-003-0243-5
dc.relation.referencesen[21] Grynyshyn, O.B.; Almauri, S.; Bratychak, M.M. Olihomery z hidroksylnymy hrupamy na osnovi ridkykh produktiv pirolizu vuhlevodniv. Visnyk DU"LP" Khimiia, tekhnolohiia rechovyn ta yikh zastosuvannia 1997, 333, 157-160.
dc.relation.referencesen[22] Grynyshyn, O.B.; Bratychak, M.M.; Almauri, S. Naftopoli-merni smoly z hidroksylnymy hrupamy na osnovi ridkykh produktiv pirolizu dyzelnoho palyva. Naftova i gazova promyslovist 1999, 3, 59-60.
dc.relation.referencesen[23] Grynyshyn, O.; Skibitskiy, V.; Bratychak, M.; Waclawek, W. Obtaining of Petroleum Resins Using Pyrolysis By-Products. 4. Resins with Carboxy Groups. Ecol. Chem. Eng. S 2004, 11, 41-51.
dc.relation.referencesen[24] Bratychak, M.; Astakhova, O.; Shyshchak, O.; Namiesnik, J.; Ripak, O.; Pyshyev, S. Obtaining of Coumarone-Indene Resins Based on Light Fraction of Coal Tar 1. Coumarone-Indene Resins with Carboxy Groups. Chem. Chem. Technol. 2017, 11, 509-516. https://doi.org/10.23939/chcht11.04.509
dc.relation.referencesen[25] Astakhova, O.; Shved, M.; Zubal, O.; Shyshchak, O.; Pry-siazhnyi, Y.; Bruździak, P.; Bratychak, M. Obtaining of Couma-rone-Indene Resins Based on Light Fraction of Coal Tar. 4. Bitu-men-Polymer Blends with Participation of Coumarone-Indene Resins with Epoxy Groups. Chem. Chem. Technol. 2019, 13, 112-120. https://doi.org/10.23939/chcht13.01.112
dc.relation.referencesen[26] Bratychak, M.; Astakhova, O.; Prysiazhnyi, Y.; Shved, M.; Shyshchak, O.; Namiesnik, J.; Plonska-Brzezinska, M. Obtaining of Coumarone-Indene Resins Based on Light Fraction of Coal Tar 3. Coumarone-Indene Resins with Methacrylic Fragments. Chem. Chem. Technol. 2018, 12, 379-385. https://doi.org/10.23939/chcht12.03.379
dc.relation.urihttps://doi.org/10.1021/acsapm.3c00050
dc.relation.urihttps://doi.org/10.1002/pi.5575
dc.relation.urihttp://www.internationaljournalssrg.org/IJIE/paper-details?Id=81
dc.relation.urihttps://doi.org/10.23939/chcht08.02.211
dc.relation.urihttp://online.budstandart.com/ua/catalog/doc-page?id_doc=53602
dc.relation.urihttp://online.budstandart.com/ua/catalog/doc-page.html?id_doc=27130
dc.relation.urihttps://www.iso.org/standard/27071.html
dc.relation.urihttp://online.budstandart.com/ua/catalog/doc-page.html?id_doc=27125
dc.relation.urihttp://online.budstandart.com/ua/catalog/doc-page.html?id_doc=78301
dc.relation.urihttps://doi.org/10.1007/s10019-003-0243-5
dc.relation.urihttps://doi.org/10.23939/chcht11.04.509
dc.relation.urihttps://doi.org/10.23939/chcht13.01.112
dc.relation.urihttps://doi.org/10.23939/chcht12.03.379
dc.rights.holder© Національний університет “Львівська політехніка”, 2023
dc.rights.holder© Prysiazhnyi Y., Grynyshyn O., Pyshyev S., Korchak B., Bratychak M., 2023
dc.subjectпродукти переробки органічної сировини
dc.subjectнафтополімерна смола
dc.subjectкумарон-інденова смола
dc.subjectфункційна група
dc.subjectorganic raw materials processing products
dc.subjectpetroleum polymer resin
dc.subjectcoumarone-indene resin
dc.subjectfunctional group
dc.titleResins with Oxygen-Containing Functional Groups Obtained from Products of Fossil Fuels Processing: A Review of Achievements
dc.title.alternativeСмоли з кисневмісними функційними групами, що одержані з продуктів переробки горючих копалин: огляд досягнень
dc.typeArticle

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Chemistry & Chemical Technology. – 2023. – Vol. 17, No. 3