Synthesis of peroxid-containing hetero-chain amphiphilic oligomers and their colloid-chemical properties

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dc.citation.epage32
dc.citation.issue1
dc.citation.spage27
dc.contributor.affiliationНаціональний університет “Львівська політехніка”
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.authorКузнецова, К. І.
dc.contributor.authorФлейчук, Р. І.
dc.contributor.authorТолстенко, А. Д.
dc.contributor.authorГевусь, О. І.
dc.contributor.authorKuznetsova, K.
dc.contributor.authorFleychuk, R.
dc.contributor.authorTolstenko, A.
dc.contributor.authorHevus, O.
dc.coverage.placenameLviv
dc.coverage.placenameLviv
dc.date.accessioned2021-01-28T11:24:21Z
dc.date.available2021-01-28T11:24:21Z
dc.date.created2020-02-24
dc.date.issued2020-02-24
dc.description.abstractСинтезовано нові поверхнево-активні олігомери з альтернатним розміщенням гідрофільних та ліпофільних блоків на основі заміщених пероксидовмісних оксетанів та поліестерів вищих дикарбонових кислот і поліетиленгліколів різної молекулярної маси. Ацилюванням пероксидовмісного оксетану дихлорангідридами декан- та додекандіової кислот синтезовано відповідні біс(пероксиалкілоксетан)естери. Взаємодією отриманих діестерів із поліетиленгліколями PEG-300 та PEG-600 синтезовано амфіфільні олігомери, з реакційноздатними пероксидними групами в бічних відгалуженнях макроланцюга.
dc.description.abstractNew surface-active oligomers were synthesized with the alternative placement of hydrophilic and lipophilic blocks based on substituted peroxide-containing oxetanes and polyesters of higher dicarboxylic acids and polyethylene glycols of different molecular weights. By acylation of peroxide-containing oxetane with dichloroanhydride decane and dodecanedioic acids, the corresponding bis (peroxyalkyloxetane) esters were synthesized. The interaction of the obtained diesters with polyethylene glycols PEG-300 and PEG-600 led to synthesys of amphiphilic oligomers, with reactive peroxide groups in the lateral branches of the macro-chain.
dc.format.extent27-32
dc.format.pages6
dc.identifier.citationSynthesis of peroxid-containing hetero-chain amphiphilic oligomers and their colloid-chemical properties / K. Kuznetsova, R. Fleychuk, A. Tolstenko, O. Hevus // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2020. — Том 3. — № 1. — С. 27–32.
dc.identifier.citationenSynthesis of peroxid-containing hetero-chain amphiphilic oligomers and their colloid-chemical properties / K. Kuznetsova, R. Fleychuk, A. Tolstenko, O. Hevus // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2020. — Vol 3. — No 1. — P. 27–32.
dc.identifier.doidoi.org/10.23939/ctas2020.01.027
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/56095
dc.language.isoen
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry, Technology and Application of Substances, 1 (3), 2020
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dc.relation.referencesen2. Luo, Q., Chen, X., Liu, Z., Sun, Z., Ming, N. (1997). Deposition of oriented polymer films for liquid crystal slignment by pulsed laser ablation. Applied Surface Science, 108(1), 89–93. doi:10.1016/s0169-4332(96)00545-4.
dc.relation.referencesen3. Park, M., Harrison, C., Chaikin P.M., (1997) Block copolymer lithography: Periodic arrays of ~10 to the 11th power holes in 1 square centimeter. Science. 276 (5317). 1401–1404.
dc.relation.referencesen4. Schmolka, I. R. (1977). A review of block polymer surfactants. Journal of the American Oil Chemists’ Society. 54. 110.
dc.relation.referencesen5. Alexandridis, P., Hatton, T. A (1995). Poly(ethylene oxide)-poly(propylene oxide)-poly (ethylene oxide) block copolymer surfactants in aqueous solutions and at interfaces: thermodynamics, structure, dynamics, and modeling. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 96(1–2), 1–46. doi:10.1016/0927-7757(94)03028-x.
dc.relation.referencesen6. Voronov A., Vasylyev S., Kohut A., Peukert, W. (2008). Surface activity of new invertible amphiphilic polyesters based on poly(ethylene glycol) and aliphatic dicarboxylic acids. Journal of Colloid and Interface Science, 323(2), 379–385. doi:10.1016/j.jcis.2008.04.053.
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dc.relation.referencesen9. Nishikubo, T., Kameyama, A., Kudo, H. (2006). Synthesis of Polymers with Well-defined Structures by Novel Ring-opening Reactions of Oxetanes. Journal of Synthetic Organic Chemistry, Japan, 64(9), 934–946. doi:10.5059/yukigoseikyokaishi.64.934.
dc.relation.referencesen10. Kudo, H., Nishikubo, T. (2007). Catalytic reactions of oxetanes with protonic reagents and aprotic reagents leading to novel polymers. Journal of Polymer Science Part A: Polymer Chemistry, 45(5), 709–726. doi:10.1002/pola.21828.
dc.relation.referencesen11. Semlitsch, S., Torron, S., Johansson, M., Martinelle, M. (2016). Enzymatic catalysis as a versatile tool for the synthesis of multifunctional, bio-based oligoester resins. Green Chemistry, 18(7), 1923–1929. doi:10.1039/P.5gc02597d.
dc.relation.referencesen12. Kuznetsova K. I., Vostres V. B., Fleychuk R. I., Hevus O. I., "Synthesis of surface-active monomers and peroxides on a disubstituted oxetane basis". Voprosy khimii i khimicheskoi tekhnologii, 2019, No. 2, pp. 5–11. http://dx.doi.org/10.32434/0321-40952019-123-2-5-11
dc.relation.referencesen13. Nishikubo, T., & Kudo, H. (2007). High Performance Photo-curable Polymers and Oligomers Based on Novel Ring-opening Reactions of Oxetanes. MRS Proceedings, 1005. doi:10.1557/proc-1005-q02-04.
dc.relation.referencesen14. Bobrova K. I., Fleychuk R. I., Hevus O. I. "SyntezneyonohennykhPARnaosnovidyzamishchenykhok setaniv". Visnyk Natsional’noho universytetu "L’vivs’ka politekhnika" Khimiya, tekhnolohiya rechovyn ta yikh zastosuvannya, 2017, No. 868, P. 3–8.
dc.relation.referencesen15. Bobrova K. I., Fleychuk R. I., Hevus O. I. Decomposition of three-, four-, and five-membered oxygenheterocyclesbytert-butylhydroperoxide, Bulletin of the Lviv Polytechnic National University. No. 886. 2018. P. 52–58.
dc.relation.referencesen16. Toroptseva A. M., Belogorodskaya K. V., Bondarenko V. M. Laboratornyy praktikum po khimii i tekhnologii vysokomolekulyarnykh soyedineniy. L., Khimiya, 1972. 416 p.
dc.relation.urihttp://dx.doi.org/10.32434/0321-40952019-123-2-5-11
dc.rights.holder© Національний університет “Львівська політехніка”, 2020
dc.subjectпероксидовмісні амфіфільні олігомери
dc.subjectполіетиленгліколі
dc.subjectоксетани
dc.subjectдикарбонові кислоти
dc.subjectperoxide-containing amphiphilic oligomers
dc.subjectpolyethylene glycols
dc.subjectoxetanes
dc.subjectdicarboxylic acids
dc.titleSynthesis of peroxid-containing hetero-chain amphiphilic oligomers and their colloid-chemical properties
dc.title.alternativeСинтез пероксидо-вмісних гетероланцюгових амфіфільних олігомерів та їх колоїдно-хімічні властивості
dc.typeArticle

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Chemistry, Technology and Application of Substances. – 2020. – Vol. 3, No. 1