Physical and Mathematical Models of Target Component Extraction from Rectlinear Capillaries

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dc.citation.epage117
dc.citation.issue1
dc.citation.spage112
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.authorGumnitsky, Jaroslav
dc.contributor.authorVenger, Lubov
dc.contributor.authorSabadash, Vira
dc.contributor.authorSymak, Dmytro
dc.contributor.authorHyvlud, Anna
dc.contributor.authorGnativ, Zoriana
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2024-01-22T10:41:28Z
dc.date.available2024-01-22T10:41:28Z
dc.date.created2022-03-16
dc.date.issued2022-03-16
dc.description.abstractДосліджено екстрагування твердого компонента з прямолінійного капіляра. Підтверджено наявність двох зон екстрагування: конвективної та молекулярно-дифузійної. Досліджено вплив вакуумування системи на швидкість екстрагування. Показано збільшення зони конвекції під час вакуумування внаслідок виникнення бульбашок пароподібної фази. Визначено коефіцієнти масовіддачі для конвективної зони. Наведено математичну модель молекулярно-дифузійної стадії з врахуванням нелінійної зміни концентрації компонента у рідині внаслідок переміщення границі екстрагування. Визначено коефіцієнти молекулярної дифузії у капілярі.
dc.description.abstractThe extraction of the solid component from the rectilinear capillary has been investigated. The presence of two extraction zones (convective and molecular diffusion) was confirmed. The effect of the system vacuumizing on the extraction rate has been studied. The convection zone during vacuumizing was found to be increased due to the appearance of the vapor phase bubbles. The mass transfer coefficients for the convective zone have been determined. A mathematical model of the molecular diffusion stage is given, taking into account the nonlinear change in the component concentration in the liquid due to the displacement of the extraction boundary. The molecular diffusion coefficients in the capillary have been determined.
dc.format.extent112-117
dc.format.pages6
dc.identifier.citationPhysical and Mathematical Models of Target Component Extraction from Rectlinear Capillaries / Jaroslav Gumnitsky, Lubov Venger, Vira Sabadash, Dmytro Symak, Anna Hyvlud, Zoriana Gnativ // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2022. — Vol 16. — No 1. — P. 112–117.
dc.identifier.citationenPhysical and Mathematical Models of Target Component Extraction from Rectlinear Capillaries / Jaroslav Gumnitsky, Lubov Venger, Vira Sabadash, Dmytro Symak, Anna Hyvlud, Zoriana Gnativ // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2022. — Vol 16. — No 1. — P. 112–117.
dc.identifier.doidoi.org/10.23939/chcht16.01.112
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/60947
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 1 (16), 2022
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dc.relation.references[12] Vorobyova, V.I.; Skiba, M.I.; Trus, I.M. Apricot Pomaces Extract (Prunus Armeniaca L.) as a Highly Efficient Sustainable Corrosion Inhibitor for Mild Steel in Sodium Chloride Solution. Int. J. Corros. Scale Inhib. 2019, 8, 1060-1083. https://doi.org/10.17675/2305-6894-2019-8-4-15
dc.relation.references[13] Allaf, T.; Tomao, V.; Besombes, C.; Chemat, F. Thermal and Mechanical Intensification of Essential Oil Extraction from Orange Peel via Instant Autovaporization. Chem. Eng. Process. 2013, 72, 24-30. https://doi.org/10.1016/j.cep.2013.06.005
dc.relation.references[14] Beiranvand, M.; Ghiasvand, A. Simple, Low-Cost and Reliable Device for Vacuum-Assisted Headspace Solid-Phase Microextraction of Volatile and Semivolatile Compounds from Complex Solid Samples. Chromatographia 2017, 80, 1771-1780. https://doi.org/10.1007/s10337-017-3422-z
dc.relation.references[15] Sabadash, V.; Mylanyk, O.; Matsuska, O.; Gumnitsky, J. Kinetic Regularities of Copper Ions Adsorption by Natural Zeolite. Chem. Chem. Technol. 2017, 11, 459-462. https://doi.org/10.23939/chcht11.04.459
dc.relation.referencesen[1] Romankov, P.G.; Frolov, V.F.; Flisyuk, O.M. Massoobmennyie Processy Khimicheskoy Tekhnologii; Khimizdat: Sankt-Peterburg, 2020.
dc.relation.referencesen[2] Kurt, S.K.; Gürsel, I.V.; Hessel, V.; Nigam, K.D.P.; Kockmann, N. Liquid-Liquid Extraction System with Microstructured Coiled Flow Inverter and Other Capillary Setups for Single-Stage Extraction Applications. Chem. Eng. J. 2016, 284, 764-777. https://doi.org/10.1016/j.cej.2015.08.099
dc.relation.referencesen[3] Vakinti, M.; Mela, S.-M.; Fernández, E.; Psillakis, E.; Psillakis, E. Room Temperature and Sensitive Determination of Haloanisoles in Wine Using Vacuum-Assisted Headspace Solid-Phase Microextraction. J. Chromatogr. 2019, 1602, 142-149. https://doi.org/10.1016/j.chroma.2019.03.047
dc.relation.referencesen[4] Mascrez, S.; Psillakis, E.; Purcaro, G. A Multifaceted Investigation on the Effect of Vacuum on the Headspace Solid-Phase Microextraction of Extra-Virgin Olive Oil. Anal. Chim. Acta 2020, 1103, 106-114. https://doi.org/10.1016/j.aca.2019.12.053
dc.relation.referencesen[5] Aksel'rud, G.A.; Gumnitskii, Y.M. Some Characteristics of the Kinetics of Ion Exchange in the Case of Pulsating Motion of a Liquid. J. Eng. Phys. 1970, 19, 1024-1026. https://doi.org/10.1007/BF00828782
dc.relation.referencesen[6] Gumnitskii Y.M.; Sen'kiv V.N. Extraction of a Solid Substance from Linear Capillaries During Periodic Boiling under Vacuum. Theor. Found. Chem. Eng. 2006, 40, 253-258. https://doi.org/10.1134/S0040579506030055
dc.relation.referencesen[7] Symak, D.; Atamanyuk, V.; Gumnitsky, J. Analysis of Dissolution Kinetics based on the Local Isotropic Turbulence Theory. Chem. Chem. Technol. 2015, 9, 493-496. https://doi.org/10.23939/chcht09.04.493
dc.relation.referencesen[8] Symak, D.; Gumnitsky, J.; Atamaniuk, V.; Nagurskyy, O. Investigation of Physical Dissolution of Benzoic Acid Polydisperse Mixture. Chem. Chem. Technol. 2017, 11, 469. https://doi.org/10.23939/chcht11.04.469
dc.relation.referencesen[9] Pavliuk, I.; Dyachok, V.; Novikov, V.; Ilkiv, N. Kinetics of Biologically Active Compound Extraction from Hops Strobiles Extraction Cake. Chem. Chem. Technol. 2017, 11, 487-491. https://doi.org/10.23939/chcht11.04.487
dc.relation.referencesen[10] Dyachok, V.; Ilkiv, I. On the Mechanism of Extraction from Solid Bodies of Cellular Structure. Chem. Chem. Technol. 2013, 7, 27-30. https://doi.org/10.23939/chcht07.01.027
dc.relation.referencesen[11] Sattari-Najafabadi, M.; Esfahany, M.N.; Wu, Z., Sunden, B. Mass Transfer between Phases in Microchannels: A Review. Chem. Eng. Process 2018, 127, 213-237. https://doi.org/10.1016/j.cep.2018.03.012
dc.relation.referencesen[12] Vorobyova, V.I.; Skiba, M.I.; Trus, I.M. Apricot Pomaces Extract (Prunus Armeniaca L.) as a Highly Efficient Sustainable Corrosion Inhibitor for Mild Steel in Sodium Chloride Solution. Int. J. Corros. Scale Inhib. 2019, 8, 1060-1083. https://doi.org/10.17675/2305-6894-2019-8-4-15
dc.relation.referencesen[13] Allaf, T.; Tomao, V.; Besombes, C.; Chemat, F. Thermal and Mechanical Intensification of Essential Oil Extraction from Orange Peel via Instant Autovaporization. Chem. Eng. Process. 2013, 72, 24-30. https://doi.org/10.1016/j.cep.2013.06.005
dc.relation.referencesen[14] Beiranvand, M.; Ghiasvand, A. Simple, Low-Cost and Reliable Device for Vacuum-Assisted Headspace Solid-Phase Microextraction of Volatile and Semivolatile Compounds from Complex Solid Samples. Chromatographia 2017, 80, 1771-1780. https://doi.org/10.1007/s10337-017-3422-z
dc.relation.referencesen[15] Sabadash, V.; Mylanyk, O.; Matsuska, O.; Gumnitsky, J. Kinetic Regularities of Copper Ions Adsorption by Natural Zeolite. Chem. Chem. Technol. 2017, 11, 459-462. https://doi.org/10.23939/chcht11.04.459
dc.relation.urihttps://doi.org/10.1016/j.cej.2015.08.099
dc.relation.urihttps://doi.org/10.1016/j.chroma.2019.03.047
dc.relation.urihttps://doi.org/10.1016/j.aca.2019.12.053
dc.relation.urihttps://doi.org/10.1007/BF00828782
dc.relation.urihttps://doi.org/10.1134/S0040579506030055
dc.relation.urihttps://doi.org/10.23939/chcht09.04.493
dc.relation.urihttps://doi.org/10.23939/chcht11.04.469
dc.relation.urihttps://doi.org/10.23939/chcht11.04.487
dc.relation.urihttps://doi.org/10.23939/chcht07.01.027
dc.relation.urihttps://doi.org/10.1016/j.cep.2018.03.012
dc.relation.urihttps://doi.org/10.17675/2305-6894-2019-8-4-15
dc.relation.urihttps://doi.org/10.1016/j.cep.2013.06.005
dc.relation.urihttps://doi.org/10.1007/s10337-017-3422-z
dc.relation.urihttps://doi.org/10.23939/chcht11.04.459
dc.rights.holder© Національний університет “Львівська політехніка”, 2022
dc.rights.holder© Gumnitsky J., Venger L., Sabadash V., Symak D., Hyvlud A., Hnativ Z., 2022
dc.subjectекстрагування
dc.subjectкапіляр
dc.subjectматематична модель
dc.subjectкоефіцієнт масовіддачі
dc.subjectкоефіцієнт молекулярної дифузії
dc.subjectextraction
dc.subjectcapillary
dc.subjectmathematical model
dc.subjectmass transfer coefficient
dc.subjectmolecular diffusion coefficient
dc.titlePhysical and Mathematical Models of Target Component Extraction from Rectlinear Capillaries
dc.title.alternativeФізико-математична модель екстрагування цільового компонента з прямолінійних капілярів
dc.typeArticle

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Chemistry & Chemical Technology. – 2022. – Vol. 16, No. 1