Adsorption of Zinc and Iron Ions from Aqueous Solution Using Waste Material as Adsorbent

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dc.citation.epage893
dc.citation.issue4
dc.citation.spage887
dc.contributor.affiliationAl-Nahrain University
dc.contributor.affiliationBaghdad University
dc.contributor.authorMarwa F. Abdul Jabbar
dc.contributor.authorRashid, Sarmad A.
dc.contributor.authorNaife, Tariq M.
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2025-03-05T08:54:13Z
dc.date.created2023-02-28
dc.date.issued2023-02-28
dc.description.abstractУ цій роботі досліджено зменшення вмісту або вилучення іонів токсичних важких елементів, таких як ферум і цинк, з водних розчинів. Для вилучення іонів металів використано періодичний процес із використанням дешевого адсорбційного матеріалу, який називається ядром глоду. Також було вивчено вплив часу контакту, рН, концентрації іонів металів і дозування адсорбенту на відсоток видалення. Це дослідження показало, що ефективність адсорбції або вилучення зростає з часом і кількістю адсорбуючого матеріалу, а також рН показало, що категорія еквівалентних і негативних зарядів є кращою для адсорбції ядром глоду. Встановлено, що найвища ефективність вилучення становить для цинку - 91% і феруму - 95%. За таких умов, тобто за тривалості 120 хвилин, концентрація металу становить 25 м.ч., кількість матеріалу адсорбента - 5 г/л, а рН - 10 для цинку і 7 для феруму. Ізотерма та кінетика адсорбції також були досліджені для іонів обох металів. Результати показали, що отримані дані з адсорбції відповідають ізотермі Ленгмюра та кінетиці псевдодругого порядку для ізотерми та кінетики адсорбції, відповідно.
dc.description.abstractReducing or eliminating ions of toxic heavy elements such as iron and zinc from aqueous solutions has been adopted in this research. The batch process is used to remove metal ions using a cheap adsorbent material that is called hawthorn nucleus. In addition, the influences of contact time, pH, metal ions concentration, and adsorbent dose on the removal percentage have been studied. This study showed that adsorption or removal efficiency increases over time and the quantity of the adsorbent material, as well as pH showed that the equivalent and negative charges category is preferred for adsorption by the hawthorn nucleus. The highest removal efficiency was found to be 91% for zinc and 95% for iron. In such conditions, i.e., 120 minutes time, the metal concentration is 25 ppm, the amount of the adsorbent material is 5 g/L and pH is 10 for zinc and 7 for iron. Adsorption isotherm and kinetics were also investigated for both metal ions. The results showed that the adsorption findings followed Langmuir isotherm and the pseudo-second-order kinetic for adsorption isotherm and kinetics, respectively.
dc.format.extent887-893
dc.format.pages7
dc.identifier.citationMarwa F. Abdul Jabbar Adsorption of Zinc and Iron Ions from Aqueous Solution Using Waste Material as Adsorbent / Marwa F. Abdul Jabbar, Sarmad A. Rashid, Tariq M. Naife // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2023. — Vol 17. — No 4. — P. 887–893.
dc.identifier.citationenMarwa F. Abdul Jabbar Adsorption of Zinc and Iron Ions from Aqueous Solution Using Waste Material as Adsorbent / Marwa F. Abdul Jabbar, Sarmad A. Rashid, Tariq M. Naife // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2023. — Vol 17. — No 4. — P. 887–893.
dc.identifier.doidoi.org/10.23939/chcht17.04.887
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/63700
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 4 (17), 2023
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dc.relation.references[12] Rao, V.D.; Rao, M.V.S.; Murali Krishna, M.P.S. Chromium (VI) Removal using Activated Thuja occidentalis Leaves Carbon Powder – Adsorption Isotherms and Kinetic Studies. Chem. Chem. Technol. 2020, 14, 362-371. https://doi.org/10.23939/chcht14.03.362
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dc.relation.references[14] Mahvi, A.; Naghipour, D.; Vaezi, F.; Nazmara, S. Tea Waste as An adsorbent for Heavy Metal Removal from Industrial Wastewaters. Am J Appl Sci 2005, 2, 372-375. https://doi.org/10.3844/ajassp.2005.372.375
dc.relation.references[15] Akoji, JN.; Jonathan, Y.; Onyebuchi, O. J.; Abdullahi, M. Abstraction of Cu and Pb Ions from Aqueous Solution using Santalum Album (Sandal Fruit Shell) Activated Carbon. Int. J. of Curr. Eng. and Tech. 2015, 5, 2926-2934. https://www.researchgate.net/publication/292156201
dc.relation.references[16] Foo, K.Y.; Hameed, B.H. Review Insights into the Modeling of Adsorption Isotherm Systems. Chem. Eng. J. 2010, 156, 2–10. https://doi.org/10.1016/j.cej.2009.09.013
dc.relation.references[17] Khambhaty, Y.; Mody, K.; Basha, S.; Jha, B. Kinetics Equilibrium and Thermodynamic Studies on Biosorption of Hexavalent Chromium by Dead Fungal Biomass of Marine Aspergillus niger. Chem. Eng. J. 2009, 145, 489–495. https://doi.org/10.1016/j.cej.2008.05.002
dc.relation.references[18] Jaber, H.A.; Abdul Jabbar, M.F. Adsorption of Cationic and Anionic Dyes from Aqueous Solution using Sunflower Husk. Chem. Chem. Technol. 2021, 15, 567-574. https://doi.org/10.23939/chcht15.04.567
dc.relation.referencesen[1] Monser, L.; Adhoum, N. Modified Activated Carbon for the Removal of Copper, Zinc, Chromium and Cyanide from Wastewater. Sep. Purif. Technol. 2002, 26, 137-146. https://doi.org/10.1016/S1383-5866(01)00155-1
dc.relation.referencesen[2] Muthusamy, Mr.P; Hannah, A. Study of Adsorption Isotherm Model and Kinetics on Removal of Zinc Ion from Industrial Waste Water by Using Novel Biosorbent (Phyllanthus Emblica). Int. j. eng. res. appl. 2017, 7, 80-86. 10.9790/9622-0701018086
dc.relation.referencesen[3] Iconaru, S.L.; Motelica-Heino, M.; Guegan, R.; Predoi, M.V.; Prodan, A.M.; Predoi, D. Removal of Zinc Ions using Hydroxyapatite and Study of Ultrasound Behavior of Aqueous Media. Materials 2018, 11, 1350. https://doi.org/10.3390/ma11081350
dc.relation.referencesen[4] Feng, Y.; Gong, J.-L.; Zeng, G.-M.; Niu, Q.-Y.; Zhang, H.-Y.; Niu, C.-G.; Deng, J.-H.; Yan, M. Adsorption of Cd (II) and Zn (II) from Aqueous Solutions using Magnetic Hydroxyapatite Nanoparticles as Adsorbents. Chem. Eng. J. 2010, 162, 487–494. https://doi.org/10.1016/j.cej.2010.05.049
dc.relation.referencesen[5] Salman, H.A.; Ibrahim, M.I.; Tarek, M.M.; Abbas, H.S. Biosorption of Heavy Metals –A Review. J. chem. sci. technol. 2014, 3, 74-102.
dc.relation.referencesen[6] Mobasherpour, I.; Salahi, E.; Pazouki, M. Comparative of the Removal of Pb2+, Cd2+ and Ni2+ by Nanocrystallite Hydroxyapatite from Aqueous Solutions: Adsorption Isotherm Study. Arab. J. Chem. 2012, 5, 439–446. https://doi.org/10.1016/j.arabjc.2010.12.022
dc.relation.referencesen[7] Skwarek, E. Adsorption of Zn on Synthetic Hydroxyapatite from Aqueous Solution. Sep Sci Technol 2014, 49, 1654–1662. https://doi.org/10.1080/01496395.2014.906466
dc.relation.referencesen[8] Crini, G. Non-Conventional Low-Cost Adsorbents for Dye Removal: A review. Bioresour. Technol. 2006, 97, 1061–1085. https://doi.org/10.1016/j.biortech.2005.05.001
dc.relation.referencesen[9] Šćiban, M.; Klašnja, M. Wood Sawdust and Wood Originate Materials as Adsorbents for Heavy Metal Ions. Holz Roh Werkst. 2004, 62, 69-73. https://doi.org/10.1007/s00107-003-0449-7
dc.relation.referencesen[10] Arabyarmohammadi, H.; Salarirad, M. M.; Behnamfard, A. Characterization and Utilization of Clay-Based Construction and Demolition Wastes as Adsorbents for Zinc (II) Removal from Aqueous Solutions: an Equilibrium and Kinetic Study. Environ. Prog. Sustain. Energy 2014, 33, 777-789. https://doi.org/10.1002/ep.11833
dc.relation.referencesen[11] Deivasigamani, P.; Ponnusamy, S.K.; Sundararaman, S.; Suresh, A. Superhigh Adsorption of Cadmium(II) Ions onto Surface Modified Nano Zerovalent Iron Composite (CNS-nZVI): Characterization, Adsorption Kinetics and Isotherm Studies. Chem. Chem. Technol. 2021, 15, 457-464. https://doi.org/10.23939/chcht15.04.457
dc.relation.referencesen[12] Rao, V.D.; Rao, M.V.S.; Murali Krishna, M.P.S. Chromium (VI) Removal using Activated Thuja occidentalis Leaves Carbon Powder – Adsorption Isotherms and Kinetic Studies. Chem. Chem. Technol. 2020, 14, 362-371. https://doi.org/10.23939/chcht14.03.362
dc.relation.referencesen[13] Zafarani, H. R.; Bahrololoom, M. E.; Noubactep, C.; Tashkhourian, J. Green Walnut Shell as A new Material for Removal of Cr(VI) Ions from Aqueous Solutions. Desalination Water Treat. 2015, 55, 431-439. https://doi.org/10.1080/19443994.2014.917986
dc.relation.referencesen[14] Mahvi, A.; Naghipour, D.; Vaezi, F.; Nazmara, S. Tea Waste as An adsorbent for Heavy Metal Removal from Industrial Wastewaters. Am J Appl Sci 2005, 2, 372-375. https://doi.org/10.3844/ajassp.2005.372.375
dc.relation.referencesen[15] Akoji, JN.; Jonathan, Y.; Onyebuchi, O. J.; Abdullahi, M. Abstraction of Cu and Pb Ions from Aqueous Solution using Santalum Album (Sandal Fruit Shell) Activated Carbon. Int. J. of Curr. Eng. and Tech. 2015, 5, 2926-2934. https://www.researchgate.net/publication/292156201
dc.relation.referencesen[16] Foo, K.Y.; Hameed, B.H. Review Insights into the Modeling of Adsorption Isotherm Systems. Chem. Eng. J. 2010, 156, 2–10. https://doi.org/10.1016/j.cej.2009.09.013
dc.relation.referencesen[17] Khambhaty, Y.; Mody, K.; Basha, S.; Jha, B. Kinetics Equilibrium and Thermodynamic Studies on Biosorption of Hexavalent Chromium by Dead Fungal Biomass of Marine Aspergillus niger. Chem. Eng. J. 2009, 145, 489–495. https://doi.org/10.1016/j.cej.2008.05.002
dc.relation.referencesen[18] Jaber, H.A.; Abdul Jabbar, M.F. Adsorption of Cationic and Anionic Dyes from Aqueous Solution using Sunflower Husk. Chem. Chem. Technol. 2021, 15, 567-574. https://doi.org/10.23939/chcht15.04.567
dc.relation.urihttps://doi.org/10.1016/S1383-5866(01)00155-1
dc.relation.urihttps://doi.org/10.3390/ma11081350
dc.relation.urihttps://doi.org/10.1016/j.cej.2010.05.049
dc.relation.urihttps://doi.org/10.1016/j.arabjc.2010.12.022
dc.relation.urihttps://doi.org/10.1080/01496395.2014.906466
dc.relation.urihttps://doi.org/10.1016/j.biortech.2005.05.001
dc.relation.urihttps://doi.org/10.1007/s00107-003-0449-7
dc.relation.urihttps://doi.org/10.1002/ep.11833
dc.relation.urihttps://doi.org/10.23939/chcht15.04.457
dc.relation.urihttps://doi.org/10.23939/chcht14.03.362
dc.relation.urihttps://doi.org/10.1080/19443994.2014.917986
dc.relation.urihttps://doi.org/10.3844/ajassp.2005.372.375
dc.relation.urihttps://www.researchgate.net/publication/292156201
dc.relation.urihttps://doi.org/10.1016/j.cej.2009.09.013
dc.relation.urihttps://doi.org/10.1016/j.cej.2008.05.002
dc.relation.urihttps://doi.org/10.23939/chcht15.04.567
dc.rights.holder© Національний університет “Львівська політехніка”, 2023
dc.rights.holder© Abdul Jabbar M. F., Rashid S. A., Naife T. M., 2023
dc.subjectадсорбція
dc.subjectвідходи
dc.subjectіони важких металів
dc.subjectадсорбент
dc.subjectглід
dc.subjectadsorption
dc.subjectwaste material
dc.subjectheavy metal ions
dc.subjectadsorbent
dc.subjecthawthorn
dc.titleAdsorption of Zinc and Iron Ions from Aqueous Solution Using Waste Material as Adsorbent
dc.title.alternativeАдсорбція іонів цинку та феруму з водного розчину з використанням відходів як адсорбенту
dc.typeArticle

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Chemistry & Chemical Technology. – 2023. – Vol. 17, No. 4