Properties of the Composites Made of Glauconite and Polyaniline in Aqueous Solutions of Phosphoric Acid

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dc.citation.epage495
dc.citation.issue4
dc.citation.spage487
dc.contributor.affiliationIvan Franko National University of Lviv
dc.contributor.authorNesterivska, Solomiia
dc.contributor.authorMakogon, Victoriia
dc.contributor.authorYatsyshyn, Mykhaylo
dc.contributor.authorSaldan, Ivan
dc.contributor.authorReshetnyak, Oleksandr
dc.contributor.authorGerman, Nestor
dc.contributor.authorStadnyk, Yurii
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2023-12-13T10:03:01Z
dc.date.available2023-12-13T10:03:01Z
dc.date.created2010-03-16
dc.date.issued2010-03-16
dc.description.abstractОкисненням аніліну з використанням амоній пероксидисульфату у водних розчинах фосфатної кислоти на поверхні порошкоподібного глауконіту приготовлені глауконіт-поліанілінові композити. За допомогою Х-променевої дифракції та ІЧ спектроскопії з перетворенням Фур’є підтверджено міжмолекулярну взаємодію між аморфними макромолекулами поліаніліну та міжфазне зв’язування поліаніліну до поверхні глауконіту. Встановлено, що збільшння концентрації фосфатної кислоти приводить до більш міцного міжмолекулярного та міжфазного контакту через водневий зв’язок, наслідком чого є вища електропровідність, але не має впливу на магнітну сприйнятливість композитів. З використанням термічного аналізу підтверджено міжфазну взаємодію між макромолекулами поліаніліну та поверхнею порошкоподібного глауконіту.
dc.description.abstractThe glauconite-polyaniline composites were prepared through oxidation of aniline using ammonium peroxodisulfate in aqueous solutions of phosphoric acid on the surface of a glauconite powder. Intermolecular interaction between amorphous polyaniline macromolecules and interphase coupling of polyaniline to the glauconite surface was confirmed by X-ray diffraction and FT-IR spectroscopy. Higher concentration of phosphoric acid led to a stronger intermolecular and interphase connection because of H-bonding, and that resulted in higher electric conductivity while a magnetic susceptibility of the composites was not affected. Thermal analysis for the prepared composites confirmed the interfacial interaction between the polyaniline macromolecules and the surface of powdered glauconite.
dc.format.extent487-495
dc.format.pages9
dc.identifier.citationProperties of the Composites Made of Glauconite and Polyaniline in Aqueous Solutions of Phosphoric Acid / Solomiia Nesterivska, Victoriia Makogon, Mykhaylo Yatsyshyn, Ivan Saldan, Oleksandr Reshetnyak, Nestor German, Yurii Stadnyk // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2020. — Vol 14. — No 4. — P. 487–495.
dc.identifier.citationenProperties of the Composites Made of Glauconite and Polyaniline in Aqueous Solutions of Phosphoric Acid / Solomiia Nesterivska, Victoriia Makogon, Mykhaylo Yatsyshyn, Ivan Saldan, Oleksandr Reshetnyak, Nestor German, Yurii Stadnyk // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2020. — Vol 14. — No 4. — P. 487–495.
dc.identifier.doidoi.org/10.23939/chcht14.04.487
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/60578
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 4 (14), 2020
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dc.relation.urihttps://doi.org/10.1177/0021998306067321
dc.relation.urihttps://doi.org/10.1002/pat.852
dc.relation.urihttps://doi.org/10.3390/ma2030992
dc.relation.urihttps://doi.org/10.1016/S0032-3861(00)00800-4
dc.relation.urihttps://doi.org/10.1016/j.matchemphys.2008.08.055
dc.relation.urihttps://doi.org/10.1016/j.matlet.2005.12.033
dc.relation.urihttps://doi.org/10.1016/j.synthmet.2013.06.004
dc.relation.urihttps://doi.org/10.23939/chcht10.04.429
dc.relation.urihttps://doi.org/10.1007/s10924-016-0763-x
dc.relation.urihttps://doi.org/10.1002/pola.21422
dc.relation.urihttps://doi.org/10.1016/j.electacta.2008.11.022
dc.relation.urihttps://doi.org/10.1016/0379-6779(94)02337-X
dc.relation.urihttps://doi.org/10.1002/pen.20167
dc.relation.urihttps://doi.org/10.1016/j.polymer.2005.10.145
dc.relation.urihttps://doi.org/10.1016/j.tsf.2006.05.038
dc.relation.urihttps://doi.org/10.1002/pat.974
dc.relation.urihttps://doi.org/10.1016/j.polymer.2008.09.044
dc.relation.urihttps://doi.org/10.1016/j.synthmet.2012.10.015
dc.relation.urihttps://doi.org/10.1016/j.synthmet.2013.09.037
dc.relation.urihttps://doi.org/10.1007/978-3-642-70733-9
dc.relation.urihttps://doi.org/10.1016/j.jpcs.2011.11.043
dc.relation.urihttps://doi.org/10.1002/app.27254
dc.relation.urihttps://doi.org/10.1016/j.synthmet.2009.10.022
dc.relation.urihttps://doi.org/10.1016/j.clay.2015.01.018
dc.relation.urihttps://doi.org/10.1007/s10853-011-5815-y
dc.relation.urihttps://doi.org/10.1016/0012-8252(72)90063-3
dc.relation.urihttps://doi.org/10.1201/9781315366357
dc.relation.urihttps://doi.org/10.1016/j.carbpol.2018.06.049
dc.relation.urihttps://doi.org/10.1016/j.eurpolymj.2008.03.010
dc.relation.urihttps://doi.org/10.1007/s10973-009-0217-y
dc.relation.urihttps://doi.org/10.1007/s10854-012-0933-0
dc.relation.urihttps://doi.org/10.1007/s12034-018-1705-0
dc.relation.urihttps://doi.org/10.1016/j.tsf.2014.05.006
dc.relation.urihttps://doi.org/10.23939/chcht13.01
dc.rights.holder© Національний університет “Львівська політехніка”, 2020
dc.rights.holder© Nesterivska S., Makogon V., Yatsyshyn M., Saldan I., Reshetnyak O., German N., Stadnyk Y., 2020
dc.subjectкомпозит глауконіт-поліанілін
dc.subjectструктура
dc.subjectелектрична провідність
dc.subjectмагнітна сприйнятливість
dc.subjectтермічна стабільність
dc.subjectglauconite-polyaniline composite
dc.subjectstructure
dc.subjectelectric conductivity
dc.subjectmagnetic susceptibility
dc.subjectthermal stability
dc.titleProperties of the Composites Made of Glauconite and Polyaniline in Aqueous Solutions of Phosphoric Acid
dc.title.alternativeВластивості композитів приготовлених з глауконіту та поліаніліну у водних розчинах фосфатної кислоти
dc.typeArticle

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Chemistry & Chemical Technology. – 2020. – Vol. 14, No. 4