Phase Equilibrium of Petroleum Dispersion Systems in Terms of Thermodynamics and Kinetics
dc.citation.epage | 141 | |
dc.citation.issue | 1 | |
dc.citation.spage | 132 | |
dc.contributor.affiliation | Ukrainian State University of Chemical Technology | |
dc.contributor.affiliation | PJSC “Ukrtatnafta” | |
dc.contributor.affiliation | Lviv Polytechnic National University | |
dc.contributor.author | Tertyshna, Olena | |
dc.contributor.author | Zamikula, Konstantin | |
dc.contributor.author | Tertyshny, Oleg | |
dc.contributor.author | Zinchenko, Olena | |
dc.contributor.author | Topilnytskyi, Petro | |
dc.coverage.placename | Львів | |
dc.coverage.placename | Lviv | |
dc.date.accessioned | 2024-01-09T09:32:58Z | |
dc.date.available | 2024-01-09T09:32:58Z | |
dc.date.created | 2021-03-16 | |
dc.date.issued | 2021-03-16 | |
dc.description.abstract | Розглянуто процес парафіноутворення, включаючи особливості будови парафінів, внаслідок фазових переходів при зниженні температури. Розроблено математичні моделі термодинамічних і кінетичних розрахунків фазової рівноваги системи “тверде тіло-рідина”. Встановлено, що для зміщення рівноваги “мазут-парафін” до рідини необхідно зменшити відношення активностей твердої і рідкої фаз за допомогою введення в систему речовини з меншим параметром розчинності. Синтезовано додаток рослинного походження для підвищення стійкості і структурно-механічних характеристик мазуту. Досліджено фазові переходи в мазуті в залежності від температури при додаванні різної кількості додатку. | |
dc.description.abstract | The process of paraffin formation has been considered, including the peculiarities of the paraffin structure as a result of phase transitions with a decreasing temperature. Mathematical models for thermodynamic and kinetic calculations of the “solid-liquid” system phase equilibrium have been developed. To shift the “fuel oilparaffin” balance towards the liquid, it is necessary to reduce the activity ratio of solid and liquid phases by introducing into the system a substance with a lower solubility parameter. To increase the stability, as well as structural and mechanical characteristics of fuel oil, the additive of plant origin was synthesized. The phase transitions in fuel oil depending on the temperature when adding different amounts of additives have been studied. | |
dc.format.extent | 132-141 | |
dc.format.pages | 10 | |
dc.identifier.citation | Phase Equilibrium of Petroleum Dispersion Systems in Terms of Thermodynamics and Kinetics / Olena Tertyshna, Konstantin Zamikula, Oleg Tertyshny, Olena Zinchenko, Petro Topilnytskyi // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2021. — Vol 15. — No 1. — P. 132–141. | |
dc.identifier.citationen | Phase Equilibrium of Petroleum Dispersion Systems in Terms of Thermodynamics and Kinetics / Olena Tertyshna, Konstantin Zamikula, Oleg Tertyshny, Olena Zinchenko, Petro Topilnytskyi // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2021. — Vol 15. — No 1. — P. 132–141. | |
dc.identifier.doi | doi.org/10.23939/chcht15.01.132 | |
dc.identifier.uri | https://ena.lpnu.ua/handle/ntb/60695 | |
dc.language.iso | en | |
dc.publisher | Видавництво Львівської політехніки | |
dc.publisher | Lviv Politechnic Publishing House | |
dc.relation.ispartof | Chemistry & Chemical Technology, 1 (15), 2021 | |
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dc.relation.referencesen | [1] Pylypiv L., Naftohazova Enerhetyka, 2013, 1, 60. | |
dc.relation.referencesen | [2] Rojenko K., Tertyshna O., Snizhko L. et al., Naftohazova Haluz Ukrainy, 2014, 2, 24. | |
dc.relation.referencesen | [3] Ivanova L., BurovE., KoshelevV.:Neftegazovoe Delo, 2011, 1, 268. | |
dc.relation.referencesen | [4] Reistle C., Paraffin and Congealing-Oil Problems. G.P.O., Washington 1932. | |
dc.relation.referencesen | [5] Musakaev N., Proceedings of International Conference RDAMM2001, Russia, Novosybirs’k 2001, 6-2, 318. | |
dc.relation.referencesen | [6] Sharafutdinov R., Prikladnaia Mechanika i Technicheskaia Fizika, 2001, 2, 111. | |
dc.relation.referencesen | [7] Brusilovskyj A., Fazovye Prevrashchenia pryRazrabotke Mestorozhdenyi Nefti i Gaza. Graal, Moskva 2002. | |
dc.relation.referencesen | [8] Ortega-Rodriguez A., Cruz S., Gil-Villegas A. et al., Energ. Fuel, 2003, 17, 1100. https://doi.org/10.1021/ef030005s | |
dc.relation.referencesen | [9] Pedersen K., Skovborg P., Ronningsen H., Energ. Fuel, 1991, 5, 924. https://doi.org/10.1021/ef00030a022 | |
dc.relation.referencesen | [10] Ghanaei E., Esmaeilzadeh F., Fathi Kaljahi F., Int. J. Chem. Mol. Eng., 2007, 1, 48. | |
dc.relation.referencesen | [11] Moiseev I., Uspechi Khimii, 2013, 82, 616. | |
dc.relation.referencesen | [12] Maksymuk Ju., Buhlak A., Kruk V. et al., Khimia i Technologia Topliv i Masel, 2013, 3, 9. | |
dc.relation.referencesen | [13] Maksymuk Ju., Buhlak A., Kruk V. et al., Khimia i Technologia Topliv i Masel, 2013, 2, 12. | |
dc.relation.referencesen | [14] Shabarov Ju., Organicheskaia Khimia. Khimia, Moskva 2010. | |
dc.relation.referencesen | [15] http://docs.cntd.ru/document/gost-30418-96 | |
dc.relation.referencesen | [16] https://www.astm.org/DATABASE.CART/HISTORICAL/D97-09.htm | |
dc.relation.referencesen | [17] http://online.budstandart.com/ua/catalog/doc-page?id_doc=65853 | |
dc.relation.referencesen | [18] http://docs.cntd.ru/document/1200122881 | |
dc.relation.referencesen | [19] http://docs.cntd.ru/document/gost-4333-87 | |
dc.relation.referencesen | [20] Tertyshna O., Royenko K., Martynenko V. et al., Chem. Chem. Technol., 2016, 10, 361. https://doi.org/10.23939/chcht10.03.361 | |
dc.relation.referencesen | [21] Zougari M., Sopkow T., Ind. Eng. Chem. Res., 2007, 46, 1360. https://doi.org/10.1021/ie061002g | |
dc.relation.referencesen | [22] Sivuchin D., Obshchyi Kurs Fiziky. Tom II. Termodynamica i Molekuliarnaia Fizika. Nauka, Moskva 1990. | |
dc.relation.referencesen | [23] Won K., Fluid Phase Equilib., 1986, 30, 265. https://doi.org/10.1016/0378-3812(86)80061-9 | |
dc.relation.referencesen | [24] Won K., Fluid Phase Equilib., 1989, 13, 377. https://doi.org/10.1016/0378-3812(89)80104-9 | |
dc.relation.referencesen | [25] Murgich J., Merino-Garcia D., Andersen S. et al., Langmuir, 2002, 18, 9080. https://doi.org/10.1021/la025882p | |
dc.relation.referencesen | [26] Chung T.-H., SPE 67th Annual Technical Conference and Exhibition. USA, Washington 1992, 869. https://doi.org/10.2118/24851-MS | |
dc.relation.referencesen | [27] Tertyshnau E., Martynenko V., Gyrenko A. et al., SOCAR Proceedings, 2018, 1, 52. https://doi.org/10.5510/OGP20180100340 | |
dc.relation.referencesen | [28] http://online.budstandart.com/ua/catalog/docpage?id_doc=70773 | |
dc.relation.referencesen | [29] Markin A., Suchoverchov S., Vestnik DVO Ros. Akad. Nauk, 2011, 5, 66. | |
dc.relation.uri | https://doi.org/10.1021/ef030005s | |
dc.relation.uri | https://doi.org/10.1021/ef00030a022 | |
dc.relation.uri | http://docs.cntd.ru/document/gost-30418-96 | |
dc.relation.uri | https://www.astm.org/DATABASE.CART/HISTORICAL/D97-09.htm | |
dc.relation.uri | http://online.budstandart.com/ua/catalog/doc-page?id_doc=65853 | |
dc.relation.uri | http://docs.cntd.ru/document/1200122881 | |
dc.relation.uri | http://docs.cntd.ru/document/gost-4333-87 | |
dc.relation.uri | https://doi.org/10.23939/chcht10.03.361 | |
dc.relation.uri | https://doi.org/10.1021/ie061002g | |
dc.relation.uri | https://doi.org/10.1016/0378-3812(86)80061-9 | |
dc.relation.uri | https://doi.org/10.1016/0378-3812(89)80104-9 | |
dc.relation.uri | https://doi.org/10.1021/la025882p | |
dc.relation.uri | https://doi.org/10.2118/24851-MS | |
dc.relation.uri | https://doi.org/10.5510/OGP20180100340 | |
dc.relation.uri | http://online.budstandart.com/ua/catalog/docpage?id_doc=70773 | |
dc.rights.holder | © Національний університет “Львівська політехніка”, 2021 | |
dc.rights.holder | © Tertyshna O., Zamikula K., Tertyshny O., Zinchenko O., Topilnytskyi P., 2021 | |
dc.subject | фазова рівновага | |
dc.subject | математична модель | |
dc.subject | термодинаміка | |
dc.subject | кінетика | |
dc.subject | додаток | |
dc.subject | мазут | |
dc.subject | парафін | |
dc.subject | кристали | |
dc.subject | phase equilibrium | |
dc.subject | mathematical model | |
dc.subject | thermodynamics | |
dc.subject | kinetics | |
dc.subject | additive | |
dc.subject | fuel oil | |
dc.subject | paraffin | |
dc.title | Phase Equilibrium of Petroleum Dispersion Systems in Terms of Thermodynamics and Kinetics | |
dc.title.alternative | Фазова рівновага нафтових дисперсних систем з позиції термодинаміки та кінетики | |
dc.type | Article |
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