Spontaneous Polymerization of 4-Vinylpyridine Monomer on Micron-Sized Mica Platelets

Simple item page
dc.citation.epage806
dc.citation.issue4
dc.citation.spage800
dc.contributor.affiliationCentre de Recherche Scientifique et Technique en Analyses PhysicoChimiques
dc.contributor.affiliationUniversité de Tlemcen
dc.contributor.authorDergal, Fayçal
dc.contributor.authorLerari, Djahida
dc.contributor.authorBachari, Khaldoun
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2025-03-05T08:54:08Z
dc.date.created2023-02-28
dc.date.issued2023-02-28
dc.description.abstractУ цій роботі повідомляється про спонтанну полімеризацію двох композитних матеріалів на основі P4VP і слюди у двох різних співвідношеннях: 4VP/слюда/R=5 і 4VP/слюда/R=10, позначених як P4VP5@mica і P4VP10@mica відповідно. Отримані композити були охарактеризовані за допомогою термогравіметричного аналізу (TGA), інфрачервоної спектроскопії з перетворенням Фур’є (FTIR) ісканувальної електронної мікроскопії (SEM). Полімеризований P4VP на неорганічній поверхні має потенційний інтерес для модифікації міжфазних властивостей слюди.
dc.description.abstractIn this study, we reported the spontaneous polymerization of two composite materials based on P4VP and mica at two different ratios, 4VP/mica/R=5 and 4VP/mica/R=10, noted as P4VP5@mica and P4VP10@mica, respectively. The obtained composites were characterized using thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). The polymerized P4VP on the inorganic surface has potential interest for the modification of the interfacial properties of the mica.
dc.format.extent800-806
dc.format.pages7
dc.identifier.citationDergal F. Spontaneous Polymerization of 4-Vinylpyridine Monomer on Micron-Sized Mica Platelets / Fayçal Dergal, Djahida Lerari, Khaldoun Bachari // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2023. — Vol 17. — No 4. — P. 800–806.
dc.identifier.citationenDergal F. Spontaneous Polymerization of 4-Vinylpyridine Monomer on Micron-Sized Mica Platelets / Fayçal Dergal, Djahida Lerari, Khaldoun Bachari // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2023. — Vol 17. — No 4. — P. 800–806.
dc.identifier.doidoi.org/10.23939/chcht17.04.800
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/63690
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 4 (17), 2023
dc.relation.references[1] Ghannam, L.;Bacou, M.;Garay, H.; Shanahan, M.E.R.; François, J.; Billon, L. Elastomer Monolayers Adsorbed on Mica Surfaces by Nitroxide-Mediated Polymerisation. Polymer2004, 45, 7035-7045. https://doi.org/10.1016/j.polymer.2004.08.002
dc.relation.references[2] Bacquet, M.; Martel, B.;Morcellet, M.; Benabadji, K.I.;Medjahed, K.;Mansri, A.;Meniai, A.H.;Lehocine, M.B. Adsorption of Poly (4-Vinylpyridine) onto Bentonites. Mater. Lett. 2004, 58, 455-459. https://doi.org/10.1016/S0167-577X(03)00524-X.
dc.relation.references[3] Gan, D.; Lu, S.; Song, C.; Wang, Z. Physical Properties of Poly (Ether Ketone Ketone)/Mica Composites: Effect of Filler Content. Mater.Lett.2001, 48, 299-302. https://doi.org/10.1016/S0167-577X(00)00318-9
dc.relation.references[4] Brotherson, B.; Deng, Y. Site Blocking Effect on the Conformation of Adsorbed Cationic Polyacrylamide on a Solid Surface. J. Colloid Interface Sci. 2008, 326, 324-328. https://doi.org/10.1016/j.jcis.2008.06.035
dc.relation.references[5] Mansri, A.; Benabadji, K.I.;Desbrières, J.; François, J. Chromium Removal Using Modified Poly (4-Vinylpyridinium) Bentonite Salts. Desalination2009, 245, 95-107. https://doi.org/10.1016/j.desal.2008.06.012
dc.relation.references[6] Brinks, M.K.;Studer, A. Polymer Brushes by Nitroxide-Mediated Polymerization. Macromol.Rapid Commun.2009, 30, 1043-1057. https://doi.org/10.1002/marc.200800720
dc.relation.references[7] Parvole, J.; Billon, L.; Montfort, J.P. Formation of Polyacrylate Brushes on Silica Surfaces. Polym. Int.2002, 51, 1111-1116. https://doi.org/10.1002/pi.1045
dc.relation.references[8] Escocio, V.;Altstadt, V.;Visconte, L.; de Carvalho, M.;Nunes, R. TPU/Mica Composites Prepared in Torque Rheometer: Processability, Mechanical Properties and Morphology.Chem. Chem. Technol.2011, 5, 191–195. https://doi.org/10.23939/chcht05.02.191
dc.relation.references[9] Jumadilov, T.;Kondaurov, R.;Imangazy, A.;Myrzakhmetova, N.;Saparbekova, I. Phenomenon of Remote Interaction and Sorption Ability of Rare Cross-linked Hydrogels of Polymethacrylic Acid and Poly-4-vinylpyridine in Relation to Erbium Ions. Chem. Chem. Technol.2019, 13, 451-458. https://doi.org/10.23939/chcht13.04.451
dc.relation.references[10] Marques, M.;Rosa, J.; Cruz, K. Influence of Chemical Treatment on Sodium Clay for Obtaining Polypropylene Nanocomposites.Chem. Chem. Technol.2011, 5, 433-438. https://doi.org/10.23939/chcht05.04.433
dc.relation.references[11] Parvole, J.;Laruelle, G.;Guimon, C.; Francois, J.; Billon, L. Initiator‐Grafted Silica Particles for Controlled Free Radical Polymerization: Influence of the Initiator Structure on the Grafting Density.Macromol.Rapid Commun.2003, 24, 1074-1078. https://doi.org/10.1002/marc.200300035
dc.relation.references[12] Kickelbick, G. Concepts for the Incorporation of Inorganic Building Blocks into Organic Polymers on a Nanoscale. Prog.Polym. Sci. 2003, 28, 83-114. https://doi.org/10.1016/S0079-6700(02)00019-9
dc.relation.references[13] Mansri, A.;Ramdani, N. In situPolymerization of 4-Vinylpyridine/Bentonite Composites and their Application for Toluene Removal.Res. Chem.Intermed.2015, 41, 1765-1776. https://doi.org/10.1007/s11164-013-1310-1
dc.relation.references[14] Mansri, A.;Dergal, F.; Billon, L. Formulation and Characterization of New pH Dependent [Alizarin‐poly (4‐vinylpyridine)‐mica] Pigments. Macromol. Symp.2015, 354, 131-144. https://doi.org/10.1002/masy.201400004
dc.relation.references[15] Choukchou-Braham, E.;Benabadji, I.;Mansri, A.; François, J. Molecular Weight Influence on Viscosimetric Parameters of Poly (4-Vinylpyridine) Polymers. Eur. Polym. J. 2003, 39, 297-303. https://doi.org/10.1016/S0014-3057(02)00221-5.
dc.relation.references[16] Mansri, A.; Frère, Y.;Chovino, C.;Gramain, P. Synthesis and Thermal Properties of Poly [n-(Monomethoxypolyethylene Oxide) - 4- Vinylpyridinium Salt]s. Des. Monomers Polym. 2000, 3, 55-66. https://doi.org/10.1163/156855500750198726
dc.relation.references[17] Ghannam, L.;Parvole, J.;Laruelle, G.; Francois, J.; Billon, L. Surface‐Initiated Nitroxide‐Mediated Polymerization: A Tool for Hybrid Inorganic/Organic Nanocomposites ‘in situ’Synthesis. Polym. Int.2006, 55, 1199-1207.https://doi.org/10.1002/pi.1985
dc.relation.referencesen[1] Ghannam, L.;Bacou, M.;Garay, H.; Shanahan, M.E.R.; François, J.; Billon, L. Elastomer Monolayers Adsorbed on Mica Surfaces by Nitroxide-Mediated Polymerisation. Polymer2004, 45, 7035-7045. https://doi.org/10.1016/j.polymer.2004.08.002
dc.relation.referencesen[2] Bacquet, M.; Martel, B.;Morcellet, M.; Benabadji, K.I.;Medjahed, K.;Mansri, A.;Meniai, A.H.;Lehocine, M.B. Adsorption of Poly (4-Vinylpyridine) onto Bentonites. Mater. Lett. 2004, 58, 455-459. https://doi.org/10.1016/S0167-577X(03)00524-X.
dc.relation.referencesen[3] Gan, D.; Lu, S.; Song, C.; Wang, Z. Physical Properties of Poly (Ether Ketone Ketone)/Mica Composites: Effect of Filler Content. Mater.Lett.2001, 48, 299-302. https://doi.org/10.1016/S0167-577X(00)00318-9
dc.relation.referencesen[4] Brotherson, B.; Deng, Y. Site Blocking Effect on the Conformation of Adsorbed Cationic Polyacrylamide on a Solid Surface. J. Colloid Interface Sci. 2008, 326, 324-328. https://doi.org/10.1016/j.jcis.2008.06.035
dc.relation.referencesen[5] Mansri, A.; Benabadji, K.I.;Desbrières, J.; François, J. Chromium Removal Using Modified Poly (4-Vinylpyridinium) Bentonite Salts. Desalination2009, 245, 95-107. https://doi.org/10.1016/j.desal.2008.06.012
dc.relation.referencesen[6] Brinks, M.K.;Studer, A. Polymer Brushes by Nitroxide-Mediated Polymerization. Macromol.Rapid Commun.2009, 30, 1043-1057. https://doi.org/10.1002/marc.200800720
dc.relation.referencesen[7] Parvole, J.; Billon, L.; Montfort, J.P. Formation of Polyacrylate Brushes on Silica Surfaces. Polym. Int.2002, 51, 1111-1116. https://doi.org/10.1002/pi.1045
dc.relation.referencesen[8] Escocio, V.;Altstadt, V.;Visconte, L.; de Carvalho, M.;Nunes, R. TPU/Mica Composites Prepared in Torque Rheometer: Processability, Mechanical Properties and Morphology.Chem. Chem. Technol.2011, 5, 191–195. https://doi.org/10.23939/chcht05.02.191
dc.relation.referencesen[9] Jumadilov, T.;Kondaurov, R.;Imangazy, A.;Myrzakhmetova, N.;Saparbekova, I. Phenomenon of Remote Interaction and Sorption Ability of Rare Cross-linked Hydrogels of Polymethacrylic Acid and Poly-4-vinylpyridine in Relation to Erbium Ions. Chem. Chem. Technol.2019, 13, 451-458. https://doi.org/10.23939/chcht13.04.451
dc.relation.referencesen[10] Marques, M.;Rosa, J.; Cruz, K. Influence of Chemical Treatment on Sodium Clay for Obtaining Polypropylene Nanocomposites.Chem. Chem. Technol.2011, 5, 433-438. https://doi.org/10.23939/chcht05.04.433
dc.relation.referencesen[11] Parvole, J.;Laruelle, G.;Guimon, C.; Francois, J.; Billon, L. Initiator‐Grafted Silica Particles for Controlled Free Radical Polymerization: Influence of the Initiator Structure on the Grafting Density.Macromol.Rapid Commun.2003, 24, 1074-1078. https://doi.org/10.1002/marc.200300035
dc.relation.referencesen[12] Kickelbick, G. Concepts for the Incorporation of Inorganic Building Blocks into Organic Polymers on a Nanoscale. Prog.Polym. Sci. 2003, 28, 83-114. https://doi.org/10.1016/S0079-6700(02)00019-9
dc.relation.referencesen[13] Mansri, A.;Ramdani, N. In situPolymerization of 4-Vinylpyridine/Bentonite Composites and their Application for Toluene Removal.Res. Chem.Intermed.2015, 41, 1765-1776. https://doi.org/10.1007/s11164-013-1310-1
dc.relation.referencesen[14] Mansri, A.;Dergal, F.; Billon, L. Formulation and Characterization of New pH Dependent [Alizarin‐poly (4‐vinylpyridine)‐mica] Pigments. Macromol. Symp.2015, 354, 131-144. https://doi.org/10.1002/masy.201400004
dc.relation.referencesen[15] Choukchou-Braham, E.;Benabadji, I.;Mansri, A.; François, J. Molecular Weight Influence on Viscosimetric Parameters of Poly (4-Vinylpyridine) Polymers. Eur. Polym. J. 2003, 39, 297-303. https://doi.org/10.1016/S0014-3057(02)00221-5.
dc.relation.referencesen[16] Mansri, A.; Frère, Y.;Chovino, C.;Gramain, P. Synthesis and Thermal Properties of Poly [n-(Monomethoxypolyethylene Oxide) - 4- Vinylpyridinium Salt]s. Des. Monomers Polym. 2000, 3, 55-66. https://doi.org/10.1163/156855500750198726
dc.relation.referencesen[17] Ghannam, L.;Parvole, J.;Laruelle, G.; Francois, J.; Billon, L. Surface‐Initiated Nitroxide‐Mediated Polymerization: A Tool for Hybrid Inorganic/Organic Nanocomposites ‘in situ’Synthesis. Polym. Int.2006, 55, 1199-1207.https://doi.org/10.1002/pi.1985
dc.relation.urihttps://doi.org/10.1016/j.polymer.2004.08.002
dc.relation.urihttps://doi.org/10.1016/S0167-577X(03)00524-X
dc.relation.urihttps://doi.org/10.1016/S0167-577X(00)00318-9
dc.relation.urihttps://doi.org/10.1016/j.jcis.2008.06.035
dc.relation.urihttps://doi.org/10.1016/j.desal.2008.06.012
dc.relation.urihttps://doi.org/10.1002/marc.200800720
dc.relation.urihttps://doi.org/10.1002/pi.1045
dc.relation.urihttps://doi.org/10.23939/chcht05.02.191
dc.relation.urihttps://doi.org/10.23939/chcht13.04.451
dc.relation.urihttps://doi.org/10.23939/chcht05.04.433
dc.relation.urihttps://doi.org/10.1002/marc.200300035
dc.relation.urihttps://doi.org/10.1016/S0079-6700(02)00019-9
dc.relation.urihttps://doi.org/10.1007/s11164-013-1310-1
dc.relation.urihttps://doi.org/10.1002/masy.201400004
dc.relation.urihttps://doi.org/10.1016/S0014-3057(02)00221-5
dc.relation.urihttps://doi.org/10.1163/156855500750198726
dc.relation.urihttps://doi.org/10.1002/pi.1985
dc.rights.holder© Національний університет “Львівська політехніка”, 2023
dc.rights.holder© Dergal F., Lerari D., Bachari Kh., 2023
dc.subjectслюда
dc.subject4-вінілпіридин (4VP)
dc.subjectспонтанна полімеризація
dc.subjectкомпозит
dc.subjectmica
dc.subject4-vinylpyridine (4VP)
dc.subjectspontaneous polymerization
dc.subjectcomposite
dc.titleSpontaneous Polymerization of 4-Vinylpyridine Monomer on Micron-Sized Mica Platelets
dc.title.alternativeСпонтанна полімеризація мономеру 4-вінілпіридину на плитах слюди мікронного розміру
dc.typeArticle

Files

Original bundle

Now showing 1 - 2 of 2
Thumbnail Image
Name:
2023v17n4_Dergal_F-Spontaneous_Polymerization_800-806.pdf
Size:
864.15 KB
Format:
Adobe Portable Document Format
Download
Thumbnail Image
Name:
2023v17n4_Dergal_F-Spontaneous_Polymerization_800-806__COVER.png
Size:
555.22 KB
Format:
Portable Network Graphics
Download

License bundle

Now showing 1 - 1 of 1
Thumbnail Image
Name:
license.txt
Size:
1.78 KB
Format:
Plain Text
Description:
Download

Collections

Chemistry & Chemical Technology. – 2023. – Vol. 17, No. 4