Thermophysical Properties of Composite Metal-Filled Copolymers of Polyvinylpyrrolidone

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dc.citation.epage43
dc.citation.issue1
dc.citation.journalTitleХімія та хімічна технологія
dc.citation.spage37
dc.citation.volume18
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.affiliationTechnical University of Kosice
dc.contributor.authorGrytsenko, Oleksandr
dc.contributor.authorMykhaylo Bratychak Jr.
dc.contributor.authorDulebova, Ludmila
dc.contributor.authorGajdoš, Ivan
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2025-09-24T06:19:58Z
dc.date.created2024-03-01
dc.date.issued2024-03-01
dc.description.abstractДосліджено вплив присутності дрібнодисперсних металевих наповнювачів різної природи (Zn, Co, Ni) на теплофізичні характеристики (теплостійкість за Віка, температура склування) блочних кополімерів полівінілпіролідону з 2-гідроксіетилметакрилатом. Встановлено, що теплостійкість одержаних композитів є значно вищою за теплостійкість ненаповнених кополімерів і лежить у межах 360-395К залежно від природи та вмісту металевого наповнювача. Зміна теплостійкості корелює зі зміною температури склування, яку оцінювали на основі результатів термомеханічного та динамічного механічного термічного аналізів. Результати роботи є додатковим джерелом характеристики структури металонаповнених кополімерів і підтверджують участь частинок металевого наповнювача у формуванні вузлів просторової сітки кополімеру, а також доводять факт утворення різної структури полімерної сітки в міжфазному шарі на поверхні металевої частинки і в об’ємі полімеру.
dc.description.abstractThe effect of the presence of finely dispersed metal fillers of various natures (Zn, Co, Ni) on the thermophysical characteristics (Vick heat resistance, glass transition temperature) of polyvinylpyrrolidone block copolymers with 2-hydroxyethylmethacrylate was studied. It was found that the heat resistance of the obtained composites significantly exceeds the heat resistance of unfilled copolymers and is in the range of 360-395K, depending on the nature and content of the metal filler. The change in heat resistance correlates with the change in glass transition temperature, which was evaluated according to the results of thermomechanical and dynamic mechanical thermal analyses. The results of this work are an additional source to characterize the structure of metal-filled copolymers: they confirm the participation of metal filler particles in the formation of the nodes of the copolymer spatial network, and also prove the formation of a different polymer network structure in the interfacial layer on the surface of the metal particle and in the polymer volume.
dc.format.extent37-43
dc.format.pages7
dc.identifier.citationThermophysical Properties of Composite Metal-Filled Copolymers of Polyvinylpyrrolidone / Oleksandr Grytsenko, Mykhaylo Bratychak Jr., Ludmila Dulebova, Ivan Gajdoš // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2024. — Vol 18. — No 1. — P. 37–43.
dc.identifier.citationenThermophysical Properties of Composite Metal-Filled Copolymers of Polyvinylpyrrolidone / Oleksandr Grytsenko, Mykhaylo Bratychak Jr., Ludmila Dulebova, Ivan Gajdoš // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2024. — Vol 18. — No 1. — P. 37–43.
dc.identifier.doidoi.org/10.23939/chcht18.01.037
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/111782
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofХімія та хімічна технологія, 1 (18), 2024
dc.relation.ispartofChemistry & Chemical Technology, 1 (18), 2024
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dc.rights.holder© Національний університет “Львівська політехніка”, 2024
dc.rights.holder© Grytsenko O., Bratychak Jr. M., Dulebova L., Gajdoš I., 2024
dc.subjectполівінілпіролідон
dc.subject2-гідроксіетилметакрилат
dc.subjectкополімери
dc.subjectметалонаповнені полімери
dc.subjectтеплостійкість
dc.subjectтемпература склування
dc.subjectpolyvinylpyrrolidone
dc.subject2-hydroxyethylmethacrylate
dc.subjectcopolymers
dc.subjectmetal-filled polymers
dc.subjectheat resistance
dc.subjectglass transition temperature
dc.titleThermophysical Properties of Composite Metal-Filled Copolymers of Polyvinylpyrrolidone
dc.title.alternativeТеплофізичні властивості композиційних металонаповнених кополімерів полівінілпіролідону
dc.typeArticle

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Chemistry & Chemical Technology. – 2024. – Vol. 18, No. 1