Synthesis and Study of Properties of Geopolymer Materials Developed Using Local Natural Raw Materials and Industrial Waste

dc.citation.epage718
dc.citation.issue4
dc.citation.spage711
dc.contributor.affiliationIvane Javakhishvili Tbilisi State University
dc.contributor.authorShapakidze, Elena
dc.contributor.authorAvaliani, Marina
dc.contributor.authorNadirashvili, Marina
dc.contributor.authorMaisuradze, Vera
dc.contributor.authorGejadze, Ioseb
dc.contributor.authorPetriashvili, Tamar
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2025-03-05T08:54:08Z
dc.date.created2023-02-28
dc.date.issued2023-02-28
dc.description.abstractОписано синтез геополімерних матеріалів з використанням термомодифікованих глинистих порід Грузії та металургійного гранульованого доменного шлаку, а також дослідження їхніх фізико-механічних властивостей, довговічності та корозійної стійкості в агресивних розчинах. Використано методи хімічного, рентгенофазового, диференційно-термічного аналізу та сканувальної електронної мікроскопії.
dc.description.abstractThis paper describes the synthesis of geopolymer materials using thermally modified clay rocks of Georgia and metallurgical granulated blast-furnace slag; as well as the study of their physical and mechanical properties, durability, and corrosion resistance in aggressive solutions.The methods of chemical, X-ray phase, differential thermal analysis and SEM were used.
dc.format.extent711-718
dc.format.pages8
dc.identifier.citationSynthesis and Study of Properties of Geopolymer Materials Developed Using Local Natural Raw Materials and Industrial Waste / Elena Shapakidze, Marina Avaliani, Marina Nadirashvili, Vera Maisuradze, Ioseb Gejadze, Tamar Petriashvili // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2023. — Vol 17. — No 4. — P. 711–718.
dc.identifier.citationenSynthesis and Study of Properties of Geopolymer Materials Developed Using Local Natural Raw Materials and Industrial Waste / Elena Shapakidze, Marina Avaliani, Marina Nadirashvili, Vera Maisuradze, Ioseb Gejadze, Tamar Petriashvili // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2023. — Vol 17. — No 4. — P. 711–718.
dc.identifier.doidoi.org/10.23939/chcht17.04.711
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/63688
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 4 (17), 2023
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dc.relation.references[4] Avaliani, M.; Chagelishvili, V.; Shapakidze, E.; Gvelesiani, M.; Barnovi, N.; Kveselava, V.; Esakia, N. Crystallization Fields of Condensed Scandium and Silver Phosphates and Regularities of Their Formation. European Chemical Bulletin2019, 8, 164–170.
dc.relation.references[5] Purbasari, A.; Ariyanti, D.; Sumardiono, S.; Khairunnisa, K.; Sidharta, T. Adsorption Kinetics and Isotherms of Cu(II) and Fe(II) Ions from Aqueous Solutions by Fly Ash-Based Geopolymer. Chem. Chem. Technol.2022, 16, 169–176. https://doi.org/10.23939/chcht16.02.169
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dc.relation.references[7] Glukhovsky, V.D.;Krivenko, P.V.;Ryumina, P.V.;Gerasimchuk, V.L. Production of Concrete and Structures Based on Slag-Alkali Binders;Budivelnik: Kiev, 1988.
dc.relation.references[8] Krivenko, P. Alkaline Cements. In Proceedings of the First International Conference on Alkaline Cements and Concrete; VIPOL Stock Company: Kiev, 1994;pp 11–129.
dc.relation.references[9] Krivenko, P.V. Special Alkaline Cements;Budivelnyk: Kiev,1995.
dc.relation.references[10] Krivenko, P. Review. Why Alkaline Activation – 60 Years of the Theory and Practice of Alkali-Activated Materials. J. Ceram. Sci.Technol. 2017,08, 323–334. https://doi.org/10.4416/JCST2017-00042
dc.relation.references[11] Davidovits, J. Soft Mineralurgy and Geopolymers. InProc. of Geopolymer 88 – Conference Internationale, Université de Technologie;Compiègne, France,1988; pp 49–56.
dc.relation.references[12] Davidovits, J. Carbon-Dioxide Greenhouse-Warming: What Future for Portland Cement. In Proceedings, Emerging Technologies Symposium on Cement and Concretes in the Global Environment; Portland Cement Association: Chicago, Illinois, 1993; pp1–21.
dc.relation.references[13] Duxon,P.;Fernández-Jiménez, A.; Provis, J.L.; Lukey, G.C.; Palomo A.; van Deventer, J.S.J. GeopolymerTechnology: The Current State of the Art. J. Mater. Sci.2007, 42, 2917–2933. https://doi.org/10.1007/s10853-006-0637-z
dc.relation.references[14] Palomo, A.;Grutzeck, M.W.;Blanco, M.T. Alkali-Activated fly Ash Cement for Future. CemConcr Res1999,29,1323–1329. https://doi.org/10.1016/S0008-8846(98)00243-9
dc.relation.references[15] Palomo, A.; Krivenko, P.; Garcia-Lodeiro, I.; Kavalerova, E.; Maltseva, O.; Fernández-Jiménez, A. A Review on Alkaline Activation: New Analytical Perspectives.Mater. deConstruccion2014, 64, 022.
dc.relation.references[16] Shapakidze, E.; Nadirashvili, M.; Maisuradze, V.; Gejadze, I.; Avaliani, M.; Todradze, G. Elaboration of Optimal Mode for Heat Treatment of Shales for Obtaining Metakaolin. European Chemical Bulletin2019,8, 31–33.
dc.relation.references[17] Shapakidze, E.; Avaliani, M.; Nadirashvili, M.; Maisuradze, V.; Gejadze, I.; Petriashvili, T. Obtaining of Geopolymer Binders Based on Thermally Modified Clay Rocks of Georgia. Nano Studies2020, 20, 43–52. http://dx.doi.org/10.13140/RG.2.2.18756.17281
dc.relation.references[18] Shapakidze, E.; Avaliani, M.; Nadirashvili, M.; Maisuradze, V.; Gejadze, I.; Petriashvili, T.GeopolymersBased on Local Rocks as a Future Alternative to Portland Cement. In Advanced Materials, Polymers, and Composites: New Research on Properties, Techniques, and Applications; Apple Acad. Press: USA, 2020, 3;pp 351–358. http://dx.doi.org/10.13140/RG.2.2.28081.12644
dc.relation.references[19] Fernando, P.T.; Said, J. Retraction Note: Resistance to Acid Attack, Abrasion and Leaching Behavior of Alkali-Activated Mine Waste Binders.Mater Struct2021, 54,154. https://doi.org/10.1617/s11527-021-01738-2
dc.relation.references[20] Bakharev, T. Resistance of Geopolymer Materials to Acid Attack. CemConcr Res2005, 35, 658–670. https://doi.org/10.1016/j.cemconres.2004.06.005
dc.relation.references[21] Hewlett, P.C. Lea’s Chemistry of Cement Concrete, third ed.; John Wily and Sons, Inc.: New York, 1998.
dc.relation.references[22] Palomo, A.; Blanco-Varela, M.T.; Granizo, M.L.; Puertas, F.; Vazquez, T.;Grutzeck, M.W. Chemical Stability of Cementitious Materials Based on Metakaolin. CemConcr Res1999,29, 997–1004. https://doi.org/10.1016/S0008-8846(99)00074-5
dc.relation.references[23] Shaikh, F.U.A. Effects of Alkali Solutions on Corrosion Durability of Geopolymer Concrete.Adv. Cem. Res. 2014, 2(2).109–123. https://doi.org/10.12989/acc.2014.2.2.109
dc.relation.references[24] Bankharev, T. Durability of Geopolymer Materials in Sodium and Magnesium Sulfate Solutions. CemConcr Res2005,35, 1233–1246. https://doi.org/10.1016/j.cemconres.2004.09.002
dc.relation.references[25] Kim, Y.Y.; Lee, B.J.; Saraswathy, V.; Kwon, S.J. Strength and Durability Performance of Alkali-Activated Rice Husk Ash Geopolymer Mortar. Sci. World. J. 2014,2014,209584. https://doi.org/10.1155/2014/209584
dc.relation.references[26] Lingyu, T.; Dongpo, H.; Jianing, Zh.;Hongguang, W. Durability of Geopolymersand Geopolymer Concretes: A Review. Rev. Adv. Mater. Sci. 2021,60, 1–14. https://doi.org/10.1515/rams-2021-0002
dc.relation.referencesen[1] Levytska, O.;Dolzhenkova, O.; Sichevyi, O.;Dorhanova, L. Masonry Unit Manufacturing Technology Using Polymeric Binder.Chem. Chem. Technol.2020, 14, 88–92. https://doi.org/10.23939/chcht14.01.088
dc.relation.referencesen[2] Savvova, O.; Voronov, H.; Fesenko, O.; Riabinin, S.; Tymofieiev, V. High-Strength Glass-Ceramic Material With Low Temperature Formation. Chem. Chem. Technol. 2022, 16, 337–344. https://doi.org/10.23939/chcht16.02.337
dc.relation.referencesen[3] Shapoval, S.; Shapoval, P; Zhelykh, V.; Pona, O.; Spodyniuk, N.; Gulai, B.; Savchenko, O.; Myroniuk, K. Ecological and Energy Aspects of Using the Combined Solar Collectors for Low-Energy Houses. Chem. Chem. Technol. 2017, 11, 503–508. https://doi.org/10.23939/chcht11.04.503
dc.relation.referencesen[4] Avaliani, M.; Chagelishvili, V.; Shapakidze, E.; Gvelesiani, M.; Barnovi, N.; Kveselava, V.; Esakia, N. Crystallization Fields of Condensed Scandium and Silver Phosphates and Regularities of Their Formation. European Chemical Bulletin2019, 8, 164–170.
dc.relation.referencesen[5] Purbasari, A.; Ariyanti, D.; Sumardiono, S.; Khairunnisa, K.; Sidharta, T. Adsorption Kinetics and Isotherms of Cu(II) and Fe(II) Ions from Aqueous Solutions by Fly Ash-Based Geopolymer. Chem. Chem. Technol.2022, 16, 169–176. https://doi.org/10.23939/chcht16.02.169
dc.relation.referencesen[6] Glukhovsky, V.D. Soil Silicates;Gosstroyizdat: Kiev,1959.
dc.relation.referencesen[7] Glukhovsky, V.D.;Krivenko, P.V.;Ryumina, P.V.;Gerasimchuk, V.L. Production of Concrete and Structures Based on Slag-Alkali Binders;Budivelnik: Kiev, 1988.
dc.relation.referencesen[8] Krivenko, P. Alkaline Cements. In Proceedings of the First International Conference on Alkaline Cements and Concrete; VIPOL Stock Company: Kiev, 1994;pp 11–129.
dc.relation.referencesen[9] Krivenko, P.V. Special Alkaline Cements;Budivelnyk: Kiev,1995.
dc.relation.referencesen[10] Krivenko, P. Review. Why Alkaline Activation – 60 Years of the Theory and Practice of Alkali-Activated Materials. J. Ceram. Sci.Technol. 2017,08, 323–334. https://doi.org/10.4416/JCST2017-00042
dc.relation.referencesen[11] Davidovits, J. Soft Mineralurgy and Geopolymers. InProc. of Geopolymer 88 – Conference Internationale, Université de Technologie;Compiègne, France,1988; pp 49–56.
dc.relation.referencesen[12] Davidovits, J. Carbon-Dioxide Greenhouse-Warming: What Future for Portland Cement. In Proceedings, Emerging Technologies Symposium on Cement and Concretes in the Global Environment; Portland Cement Association: Chicago, Illinois, 1993; pp1–21.
dc.relation.referencesen[13] Duxon,P.;Fernández-Jiménez, A.; Provis, J.L.; Lukey, G.C.; Palomo A.; van Deventer, J.S.J. GeopolymerTechnology: The Current State of the Art. J. Mater. Sci.2007, 42, 2917–2933. https://doi.org/10.1007/s10853-006-0637-z
dc.relation.referencesen[14] Palomo, A.;Grutzeck, M.W.;Blanco, M.T. Alkali-Activated fly Ash Cement for Future. CemConcr Res1999,29,1323–1329. https://doi.org/10.1016/S0008-8846(98)00243-9
dc.relation.referencesen[15] Palomo, A.; Krivenko, P.; Garcia-Lodeiro, I.; Kavalerova, E.; Maltseva, O.; Fernández-Jiménez, A. A Review on Alkaline Activation: New Analytical Perspectives.Mater. deConstruccion2014, 64, 022.
dc.relation.referencesen[16] Shapakidze, E.; Nadirashvili, M.; Maisuradze, V.; Gejadze, I.; Avaliani, M.; Todradze, G. Elaboration of Optimal Mode for Heat Treatment of Shales for Obtaining Metakaolin. European Chemical Bulletin2019,8, 31–33.
dc.relation.referencesen[17] Shapakidze, E.; Avaliani, M.; Nadirashvili, M.; Maisuradze, V.; Gejadze, I.; Petriashvili, T. Obtaining of Geopolymer Binders Based on Thermally Modified Clay Rocks of Georgia. Nano Studies2020, 20, 43–52. http://dx.doi.org/10.13140/RG.2.2.18756.17281
dc.relation.referencesen[18] Shapakidze, E.; Avaliani, M.; Nadirashvili, M.; Maisuradze, V.; Gejadze, I.; Petriashvili, T.GeopolymersBased on Local Rocks as a Future Alternative to Portland Cement. In Advanced Materials, Polymers, and Composites: New Research on Properties, Techniques, and Applications; Apple Acad. Press: USA, 2020, 3;pp 351–358. http://dx.doi.org/10.13140/RG.2.2.28081.12644
dc.relation.referencesen[19] Fernando, P.T.; Said, J. Retraction Note: Resistance to Acid Attack, Abrasion and Leaching Behavior of Alkali-Activated Mine Waste Binders.Mater Struct2021, 54,154. https://doi.org/10.1617/s11527-021-01738-2
dc.relation.referencesen[20] Bakharev, T. Resistance of Geopolymer Materials to Acid Attack. CemConcr Res2005, 35, 658–670. https://doi.org/10.1016/j.cemconres.2004.06.005
dc.relation.referencesen[21] Hewlett, P.C. Lea’s Chemistry of Cement Concrete, third ed.; John Wily and Sons, Inc., New York, 1998.
dc.relation.referencesen[22] Palomo, A.; Blanco-Varela, M.T.; Granizo, M.L.; Puertas, F.; Vazquez, T.;Grutzeck, M.W. Chemical Stability of Cementitious Materials Based on Metakaolin. CemConcr Res1999,29, 997–1004. https://doi.org/10.1016/S0008-8846(99)00074-5
dc.relation.referencesen[23] Shaikh, F.U.A. Effects of Alkali Solutions on Corrosion Durability of Geopolymer Concrete.Adv. Cem. Res. 2014, 2(2).109–123. https://doi.org/10.12989/acc.2014.2.2.109
dc.relation.referencesen[24] Bankharev, T. Durability of Geopolymer Materials in Sodium and Magnesium Sulfate Solutions. CemConcr Res2005,35, 1233–1246. https://doi.org/10.1016/j.cemconres.2004.09.002
dc.relation.referencesen[25] Kim, Y.Y.; Lee, B.J.; Saraswathy, V.; Kwon, S.J. Strength and Durability Performance of Alkali-Activated Rice Husk Ash Geopolymer Mortar. Sci. World. J. 2014,2014,209584. https://doi.org/10.1155/2014/209584
dc.relation.referencesen[26] Lingyu, T.; Dongpo, H.; Jianing, Zh.;Hongguang, W. Durability of Geopolymersand Geopolymer Concretes: A Review. Rev. Adv. Mater. Sci. 2021,60, 1–14. https://doi.org/10.1515/rams-2021-0002
dc.relation.urihttps://doi.org/10.23939/chcht14.01.088
dc.relation.urihttps://doi.org/10.23939/chcht16.02.337
dc.relation.urihttps://doi.org/10.23939/chcht11.04.503
dc.relation.urihttps://doi.org/10.23939/chcht16.02.169
dc.relation.urihttps://doi.org/10.4416/JCST2017-00042
dc.relation.urihttps://doi.org/10.1007/s10853-006-0637-z
dc.relation.urihttps://doi.org/10.1016/S0008-8846(98)00243-9
dc.relation.urihttp://dx.doi.org/10.13140/RG.2.2.18756.17281
dc.relation.urihttp://dx.doi.org/10.13140/RG.2.2.28081.12644
dc.relation.urihttps://doi.org/10.1617/s11527-021-01738-2
dc.relation.urihttps://doi.org/10.1016/j.cemconres.2004.06.005
dc.relation.urihttps://doi.org/10.1016/S0008-8846(99)00074-5
dc.relation.urihttps://doi.org/10.12989/acc.2014.2.2.109
dc.relation.urihttps://doi.org/10.1016/j.cemconres.2004.09.002
dc.relation.urihttps://doi.org/10.1155/2014/209584
dc.relation.urihttps://doi.org/10.1515/rams-2021-0002
dc.rights.holder© Національний університет “Львівська політехніка”, 2023
dc.rights.holder© Shapakidze E., Avaliani M., Nadirashvili M., Maisuradze V., Gejadze I., Petriashvili T., 2023
dc.subjectгеополімер
dc.subjectтермічно модифікована глиниста порода
dc.subjectдовговічність
dc.subjectагресивний розчин
dc.subjectкорозійна стійкість
dc.subjectgeopolymer
dc.subjectthermally modified clay rock
dc.subjectdurability
dc.subjectaggressive solution
dc.subjectcorrosion resistance
dc.titleSynthesis and Study of Properties of Geopolymer Materials Developed Using Local Natural Raw Materials and Industrial Waste
dc.title.alternativeСинтез і дослідження властивостей геополімерних матеріалів, одержаних з використанням місцевої природної сировини та промислових відходів
dc.typeArticle

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