Трансестерифікація тригліцеридів соняшникової олії аліфатичними спиртами С1–С4

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dc.citation.epage104
dc.citation.issue1
dc.citation.spage99
dc.contributor.affiliationНаціональний університет “Львівська політехніка”
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.authorМельник, Ю. Р.
dc.contributor.authorМельник, С. Р.
dc.contributor.authorБезділь, В. В.
dc.contributor.authorМагорівська, Г. Я.
dc.contributor.authorMelnyk, Yu. R.
dc.contributor.authorMelnyk, S. R.
dc.contributor.authorBezdil, V. V.
dc.contributor.authorMahorivska, H. Ya.
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2024-01-22T08:14:41Z
dc.date.available2024-01-22T08:14:41Z
dc.date.created2021-03-16
dc.date.issued2021-03-16
dc.description.abstractДосліджено закономірності трансестерифікації тригліцеридів соняшникової олії аліфатичними спиртами С1–С4 у присутності катіоніту КУ-2-8 із іммобілізованими іонами двовалентних металів. Встановлено, що реакція відбувається із високою початковою швидкістю, а конверсія олії в перерахунку на тригліцериди під час їх трансестерифікації аліфатичними спиртами С1–С3 за 180 хв досягає 88,4–99,8 %. Показано що швидкість реакції трансестерифікації тригліцеридів бутан-1-олом істотно нижчі, а конверсія, що досягається за 180 хв, не перевищує 52,3 %
dc.description.abstractTransesterification of sunflower oil triglycerides by C1-C4 aliphatic alcohols in the presence of cation exchange resin KU-2-8 with immobilized divalent metal ions has been studied. It was found that the reaction occurs at a high initial rate and the conversion of triglycerides for 180 min in presence aliphatic alcohols C1– C3 is 88.4–99.8 %. It isshown that under these conditionsthe rate of transesterification reaction of triglycerides with butan-1-ol is significantly lower and the conversion achieved in 180 min does not exceed 52.3 %.
dc.format.extent99-104
dc.format.pages6
dc.identifier.citationТрансестерифікація тригліцеридів соняшникової олії аліфатичними спиртами С1–С4 / Ю. Р. Мельник, С. Р. Мельник, В. В. Безділь, Г. Я. Магорівська // Chemistry, Technology and Application of Substances. — Львів : Видавництво Львівської політехніки, 2021. — Том 4. — № 1. — С. 99–104.
dc.identifier.citationenTransesterification of sunflower oil’s triglycerides by aliphatic alcohols С1–С4 / Yu. R. Melnyk, S. R. Melnyk, V. V. Bezdil, H. Ya. Mahorivska // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2021. — Vol 4. — No 1. — P. 99–104.
dc.identifier.doidoi.org/10.23939/ctas2021.01.099
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/60843
dc.language.isouk
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry, Technology and Application of Substances, 1 (4), 2021
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dc.relation.references14. Melnyk, Y., Melnyk, S., Palyukh, Z., & Dzinyak, B. (2018). Research into transesterification of triglycerides by aliphatic alcohols C2–C4 in the presence of ionites. Eastern-European Journal of Enterprise Technologies, 1/6 (91), 10–16. doi:10.15587/ 1729-4061.2018.122938.
dc.relation.references15. Melnyk, Y., Paljuh, Z., & Melnyk, S. (2015). Alkoholiz tryhlitserydiv etanolom u prysutnosti kationitu KU-2-8, modyfikovanoho ionamy metaliv. Visnyk Skhidnoukrainskoho Natsionalnoho universytetu im. Volodymyra Dalia, 3 (220), 78–82.
dc.relation.references16. Melnyk, Y., Melnyk, S., & Paljuh, Z. (2016). The effect of parameters on the transesterification process of sunflower oil with ethanol. Bulletin of the National Technical University “KhPI” Series: New Solutions in Modern Technologies, 12 (1184), 163–168. doi:10.20998/2413-4295.2016.12.24.
dc.relation.references17. Melnyk, Yu. R., Tierin, A. A. & Melnyk, S. R. (2020). Porivniannia aktyvnosti oksydiv metaliv u reaktsiitransesteryfikatsii tryhlitserydiv spyrtamy C1–C4. Voprosy khimii i khimicheskoi tekhnologii, 2020, 6, 99–105. doi: 10.32434/0321-4095-2020-133-6-99-105.
dc.relation.referencesen1. Singh, S., & Singh, D. (2010). Biodiesel production through the use of different sources and characterization of oils and their esters as the substitute of diesel: A review. Renewable and Sustainable Energy Reviews, 14(1), 200–216. doi:10.1016/j.rser.2009.07.017.
dc.relation.referencesen2. Ejikeme, P. M., Anyaogu, I. D., Ejikeme, C. L., Nwafor, N. P., Egbuonu, C. A., Ukogu, K., & Ibemesi, J. A. (2010). Catalysisin Biodiesel Production by Transesterification Processes-An Insight. E-Journal of Chemistry, 7(4), 1120–1132. doi:10.1155/2010/689051.
dc.relation.referencesen3. Demirbas, A. (2003). Biodiesel fuels from vegetable oils via catalytic and non-catalytic supercritical alcohol transesterifications and other methods: a survey. Energy Conversion and Management, 44, 2093–2109. doi:10.1016/S0196-8904(02)00234-0.
dc.relation.referencesen4. Patryliak, Zubenko S. O., Konovalov S. V. (2018). Pereesteryfikatsiia ripakovoi olii butanolom na luzhnykh katalizatorakh. Voprosy khimii i khimicheskoi tekhnologii, 5, 125–130. Retrieved from: http://vhht.dp.ua/wp-content/uploads/pdf/2018/5/Patrylak.pdf.
dc.relation.referencesen5. Zubenko, S. O., Patryliak, L. K., Yakovenko, A. V. & Konovalov, S. V. (2016). Pereesteryfikatsiia soniashnykovoi olii butanolom. Kataliz i neftekhymyia, 25, 90–92. Retrieved from: http://kataliz.org.ua/arhiv/25/25_2016_15.pdf.
dc.relation.referencesen6. Balat, M. & Balat, H. (2010). Progress in biodiesel processing. Applied Energy, 87, 1815–1835. doi:10.1016/j.apenergy.2010.01.012.
dc.relation.referencesen7. Alptekin, E., & Canakci, M. (2011). Optimization of transesterification for methyl ester production from chicken fat. Fuel, 90(8), 2630–2638. doi:10.1016/j.fuel.2011.03.042.
dc.relation.referencesen8. Ribun, V., Kurta, S., Gromovy, T., & Khatsevich, O. (2019). Improving the Technology Synthesis and Properties of Biodiesel. Physics and Chemistry of Solid State, 19(3), 258–269. doi:10.15330/pcss.19.3.258-269.
dc.relation.referencesen9. Becerra Ortega, Mónica, Centeno Hurtado, Aristóbulo, & Giraldo Duarte, Sonia Azucena. (2011). Triglyceride transesterification in heterogeneous reaction system with calcium oxide as catalyst. Revista Facultad de Ingeniería Universidad de Antioquia, (57), 7–13. Retrieved January 28, 2021, from http://www.scielo.org.co/scielo.php?script=sci_arttext&pid=S0120-62302011000100001&lng=en&tlng=en.
dc.relation.referencesen10. Tan, Y. H., Abdullah, M. O., & Hipolito, C. N. (2016). Comparison of Biodiesel Production between Homogeneous and Heterogeneous Base Catalysts. Applied Mechanics and Materials, 833, 71–77. doi:10.4028/www.scientific.net/amm.833.71.
dc.relation.referencesen11. Marchetti, J. M., & Errazu, A. F. (2010). Biodiesel production from acid oils and ethanol using a solid basic resin as catalyst. Biomass and Bioenergy, 34(3), 272–277. doi:10.1016/j.biombioe.2009.10.016.
dc.relation.referencesen12. Einloft, S., Magalhães, T. O., Donato, A., Dullius, J., & Ligabue, R. (2008). Biodiesel from Rice Bran Oil: Transesterification by Tin Compounds. Energy & Fuels, 22(1), 671–674. doi:10.1021/ef700510a.
dc.relation.referencesen13. Brucato A., Busciglio A., Di Stefano F., Grisafi F., Micale G., & Scargiali F. (2010). High Temperature Solidcatalized Transesterification for Biodiesel Production, Chemical Engineering Transactions, 19, 31–36. doi: 10.3303/CET1019006.
dc.relation.referencesen14. Melnyk, Y., Melnyk, S., Palyukh, Z., & Dzinyak, B. (2018). Research into transesterification of triglycerides by aliphatic alcohols P.2–P.4 in the presence of ionites. Eastern-European Journal of Enterprise Technologies, 1/6 (91), 10–16. doi:10.15587/ 1729-4061.2018.122938.
dc.relation.referencesen15. Melnyk, Y., Paljuh, Z., & Melnyk, S. (2015). Alkoholiz tryhlitserydiv etanolom u prysutnosti kationitu KU-2-8, modyfikovanoho ionamy metaliv. Visnyk Skhidnoukrainskoho Natsionalnoho universytetu im. Volodymyra Dalia, 3 (220), 78–82.
dc.relation.referencesen16. Melnyk, Y., Melnyk, S., & Paljuh, Z. (2016). The effect of parameters on the transesterification process of sunflower oil with ethanol. Bulletin of the National Technical University "KhPI" Series: New Solutions in Modern Technologies, 12 (1184), 163–168. doi:10.20998/2413-4295.2016.12.24.
dc.relation.referencesen17. Melnyk, Yu. R., Tierin, A. A. & Melnyk, S. R. (2020). Porivniannia aktyvnosti oksydiv metaliv u reaktsiitransesteryfikatsii tryhlitserydiv spyrtamy P.1–P.4. Voprosy khimii i khimicheskoi tekhnologii, 2020, 6, 99–105. doi: 10.32434/0321-4095-2020-133-6-99-105.
dc.relation.urihttp://vhht.dp.ua/wp-content/uploads/pdf/2018/5/Patrylak.pdf
dc.relation.urihttp://kataliz.org.ua/arhiv/25/25_2016_15.pdf
dc.relation.urihttp://www.scielo.org.co/scielo.php?script=sci_arttext&pid=S0120-62302011000100001&lng=en&tlng=en
dc.rights.holder© Національний університет “Львівська політехніка”, 2021
dc.subjectтрансестерифікація
dc.subjectаліфатичні спирти
dc.subjectтригліцериди
dc.subjectсоняшникова олія
dc.subjectкатіони двовалентних металів
dc.subjectкатіоніт
dc.subjecttransesterification
dc.subjectaliphatic alcohols
dc.subjecttriglycerides
dc.subjectsunflower oil
dc.subjectdivalent metal cations
dc.subjectcatione exchange resine
dc.titleТрансестерифікація тригліцеридів соняшникової олії аліфатичними спиртами С1–С4
dc.title.alternativeTransesterification of sunflower oil’s triglycerides by aliphatic alcohols С1–С4
dc.typeArticle

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Chemistry, Technology and Application of Substances. – 2021. – Vol. 4, No. 1