Bamboo-Containing Composites with Environmentally Friendly Binders

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dc.citation.epage819
dc.citation.issue4
dc.citation.spage807
dc.contributor.affiliationIvane Javakhishvili’ Tbilisi State University
dc.contributor.affiliationSokhumi State University
dc.contributor.affiliationVladimir Chavchanidze Institute of Cybernetics of the Georgian Technical University
dc.contributor.authorMukbaniani, Omar
dc.contributor.authorTatrishvili, Tamara
dc.contributor.authorKvnikadze, Nikoloz
dc.contributor.authorBukia, Tinatini
dc.contributor.authorPirtskheliani, Nana
dc.contributor.authorMakharadze, Tamar
dc.contributor.authorPetriashvili, Gia
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2025-03-05T08:54:09Z
dc.date.created2023-02-28
dc.date.issued2023-02-28
dc.description.abstractУперше синтезовано екологічно чисту в'яжучу речовину– полі[(триметокси)4-вінілфенетил)]силан за допомогою реакції алкілування Фріделя-Крафтса, яку проводили взаємодією полістирену з вінілтриметоксисиланом у присутності безводного AlCl3. Синтезований полімер було ідентифіковано за допомогою 1H, 13C, 1H COSY ЯМР і FTIR спектроскопії. Композити на основі бамбукової тирси з різними дисперсійними властивостями були створені з використанням синтетичного триметоксисилільованогополістирену (TMSPSt) та стирену з різним ступенем силілювання (5-10%). Композиційні матеріали на основі бамбукового порошку з різними органічними/неорганічними добавками, антипіренамий антиоксидантами були оброблені за різних температур і тисків методом гарячого пресування. Отримані композити досліджували методами інфрачервоної спектроскопії з перетворенням Фур'є (FTIR), оптичної та растрової електронної мікроскопії (SEM), а також енергодисперсійної рентгенівської спектроскопії (EDS). Термостабільність отриманих матеріалів визначали за допомогою термогравіметрії та методу Віка. Також досліджено водопоглинання та деякі механічні властивості.
dc.description.abstractThe environmentally friendly binder - poly[(trimethoxy)4-vinylphenethyl)] silane was synthesized for the first time via Friedel-Crafts alkylation reaction, which was conducted by the reaction of polystyrene with vinyltrimethoxysilane in the presence of anhydrous AlCl3.The synthesized polymer was identified using 1H, 13C, 1H COSY NMR, and FTIR spectroscopy. Bamboo sawdust-based composites with various dispersion properties have been created using synthetic trimethoxysilylated polystyrene (TMSPSt) and styrenewith various degrees of silylation (5-10%). Composite materialsbased on bamboo powder with various organic/inorganic additives, flame retardants, and antioxidants, were processed at different temperatures and pressures using the hot pressing method. Obtained compositeswere studied by Fourier transformation infrared spectroscopy (FTIR), optical and scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDS). Thermal stability of the obtained materials was determined by thermogravimetry and the Vicat method. Also, water absorption and some mechanical properties were studied.
dc.format.extent807-819
dc.format.pages13
dc.identifier.citationBamboo-Containing Composites with Environmentally Friendly Binders / Omar Mukbaniani, Tamara Tatrishvili, Nikoloz Kvnikadze, Tinatini Bukia, Nana Pirtskheliani, Tamar Makharadze, Gia Petriashvili // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2023. — Vol 17. — No 4. — P. 807–819.
dc.identifier.citationenBamboo-Containing Composites with Environmentally Friendly Binders / Omar Mukbaniani, Tamara Tatrishvili, Nikoloz Kvnikadze, Tinatini Bukia, Nana Pirtskheliani, Tamar Makharadze, Gia Petriashvili // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2023. — Vol 17. — No 4. — P. 807–819.
dc.identifier.doidoi.org/10.23939/chcht17.04.807
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/63691
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 4 (17), 2023
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dc.rights.holder© Національний університет “Львівська політехніка”, 2023
dc.rights.holder© Mukbaniani O., Tatrishvili N., Kvnikadze N., Bukia T., Pirtskheliani N., Makharadze T., Petriashvili G., 2023
dc.subjectреакція Фріделя-Крафтса
dc.subjectсилільований полістирен
dc.subjectантипірен
dc.subjectбамбуковий порошок
dc.subjectFTIR і ЯМР спектроскопія
dc.subjectмеханічні властивості
dc.subjectFriedel-Crafts reaction
dc.subjectsilylated polystyrene
dc.subjectantipirene
dc.subjectbamboo powder
dc.subjectFTIR and NMR spectroscopy
dc.subjectmechanical properties
dc.titleBamboo-Containing Composites with Environmentally Friendly Binders
dc.title.alternativeБамбуковмісні композити з екологічно чистими в'яжучими речовинами
dc.typeArticle

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Chemistry & Chemical Technology. – 2023. – Vol. 17, No. 4