Synthesis, Characterization and Antibacterial Activity of Sn(II) and Sn(IV) Ions Complexes Containing N-Alkyl-N-Phenyl Dithiocarbamate Ligands

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dc.citation.epage739
dc.citation.issue4
dc.citation.spage729
dc.contributor.affiliationKerbala University
dc.contributor.authorAli, Wissam Abbas
dc.contributor.authorMihsen, Hayder Hamied
dc.contributor.authorGuzar, Sajid H.
dc.coverage.placenameЛьвів
dc.coverage.placenameLviv
dc.date.accessioned2025-03-05T08:54:16Z
dc.date.created2023-02-28
dc.date.issued2023-02-28
dc.description.abstractУ цій роботі ліганди з донорними атомами S2, N-метил-N-фенілдитіокарбамат натрію [L1] та N-етил-N-фенілдитіокарбамат натрію [L2] одержано з дисульфіду карбону за допомогою N-метиланіліну та N-етиланіліну, відповідно. Комплекси іонів Sn(II) та Sn(IV) з N-алкіл-N-фенілдитіокарбаматом одержано та охарактеризовано за допомогою CHNS елементного аналізу, інфрачервоної спектроскопії (FT-IR), 1Н ЯМР-спектроскопії, мас-спектроскопії, УФ-спектроскопії, вимірювання магнітної сприйнятливості та провідності. Аналітичні та спектральні дані показують, що стехіометрія для всіх комплексів становить 1 : 2 метал до ліганду. Спектральні дані підтверджують добру координацію дитіокарбаматного ліганду з металом через атоми сульфуру в дитіокарбаматному фрагменті. Вимірювання молярної провідності комплексів з використанням ДМФА як розчинника показало, що комплекси Sn(II) є неіонними, тоді як комплекси Sn(IV) є іонними. Ліганди L1 і L2 та їхні комплекси досліджено щодо бактерій Staphylococcusaureus і Escherichiacoli.
dc.description.abstractIn the current study, ligands S2 donor atoms, sodium N-methyl-N-phenyldithiocarbamate [L1], and sodium N-ethyl-N-phenyldithiocarbamate [L2] are prepared from carbon disulfide with N-methyl aniline and N-ethyl aniline, respectively. Sn(II) and Sn(IV) ions complexes containing N-alkyl-N-Phenyl dithiocarbamateare prepared and characterized by CHNS elemental analysis, infrared spectroscopy (FT-IR), 1HNMR-spectroscopy, mass spectroscopy, UV-visible spectroscopy, magnetic susceptibility and conductivity measurements. The analytical and spectral data show that the stoichiometry for all complexes is 1 : 2 metal to ligand. The spectral data confirm good coordination of dithiocarbamate ligand with the metal through sulfur atoms of dithiocarbamate moiety. Molar conductivity of complexes are measured using DMF as a solvent and indicated that the complexes of Sn(II) are non-ionic whereas Sn(IV) complexes are ionic. The ligands L1 and L2 and their complexes are examined against Staphylococcus aureus bacteria and Escherichia coli bacteria.
dc.format.extent729-739
dc.format.pages11
dc.identifier.citationAli W. A. Synthesis, Characterization and Antibacterial Activity of Sn(II) and Sn(IV) Ions Complexes Containing N-Alkyl-N-Phenyl Dithiocarbamate Ligands / Wissam Abbas Ali, Hayder Hamied Mihsen, Sajid H. Guzar // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2023. — Vol 17. — No 4. — P. 729–739.
dc.identifier.citationenAli W. A. Synthesis, Characterization and Antibacterial Activity of Sn(II) and Sn(IV) Ions Complexes Containing N-Alkyl-N-Phenyl Dithiocarbamate Ligands / Wissam Abbas Ali, Hayder Hamied Mihsen, Sajid H. Guzar // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2023. — Vol 17. — No 4. — P. 729–739.
dc.identifier.doidoi.org/10.23939/chcht17.04.729
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/63707
dc.language.isoen
dc.publisherВидавництво Львівської політехніки
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 4 (17), 2023
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dc.relation.referencesen[26] Mihsen, H.H.; Shareef, N.K. Synthesis, Characterization of Mixed-Ligand Complexes Containing 2,2-Bipyridine and 3-Aminopropyltriethoxysilane. J Phys Conf Ser2018, 1032,012066. https://doi:10.1088/1742-6596/1032/1/012066
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dc.rights.holder© Національний університет “Львівська політехніка”, 2023
dc.rights.holder© Ali W. A., Mihsen H. H., Guzar S. H., 2023
dc.subjectантибактеріальна активність
dc.subjectNалкіл-N-фенілдитіокарбамат
dc.subjectкомплекси стануму
dc.subjectспектральні дані
dc.subjectantibacterial activity
dc.subjectN-alkyl-N-phenyl dithiocarbamate
dc.subjecttin complexes
dc.subjectspectral data
dc.titleSynthesis, Characterization and Antibacterial Activity of Sn(II) and Sn(IV) Ions Complexes Containing N-Alkyl-N-Phenyl Dithiocarbamate Ligands
dc.title.alternativeСинтез, характеристика й антибактеріальна активність комплексів іонів Sn(II) та Sn(IV), що містять N-алкіл-N-фенілдитіокарбаматні ліганди
dc.typeArticle

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Chemistry & Chemical Technology. – 2023. – Vol. 17, No. 4